journal article·2024-01Open access

Cold‐cap structure in a slurry‐fed electric melter

Pavel Ferkl, Pavel Hrma, Jaroslav Kloužek, Albert A. Kruger, Richard Pokorný

Abstract

Abstract As glass batch is charged into an electric melter, a cold cap forms on the glass melt surface. Heat transfer to the cold cap from the molten glass below and the melter atmosphere above determines the melting rate. A mathematical model of the cold cap and the experimental kinetic data of the feed‐to‐glass conversion that were collected for several simulated low‐activity and high‐level waste melter feeds allowed us to develop relationships between the internal structure of the cold cap, its properties, its thickness, and the internal heat transfer. This contribution shows the distribution of major crystalline phases and the cumulative evolution of gases within the cold cap. It also examines the temperature, conversion degree, and heating rate the melter feed is experiencing during the passage through the cold cap and their effects on the cold‐cap bottom temperature and morphology, which are important for the computational fluid dynamics simulations of melters.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Nuclear materials and radiation effects · Glass properties and applications · Recycling and utilization of industrial and municipal waste in materials production

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Pacific Northwest National Laboratory Richland Washington USA

U.S. Department of Energy, AttainX Support Services Contractor to the Office of River Protection Richland Washington USA

Laboratory of Inorganic Materials University of Chemistry and Technology Prague Prague Czech Republic

Institute of Rock Structure and Mechanics Czech Academy of Sciences Prague Czech Republic

U.S. Department of Energy Office of River Protection Richland Washington USA

References (70)

Show source-provided references
1. 10.1111/j.2041‐1294.2010.00023.x10.1111/j.2041‐1294.2010.00023.x ↗
2. 10.1023/a:101864650743810.1023/a:1018646507438 ↗
3. 10.1179/174367606X8168710.1179/174367606X81687 ↗
4. 10.1533/9780857090959.1.15910.1533/9780857090959.1.159 ↗
5. 10.2172/186282310.2172/1862823 ↗
6. 10.1016/j.jnucmat.2005.03.02610.1016/j.jnucmat.2005.03.026 ↗
7. 10.2172/177223610.2172/1772236 ↗
8. 10.1111/j.1151‐2916.1990.tb06715.x10.1111/j.1151‐2916.1990.tb06715.x ↗
9. 10.13036/17533546.59.3.01410.13036/17533546.59.3.014 ↗
10. 10.1111/ijag.1503110.1111/ijag.15031 ↗
11. 10.1111/jace.1377510.1111/jace.13775 ↗
12. 10.2172/105948210.2172/1059482 ↗
13. 10.1016/0022‐3093(80)90536‐010.1016/0022‐3093(80)90536‐0 ↗
14. Melting behavior of continuously charged loose batch blankets in glass melting furnaces
15. 10.1016/j.jnucmat.2013.11.00910.1016/j.jnucmat.2013.11.009 ↗
16. 10.1080/21870764.2021.190791410.1080/21870764.2021.1907914 ↗
17. 10.1111/ijag.1266610.1111/ijag.12666 ↗
18. 10.1111/ijag.1591110.1111/ijag.15911 ↗
19. 10.1111/jace.1728110.1111/jace.17281 ↗
20. 10.1016/j.jnoncrysol.2021.12136310.1016/j.jnoncrysol.2021.121363 ↗
21. 10.1111/ijag.1661510.1111/ijag.16615 ↗
22. Kuhn WS · 2002 · 73
23. Laboratory techniques for studying foam formation and stability in glass melting
24. 10.1111/ijag.1663110.1111/ijag.16631 ↗
25. 10.1111/jace.1431010.1111/jace.14310 ↗
26. 10.1002/9781118407004.ch1210.1002/9781118407004.ch12 ↗
27. 10.1002/9781118407004.ch1310.1002/9781118407004.ch13 ↗
28. Mathematical modeling of cold cap: effect of bubbling on melting rate
29. 10.1016/j.ecmx.2021.10008310.1016/j.ecmx.2021.100083 ↗
30. 10.2109/jcersj2.2206810.2109/jcersj2.22068 ↗
31. 10.2172/115471810.2172/1154718 ↗
32. Chapman C · 2004
33. 10.1111/jace.1575510.1111/jace.15755 ↗
34. 10.1016/j.ceramint.2019.12.25610.1016/j.ceramint.2019.12.256 ↗
35. 10.1021/acs.est.5b0093110.1021/acs.est.5b00931 ↗
36. 10.1016/j.ceramint.2018.12.12710.1016/j.ceramint.2018.12.127 ↗
37. 10.1111/ijag.1580310.1111/ijag.15803 ↗
38. Drainage of primary melt in a glass batch
39. 10.1111/jace.1687610.1111/jace.16876 ↗
40. 10.1016/j.tca.2012.04.01910.1016/j.tca.2012.04.019 ↗
41. 10.1016/j.net.2018.12.00210.1016/j.net.2018.12.002 ↗
42. The dissolution of silica grains in isothermally heated batches of sodium carbonate and silica sand
43. 10.1016/j.jnucmat.2013.07.03910.1016/j.jnucmat.2013.07.039 ↗
44. 10.1016/j.ceramint.2020.02.21510.1016/j.ceramint.2020.02.215 ↗
45. 10.1021/la00070a02010.1021/la00070a020 ↗
46. 10.1111/j.1151‐2916.1992.tb04371.x10.1111/j.1151‐2916.1992.tb04371.x ↗
47. 10.1016/j.jnoncrysol.2006.08.03510.1016/j.jnoncrysol.2006.08.035 ↗
48. 10.1111/ijag.1235310.1111/ijag.12353 ↗
49. 10.1111/ijag.1586310.1111/ijag.15863 ↗
50. 10.1016/j.ceramint.2021.11.34410.1016/j.ceramint.2021.11.344 ↗
51. 10.1111/ijag.1221410.1111/ijag.12214 ↗
52. X‐ray CT imaging of vitrified glasses containing simulant radioactive wastes: structure and chemical reactions of glass beads and wastes in the cold cap
53. 10.13168/cs.2021.004410.13168/cs.2021.0044 ↗
54. 10.5796/electrochemistry.81.54310.5796/electrochemistry.81.543 ↗
55. 10.1016/j.tca.2013.02.01610.1016/j.tca.2013.02.016 ↗
56. 10.1007/s10973‐015‐4998‐x10.1007/s10973‐015‐4998‐x ↗
57. 10.1016/0040‐6031(71)85051‐710.1016/0040‐6031(71)85051‐7 ↗
58. 10.1016/j.jnoncrysol.2013.02.01410.1016/j.jnoncrysol.2013.02.014 ↗
59. 10.1111/jace.1376610.1111/jace.13766 ↗
60. 10.1016/0021‐9797(90)90262‐M10.1016/0021‐9797(90)90262‐M ↗
61. Bikerman JJ · 1970
62. 10.1002/pi.120310.1002/pi.1203 ↗
63. 10.1016/0377‐0273(93)90084‐510.1016/0377‐0273(93)90084‐5 ↗
64. 10.1016/j.cis.2015.11.00910.1016/j.cis.2015.11.009 ↗
65. 10.1111/jace.1489510.1111/jace.14895 ↗
66. 10.1111/jace.1462910.1111/jace.14629 ↗
67. 10.1111/jace.1646310.1111/jace.16463 ↗
68. 10.1111/jace.1740610.1111/jace.17406 ↗
69. 10.1007/978-3-642-55966-2_210.1007/978-3-642-55966-2_2 ↗
70. 10.1016/j.jnucmat.2021.15342310.1016/j.jnucmat.2021.153423 ↗