Resurgence of a Nation’s Radiation Science Driven by Its Nuclear Industry Needs
Source abstract
Abstract
This article describes the radiation facilities and associated sample preparation, management, and analysis equipment currently in place at the Dalton Cumbrian Facility, a facility which opened in 2011 to support the UK’s nuclear industry. Examples of measurements performed using these facilities are presented to illustrate their versatility and the breadth of research they make possible. Results are presented from research which furthers our understanding of radiation damage to polymeric materials, radiolytic yield of gaseous products in situations relevant to nuclear materials, radiation chemistry in light water reactor cooling systems, material chemistry relevant to immobilization of nuclear waste, and radiation-induced corrosion of fuel cladding elements. Applications of radiation chemistry relevant to health care are also described. Research concerning the mechanisms of radioprotection by dietary carotenoids is reported. An ongoing open-labware project to develop a suite of modular sample handling components suited to radiation research is described, as is the development of a new neutron source able to provide directional beams of neutrons.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Radioactive element chemistry and processing · Nuclear Materials and Properties · Radioactive contamination and transfer
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
The University of Manchester’s Dalton Cumbrian Facility, Westlakes Science Park, Moor Row, Cumbria CA24 3HA, UK
Department of Chemistry, The University of Manchester, Oxford Road, Manchester M13 9PL, UK
Jacobs, Walton House, Birchwood Park, Faraday St., Warrington WA3 6GA, UK
Sellafield Limited, Seascale, Cumbria CA20 1PG, UK
Scottish Universities Environmental Research Centre, Rankine Avenue, Scottish Enterprise Technology Park, East Kilbride G75 0QF, UK
ISIS Pulsed Neutron and Muon Source, STFC, Rutherford Appleton Laboratory, Harwell, Didcot OX11 0QX, UK
National Nuclear Laboratory, Havelock Road, Derwent Howe, Workington, Cumbria CA14 3YQ, UK
TÜV SÜD Nuclear Technologies, Ennerdale Pavillion, Westlakes Science and Technology Park, Ingwell Dr, Moor Row, Cumbria CA24 3JZ, UK
National Nuclear Laboratory, Seascale, Cumbria CA20 1PG, UK
Idaho National Laboratory, 1955 N. Fremont Avenue, Idaho Falls, ID 83415, USA
Diamond Light Source, Diamond House, Harwell Science and Innovation Campus, Didcot OX11 0DE, UK
References (64)
Show source-provided references
1. Ayres, G.P. (1986). An Overview of Thirty Years of Operation of Calder Hall, British Nuclear Fuels Ltd.
2. World Nuclear Association Information Library (2021, October 25). Nuclear Development in the United Kingdom Appendix 1. Available online: https://www.world-nuclear.org/information-library/country-profiles/countries-t-z/appendices/nuclear-development-in-the-united-kingdom.aspx.
3. House of Lords Select Committee on Science and Technology (2021, September 03). Report of Inquiry into Nuclear Research and Development (R&D) Capabilities in the UK. Available online: https://publications.parliament.uk/pa/ld201012/ldselect/ldsctech/221/22102.htm.
4. UK Public General Acts (2021, September 03). Energy Act 2004; Part 1: The Civil Nuclear Industry, Available online: https://www.legislation.gov.uk/ukpga/2004/20/contents.
5. (2021, September 03). Nuclear Decommissioning Authority Corporate Report. Dalton Cumbrian Facility: 10 Years of Collaboration, Available online: https://www.gov.uk/government/publications/dalton-cumbrian-facility-celebrating-a-10-year-journey-to-success/dalton-cumbrian-facility-10-years-of-collaboration.
6. UK Government Department for Business, Energy & Industrial Strategy, and Nuclear Innovation and Research Office (2021). UK Nuclear Fission R&D Catalogue: Facilities, Equipment and Capabilities.
