journal article·2023-12-15Open access

The Influence of Low-Pressure Plasma Treatments on the Lap Shear Strength of Laser-Joined AISI 304 Hybrids with Polypropylene and Polyamide 6.6

Wolfgang Tillmann, Lukas Wojarski, Christian Hopmann, Patricia Fatherazi, Christian Timmer

Applied Sciences· Volume 13· Issue 24

Abstract

This paper investigates if the polar groups induced by a plasma treatment can increase the lap shear strength of laser-joined metal and plastic hybrids. Optimal laser joining parameters for cold-rolled AISI304–polyamide 6.6 and sandblasted AISI304–polypropylene hybrids were developed at 2.85 MPa and 4.22 MPa, respectively. The surface free energy was doubled for all used plasma gases to a value of ca. 80 mN m−1 at 180 s. The plasma-treated samples were joined and tested. The arithmetic means of the plasma-treated hybrids’ lap shear strength with polyamide 6.6 varied slightly, but all measured values were within the range of the untreated samples. Residue on the sheared metal samples indicated covalent bonds between AISI304 and polyamide 6.6. The lap shear strengths of the plasma-treated polypropylene hybrids were significantly reduced between −30.8% and −53.3%, depending on the used plasma gas. This was attributed to the over-aging and development of low-molecular-weight oxidized materials, which led to a weak boundary layer. No residue of polypropylene was found on treated or untreated lap shear samples. No correlation between the surface free energy and lap shear strength could be found.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Mechanical Behavior of Composites · Structural Analysis of Composite Materials · Material Properties and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Materials Engineering (LWT), TU Dortmund University, Leonhard-Euler-Straße 2, 44227 Dortmund, Germany

RWTH Aachen, Institute of Plastics and Processing in Industry and Craft, RWTH Aachen University (IKV), Seffenter Weg 201, 52074 Aachen, Germany

Funding

German Research Foundation

References (37)

