DataVXInternational Journal of Applied Glass SciencePaper
journal article·2022-10

Transparent glass‐ceramics in the TeO 2 –InF 3 system

Rémi Piotrowski, Hasnaa Benchorfi, Jean‐Paul Laval, Jean‐René Duclère, Cécile Genevois, Pierre Carles, Sébastien Chenu, Maggy Colas, Julie Cornette, Philippe Thomas, Gaëlle Delaizir

International Journal of Applied Glass Science· Volume 13· Issue 4
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Source abstract

Abstract

Abstract A crystallization study of the TeO 2 –InF 3 glass system shows that the specific glass composition 75TeO 2 –25InF 3 stabilizes a novel cubic anti‐glass phase within the glass matrix upon heat treatment. This peculiar crystalline phase also called “glass of anions” exhibits an interesting order/disorder coexistence, that is, a long‐range cation order but with a highly disordered anion sublattice. The thermal properties, structure and microstructure of the parent glass and corresponding glass‐ceramics have been studied. Finally, the luminescence of Yb 3+ ‐doped glass‐ceramics has been characterized, which confirmed the presence of the disordered anti‐glass phase.
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Research context

Ceramics & glassesMaterials processing

OpenAlex topics: Glass properties and applications · Luminescence Properties of Advanced Materials · Nuclear materials and radiation effects

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institut de Recherche sur les Céramiques (IRCER) UMR 7315 CNRS Université de Limoges Centre Européen de la Céramique Limoges France

Conditions Extrêmes et Matériaux: Haute Température et Irradiation (CEMHTI) Orléans France

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