Thermodynamic Aspects of Pressure‐Induced Crystallization: Kauzmann Pressure
Source abstract
Abstract
General equations for the dependence of the thermodynamic driving force and the specific interfacial energy melt‐crystal of critical clusters on temperature and pressure are derived. Analytical estimates of these and related thermodynamic quantities are advanced directly applicable in the analysis of experimental data of crystal nucleation. Similar to the well‐known notation of a Kauzmann temperature, the concept of a Kauzmann pressure is introduced. It is shown that the thermodynamic driving force of crystal nucleation has maxima not only at the Kauzmann temperature but also at the Kauzmann pressure. Estimates of the magnitude of the thermodynamic driving force of crystallization at these states are given and some consequences are discussed.
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Research context
OpenAlex topics: nanoparticles nucleation surface interactions · Material Dynamics and Properties · Chemical Thermodynamics and Molecular Structure
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Affiliations
Institute of Physics University of Rostock Albert‐Einstein‐Strasse 23‐25 Rostock 18059 Germany
National Science Center Kharkov Institute of Physics and Technology Kharkov 61108 Ukraine
Vavilov State Optical Institute ul. Babushkina 36‐1 St. Petersburg 193 171 Russia
Funding
Bundesministerium für Bildung und Forschung
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