journal article·2023-07-25Open access

Two Convenient Methods for Detection of Non-Dairy Fats in Butter by Dynamic Light Scattering and Luminescence Spectroscopy

Leonid L. Chaikov, Marina N. Kirichenko, Svetlana V. Krivokhizha, Maskhud R. Kupov, Andrey N. Lobanov, Pavel P. Sverbil, Egor I. Nagaev, Alexey V. Shkirin

Applied Sciences· Volume 13· Issue 15

Abstract

We propose two convenient methods to quickly detect the presence of non-milk fat (palm oil) in butter, as well as to determine its amount in the product. For the first time, we have experimentally obtained the dependence of the size of drops of an alcoholic emulsion of oil or spread on the content of palm oil in it by the dynamic light scattering (DLS) method. We have also obtained the dependence of intensity ratio of the components of spread luminescence spectrum on palm oil content when excited at a wavelength λ = 266 nm. These results allowed us to propose two methods for determining the adulteration of butter with palm oil using DLS and measuring luminescence spectra. The two methods are physically independent but successfully supplement each other. DLS and luminescent methods for determining the proportion of palm oil give errors of no more than 10% and 6%, respectively.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Spectroscopy and Chemometric Analyses · Advanced Chemical Sensor Technologies · Edible Oils Quality and Analysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

P.N. Lebedev Physical Institute of the Russian Academy of Sciences, Leninskiy Prospekt 53, 119991 Moscow, Russia

Physics Department, Bauman Moscow State Technical University, 2-nd Baumanskaya Str. 5, 105005 Moscow, Russia

Prokhorov General Physics Institute of the Russian Academy of Sciences, Vavilova St. 38, 119991 Moscow, Russia

Laser Physics Department, National Research Nuclear University MEPhI, Kashirskoe sh. 31, 115409 Moscow, Russia

Funding

Russian Science Foundation

References (31)

Show source-provided references
1. The adulteration of food, lessons from the past, with reference to butter, margarine and fraud10.1007/s00217-014-2274-0 ↗
2. Comparative study between some methods for the detection of palm oil addition to milk fat
3. Preliminary Discrimination of Butter Adulteration by ATR-FTIR Spectroscopy. Bulletin of University of Agricultural Sciences and Veterinary Medicine Cluj-Napoca
4. Detection of Milk Fat Adulteration in Commercial Butter and Sour Cream10.3923/ijds.2021.18.28 ↗
5. Raman spectroscopy in the quality analysis of dairy products: A literature review10.1002/jrs.6214 ↗
6. (2021, June 20). Council Regulation (EC) No 1234/2007 of 22 October 2007. Establishing a common organisation of agricultural markets and on specific provisions for certain agricultural products (Single CMO Regulation). Available online: https://lexparency.org/eu/32007R1234/.
7. Horwitz, W., and Latimer, G.W. (2005). AOAC Official Methods of Analysis, AOAC International. [18th ed.].
8. Determination of Milk Fat Adulteration with Vegetable Oils and Animal Fats by Gas Chromatographic Analysis10.1111/1750-3841.12979 ↗
9. A review on the application of chromatographic methods, coupled to chemometrics, for food authentication10.1016/j.foodcont.2018.06.015 ↗
10. A chromatographic method for detection of palm oil in butter
11. Use of spectroscopic methods in combination with linear discriminant analysis for authentication of food products10.1016/j.foodcont.2018.03.031 ↗
12. Determination of the adulteration of butter10.1002/ejlt.201100006 ↗
13. Edible Oils Adulteration: A Review on Regulatory Compliance and Its Detection Technologies10.5650/jos.ess21109 ↗
14. Determination of butter adulteration with margarine using Raman spectroscopy10.1016/j.foodchem.2013.06.061 ↗
15. Assessment of laser induced breakdown spectroscopy as a tool for analysis of butter adulteration10.1016/j.jfca.2017.12.032 ↗
16. Authentication analysis of butter from beef fat using Fourier Transform Infrared (FTIR) spectroscopy coupled with chemometrics
17. Application of temperature-controlled attenuated total reflectance-mid-infrared (ATR-MIR) spectroscopy for rapid estimation of butter adulteration10.1016/j.foodchem.2009.12.083 ↗
18. Rapid quantitative determination of butter adulteration with palm oil using the DSC technique10.1016/j.foodcont.2015.09.001 ↗
19. Zhong, J., and Wang, X. (2019). Woodhead Publishing Series in Food Science, Technology and Nutrition, Woodhead Publishing.
20. Application of synchronous fluorescence spectroscopy with multivariate data analysis for determination of butter adulteration10.1111/ijfs.12594 ↗
21. Short communication: Rapid detection of milk fat adulteration with vegetable oil by fluorescence spectroscopy10.3168/jds.2012-6417 ↗
22. Interstate Standard for Milk and Dairy Products. Methods for Determining Fat (Standard No. GOST 5867-90). (In Russian).
23. Cosmetic Creams. General Technical Conditions (Standard No. GOST R52343-2005). (In Russian).
24. New Technique for Identifying Butter Adulteration with Palm Fat by the DLS Method10.3103/S1068335621060038 ↗
25. Shaking-Induced Aggregation and Flotation in Immunoglobulin Dispersions: Differences between Water and Water–Ethanol Mixtures10.1021/acsomega.0c01444 ↗
26. Dhont, J.K. (1996). An Introduction to Dynamics of Colloids, Elsevier.
27. Correlation spectroscopy measurements of particle size using an optical fiber probe10.3103/S1068335609040010 ↗
28. (2022, December 06). Photocor-FC. Available online: https://www.photocor.com/products/photocor-fc.
29. A Simple New Way to Detect Butter Adulteration by Palm Oil Using Luminescence10.3103/S1068335622120053 ↗
30. Appearance of an artifact peak in the particle size distribution measured by DLS at low concentrations10.3103/S1068335616080066 ↗
31. Influence of low concentrations of scatterers and signal detection time on the results of their measurements using dynamic light scattering10.1070/QEL16408 ↗