journal article·2018-01-30Open access

Intrinsic Magnetic Properties of Ce2Fe14B Modified by Al, Ni, or Si

Kayode Orimoloye, Dominic Ryan, Frederick Pinkerton, Mamoun Medraj

Applied Sciences· Volume 8· Issue 2

Abstract

Intrinsic magnetic properties (saturation magnetization, anisotropy fields, and Curie temperatures) of Ce2Fe14B doped with Al, Ni, and Si are presented. Substitution for Fe by these elements leads to the formation of solid solutions that crystallize in the tetragonal Nd2Fe14B structure. Substituting Al, Ni, or Si for Fe leads to a decrease in both the saturation magnetization and the anisotropy field of Ce2Fe14B. Ni and Si increase the Curie temperature of Ce2Fe14B while Al reduces it. While, for the Ce2(Fe14−xTx)B containing Ni, a maximum Curie temperature of 210 °C was observed at 9 atom % Ni (x = 1.45), the highest value of 252 °C was found for the Ce2Fe14B containing 14 atom % Si (x = 2.26).
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Research context

OpenAlex topics: Magnetic Properties of Alloys · Magnetic properties of thin films · Metallic Glasses and Amorphous Alloys

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Mechanical, Industrial and Aerospace Engineering, Concordia University, Montreal, QC H3G 1M8, Canada

Physics Department and Centre for the Physics of Materials, McGill University, Montreal, QC H3A 2T8, Canada

Chemical and Materials Systems Lab, General Motors R&D Center, 30500 Mound Rd., Warren, MI 48090, USA

Funding

Natural Sciences and Engineering Research Council of Canada

References (50)