Show source-provided references
1. Zhou, Z., Gao, X., and Zhang, Y. (2022). Research Progress on Characterization and Regulation of Forming Quality in Laser Joining of Metal and Polymer, and Development Trends of Lightweight Automotive Applications. Metals, 12.10.3390/met12101666 ↗
2. Laser joining technology of polymer-metal hybrid structures—A review10.1016/j.jmapro.2022.05.026 ↗
3. Lambiase, F., Scipioni, S.I., Lee, C.-J., Ko, D.-C., and Liu, F. (2021). A State-of-the-Art Review on Advanced Joining Processes for Metal-Composite and Metal-Polymer Hybrid Structures. Materials, 14.10.3390/ma14081890 ↗
4. Joinability of different thermoplastic polymers with aluminium AA6082 sheets by mechanical clinching10.1007/s00170-015-7192-1 ↗
5. Mechanical behaviour of polymer–metal hybrid joints produced by clinching using different tools10.1016/j.matdes.2015.08.037 ↗
6. Mechanical and failure behaviour of hybrid polymer–metal staked joints10.1016/j.matdes.2012.10.043 ↗
7. Development of carbon/epoxy structural components for a high performance vehicle10.1016/j.compositesb.2003.11.010 ↗
8. Adhesion properties of novel corrosion resistant hybrid structures10.1016/j.ijadhadh.2013.12.009 ↗
9. Damage and failure processes of hybrid joints: Adhesive bonded aluminium plates reinforced by rivets10.1016/j.commatsci.2010.06.022 ↗
10. Induction-based joining of titanium with thermoplastics10.1007/s11740-019-00888-1 ↗
11. Development of ultrasonic direct joining of thermoplastic to laser structured metal10.1016/j.ijadhadh.2015.11.001 ↗
12. Novel Strategies for Laser Joining of Polyamide and AISI 30410.1016/j.phpro.2012.10.018 ↗
13. Potential of Laser-manufactured Polymer-metal hybrid Joints10.1016/j.phpro.2012.10.017 ↗
14. Toward process optimization in laser welding of metal to polymer. Prozessoptimierung beim Laserstrahlschweißen von Metall mit Kunststoff10.1002/mawe.201000674 ↗
15. Combined effects of temperature field and ultrasonic vibration on bubble motion in laser joining of plastic to metal10.1016/j.jmatprotec.2020.116846 ↗
16. Kawahito, Y., Tange, A., Kubota, S., and Katayama, S. (2006). International Congress on Applications of Lasers & Electro-Optics; ICALEO® 2006: 25th International Congress on Laser Materials Processing and Laser Microfabrication, Scottsdale, ZA, USA, 30 October–2 November 2006, Laser Institute of America.
17. A new laser joining technology for direct-bonding of metals and plastics10.1016/j.matdes.2016.08.018 ↗
18. Improving the interfacial bonding strength of dissimilar PA66 plastic and 304 stainless steel by oscillating laser beam10.1016/j.optlastec.2020.106869 ↗
19. Bonding mechanisms in laser-assisted joining of metal-polymer composites10.1016/j.jajp.2020.100008 ↗
20. Laser direct joining of metal and plastic10.1016/j.scriptamat.2008.08.026 ↗
21. Highlighting Chemical Bonding between Nylon-6.6 and the Native Oxide from an Aluminum Sheet Assembled by Laser Welding10.1021/acsapm.0c00015 ↗
22. Binding Mechanisms Between Laser-Welded Polyamide-6.6 and Native Aluminum Oxide10.1021/acsomega.1c04264 ↗
23. Failure mechanism analysis based on laser-based surface treatments for aluminum-polyamide laser joining10.1016/j.jmatprotec.2021.117318 ↗
24. Huang, Y., Gao, X., Ma, B., and Zhang, Y. (2021). Interface Formation and Bonding Mechanisms of Laser Welding of PMMA Plastic and 304 Austenitic Stainless Steel. Metals, 11.10.3390/met11091495 ↗
25. Al-Sayyad, A., Bardon, J., Hirchenhahn, P., Mertz, G., Haouari, C., Laurent, H., and Plapper, P. (2017, January 13–14). Influence of laser ablation and plasma surface treatment on the joint strength of laser welded aluminum-polyamide assemblies. Proceedings of the Journées Nationales des Procédés Laser pour l’Industrie––JNPLI 2017, Strassbourg, France.
26. Friedrich, J., and Friedrich, J.G. (2012). The Plasma Chemistry of Polymer Surfaces: Advanced Techniques for Surface Design, Wiley-VCH-Verlag.10.1002/9783527648009 ↗
27. Polypropylene surface modification by low pressure plasma to increase adhesive bonding: Effect of process parameters10.1016/j.surfcoat.2019.03.047 ↗
28. Van der Straeten, K.M. (2021). Laser-Based Joining of Plastic-Metal Hybrid Joints by Means of Self-Organizing Microstructures, RWTH Aachen University.
29. Habenicht, G. (2006). Kleben: Grundlagen, Technologien, Anwendungen: Mit 37 Tabellen, 5., erw. und Aktualisierte Aufl., Springer.10.1007/3-540-31223-4 ↗
30. Plasma Technology GmbH (2023, November 26). SmartPlasma 2–Plasma Technology. Available online: https://www.plasmatechnology.de/smartplasma-2.html.
32. (2023). Beschichtungsstoffe–Benetzbarkeit–Teil 2: Bestimmung der Freien Oberflächenenergie Fester Oberflächen Durch Messung des Kontaktwinkels (ISO/DIS 19403-2:2023). Deutsche und Englische Fassung prEN ISO 19403-2:2023 (Standard No. DIN EN ISO 19403-2).
33. Hybrid metal-plastic joining by means of laser10.1007/s12289-010-0971-1 ↗
34. Polášková, K., Klíma, M., Jeníková, Z., Blahová, L., and Zajíčková, L. (2021). Effect of Low Molecular Weight Oxidized Materials and Nitrogen Groups on Adhesive Joints of Polypropylene Treated by a Cold Atmospheric Plasma Jet. Polymers, 13.10.3390/polym13244396 ↗
35. Quantitative and selective study of the effect of O radicals on polypropylene surface treatment10.1088/1361-6595/ace5d3 ↗
36. Baur, E., Osswald, T.A., and Rudolph, N. (2013). Saechtling Kunststoff Taschenbuch, [Komplett Überarb., Aktualisiert und zum Ersten Mal in Farbe], Hanser. [31st ed.].10.3139/9783446437296.fm ↗
37. Scheik, S. (2016). Untersuchungen des Verbundverhaltens von Thermisch Direkt Gefügten Metall-Kunststoffverbindungen unter Veränderlichen Umgebungsbedingungen. [Ph.D. Dissertation, Rheinisch-Westfälische Technische Hochschule Aachen].