Show source-provided references
1. Leaching study of precious metal recovery from ferric permanent magnet waste
2. Recycling of rare earths from NdFeB magnets using a combined leaching/extraction system based on the acidity and thermomorphism of the ionic liquid [Hbet][Tf2N]10.1039/C5GC00155B ↗
3. Magnetic hardening of Ce2Fe14B10.1063/1.3675175 ↗
4. R2Fe14B materials: Intrinsic properties and technological aspects10.1103/RevModPhys.63.819 ↗
5. The temperature dependence of the anisotropy field in R2Fe14B compounds (R = Y, La, Ce, Pr, Nd, Gd, Ho, Lu)
6. Neodymium-iron-boron permanent magnets10.1016/0304-8853(91)90812-O ↗
7. Magnetic properties of ternary rare-earth compounds of the type R2Fe14B10.1016/0304-8853(84)90261-0 ↗
8. Mixed valency and site-preference chemistry for cerium and its compounds: A predictive density-functional theory study10.1103/PhysRevB.89.235126 ↗
9. Cerium: An unlikely replacement of Dysprosium in high performance Nd–Fe–B permanent magnets10.1002/adma.201404892 ↗
10. Site-preference and valency for rare-earth sites in (R-Ce)2Fe14B magnets10.1063/1.4789527 ↗
11. Magnetic properties of bulk, and rapidly solidified nanostructured (Nd1−xCex)2Fe14−yCoyB ribbons10.1016/j.actamat.2015.09.049 ↗
12. High performance Nd–Fe–B permanent magnets without critical elements10.1016/j.jallcom.2016.01.194 ↗
13. Substitution of Ce for Nd in preparing R2Fe14B nanocrystalline magnets10.1016/j.jallcom.2014.12.042 ↗
14. Effect of Ce on the magnetic properties and microstructure of sintered Didymium–Fe–B magnets
15. Magnetic hardening of CeFe11Ti and the effect of TiC addition10.1109/TMAG.2014.2361644 ↗
16. Magnetic properties of CeFe11−xCoxTi with ThMn12 structure10.1063/1.4863382 ↗
17. High Curie temperature of Ce–Fe–Si compounds with ThMn12 structure10.1016/j.scriptamat.2014.10.006 ↗
18. Synthesis of CeFe10.5Mo1.5 with ThMn12-type structure by melt spinning10.1016/j.jmmm.2013.02.031 ↗
19. Magnetic hardening of CeFe12−xMox and the effect of nitrogenation10.1016/j.jallcom.2013.08.175 ↗
20. Effects of Ga addition on the formability of main phase and microstructure of hot-deformed Ce–Fe–B Magnets10.1109/TMAG.2016.2569519 ↗
21. Phase constitution and microstructure of Ce–Fe–B strip-casting alloy10.1088/1674-1056/23/10/107501 ↗
22. Magnetization and magnetic anisotropy of R2Fe14B measured on single crystals10.1063/1.336611 ↗
23. The microstructure and magnetic properties of melt-spun CeFeB ribbons with varying Ce content10.1007/s13391-014-4173-8 ↗
24. Crystal structure and magnetic properties of Ce2Fe14−xCoxB alloys10.1016/j.jallcom.2013.05.101 ↗
25. Anisotropic ternary Ce13Fe80B7 powders prepared by hydrogenation–disproportionation–desorption–recombination process and the diffusion of Ce–Cu eutectic alloys10.1016/j.jmmm.2012.11.035 ↗
26. Zhang, M., Shen, B., Hu, F., and Sun, J. (2015, January 11–15). The effect of Si substitution on structure and magnetic properties in Mischmetal–Fe–B ribbons. Proceedings of the 2015 IEEE International Magnetics Conference (INTERMAG), Beijing, China.10.1109/INTMAG.2015.7156593 ↗
27. Magnetic properties of Nd2(Fe1−xMx)14B measured on single crystals (M = Al, Cr, Mn and Co)10.1109/TMAG.1987.1065623 ↗
28. Structure and magnetic properties of R2Fe14−xNixB compounds (R = Nd and Gd)10.1002/pssa.2211140136 ↗
29. Exchange interaction and magnetic anisotropy in Nd2(Fe13M)B compounds (M = Ga, Si, Al)10.1016/0304-8853(89)90174-1 ↗
30. Magnetic properties of Nd2Fe14−xSixB compounds10.1002/pssa.2211010145 ↗
31. Effect of silicon additions on the magnetic properties of Nd2Fe12Co2B alloy10.1016/0304-8853(87)90010-2 ↗
32. Orimoloye, K., Kevorkov, D., and Medraj, M. (2017). Phase equilibria and magnetic phases in the Fe-rich regions of the Fe-Ce-{Ni, Si, Al}-B quaternary systems. J. Alloys Compd., submitted.10.1016/j.jallcom.2018.05.329 ↗
33. Putz, H., and Brandenburg, K. (2007). Pearson’s Crystal Data. Crystal Structure Database for Inorganic Compounds, ASM International. CD-ROM Software Version 1.3.
34. Nonaliticity of the magnetization curve: Application to the measurement of anisotropy in polycrystalline samples10.1103/PhysRevLett.28.1584 ↗
35. Singular points in the magnetization curve of a polycrystalline ferromagnet10.1063/1.1663823 ↗
36. Experimental and first-principles determination of the magnetocrystalline anisotropy in MnxGa10.1063/1.4974890 ↗
37. Temperature dependence of anisotropy fields and initial susceptibilities in R2Fe14B compounds10.1016/0304-8853(86)90122-8 ↗
39. Pinning effect of the grain boundaries on magnetic domain wall in FeCo-based magnetic alloys10.1063/1.370175 ↗
40. Determining the effect of grain size and maximum induction upon coercive field of electrical steels10.1016/j.jmmm.2011.03.034 ↗
41. Magnetic properties of polycrystalline FeBSi alloys with ultrafine grains10.1016/1359-6462(96)00074-7 ↗
42. Bulk magnetic properties of the Y2TxFe14−xB compounds, where T = Al, Ni, or Co10.1016/0038-1098(86)90773-8 ↗
43. On the magnetic behaviour of Nd2Fe12−xTxCo2B compounds (T = Al, V, Cr)10.1109/20.11653 ↗
44. Magnetocrystalline anisotropy of Ni and Mn substituted Nd2Fe14B compounds10.1016/0304-8853(87)90197-1 ↗
45. Magnetic properties of the new permanent magnet compounds Nd2(Fe0.9M0.1)14B (M = Sc, Ti, V, Cr, Mn, Co, Ni)10.1016/0022-5088(87)90356-0 ↗
46. On the magnetic behaviour of Y2Fe14−xNixB and Y2Fe14−xCoxB10.1016/0022-5088(85)90171-7 ↗
47. Magnetic properties of Y2Fe14−xMxB compounds where M = Si or Cu10.1016/0038-1098(87)90016-0 ↗
48. Mossbauer study of the permanent magnet material Nd2(Fe1−xNix)14B10.1063/1.340647 ↗
49. A neutron diffraction and Mössbauer spectral study of the structure and magnetic properties of the Y2Fe14−xSixB solid solutions10.1063/1.357536 ↗
50. Neutron diffraction and Mössbauer effect study of the preferential silicon site occupation and magnetic structure of Nd2Fe14−xSixB10.1063/1.355080 ↗