7. Development of irradiation capabilities to address the challenges of the nuclear industry10.1016/j.nimb.2014.11.028 ↗
8. High current He− injector for tandem accelerators10.1016/j.nimb.2006.03.167 ↗
9. Benson, J., Rowton, L., Tesmer, J., and Darling, R. (1991, January 16–19). Multi cathode SNICS ion source. Proceedings of the 25th Symposium of North Eastern Accelerator Personnel, Santa Fe, NM, USA.10.1142/9789814537094 ↗
10. Materials challenges in nuclear energy10.1016/j.actamat.2012.11.004 ↗
11. Gilbert, M., Dudarev, S., Zheng, S., Packer, L., and Sublet, J.-C. (2012). An integrated model for materials in a fusion power plant: Transmutation, gas production, and helium embrittlement under neutron irradiation. Nucl. Fusion, 52.10.1088/0029-5515/52/8/083019 ↗
12. Evolution of spent nuclear fuel in dry storage conditions for millennia and beyond10.1016/j.jnucmat.2014.03.055 ↗
13. Accelerated radiation damage test facility using a 5 MV tandem ion accelerator10.1016/j.nima.2015.09.088 ↗
14. Structural defect accumulation in tungsten and tungsten-5wt.% tantalum under incremental proton damage10.1016/j.jnucmat.2017.11.030 ↗
15. Radiation-induced void formation and ordering in Ta-W alloys10.1016/j.jnucmat.2017.08.029 ↗
16. High-dose ion irradiation damage in Fe28Ni28Mn26Cr18 characterised by TEM and depth-sensing nanoindentation10.1016/j.nme.2021.101028 ↗
17. Monolayer-thick TiO precipitation in V-4Cr-4Ti alloy induced by proton irradiation10.1016/j.scriptamat.2016.12.002 ↗
18. Observations of fatigue crack behaviour in proton-irradiated 304 stainless steel10.1111/ffe.13087 ↗
19. Characterisation of irradiation enhanced strain localisation in a zirconium alloy10.1016/j.mtla.2019.100248 ↗
20. The stability of irradiation-induced defects in Zr3AlC2, Nb4AlC3 and (Zr0.5, Ti0.5)3AlC2 MAX phase-based ceramics10.1016/j.actamat.2019.10.049 ↗
21. Influence of proton-irradiation temperature on the damage accumulation in Ti3SiC2 and Ti3AlC210.1016/j.scriptamat.2019.02.022 ↗
22. Radiolytic hydrogen generation at silicon carbide–water interfaces10.1016/j.jnucmat.2015.11.031 ↗
23. Jones, L. (2015). The Radiation Chemistry of Gases at the Interface with Ceramic Oxides. [Ph.D. Thesis, The University of Manchester].
24. Geopolymers from fly ash and their gamma irradiation10.1016/j.matlet.2018.05.088 ↗
25. Evidence for pore water composition controlling carbonate morphology in concrete and the further effect of gamma radiation10.1016/j.conbuildmat.2020.122049 ↗
26. Long term effects of gamma irradiation on in-service concrete structures10.1016/j.jnucmat.2021.152868 ↗
27. Barr, L. (2015). Radiation Effects on Novel Polymeric Encapsulants. [Ph.D. Thesis, The University of Manchester].
28. Effect of ionising radiation on the mechanical and structural properties of 3D printed plastics
29. Horne, G. (2015). An Experimental and Computational Investigation into the Radiolysis of PUREX Solvent Systems. [Ph.D. Thesis, The University of Manchester].
30. Gamma irradiation-induced defects in borosilicate glasses for high-level radioactive waste immobilisation10.1016/j.jnucmat.2020.152702 ↗
31. (2020, September 30). Unisense H2 MICROSENSOR. Available online: http://www.unisense.com/H2/.
32. O’Leary, M., Baidak, A., Barnes, M., Donoclift, T., Emerson, C., Figueira, C., Fox, O.J.L., Kleppe, A., McCulloch, A., and Messer, D.M. (2021). First Observation of Radiolytic Bubble Formation in Unstirred Nano-powder Sludges and a Consistent Model Thereof. Sci. Rep., in press.10.1038/s41598-021-01868-1 ↗
33. Haschke, J.M., and Allen, T.H. (1999). Interactions of Plutonium Dioxide with Water and Oxygen-Hydrogen Mixtures, LA-13537-MS.10.2172/3509 ↗
34. Morales, L.A. (1998). Preliminary Report on the Recombination Rates of Hydrogen and Oxygen over Pure and Impure Plutonium Oxides, LA-UR-98-5022.
35. Messer, D. (2021). Radiolytic Recombination of H2, O2 and N2 over PuO2 Surrogate Materials. [Ph.D. Thesis, The University of Manchester].
36. Phase Separation and Crystallisation in UK HLW Vitrified Products10.1016/j.mspro.2014.10.013 ↗
37. An international initiative on long-term behavior of high-level nuclear waste glass10.1016/j.mattod.2013.06.008 ↗
38. SRIM—The stopping and range of ions in matter10.1016/j.nimb.2010.02.091 ↗
39. Compaction of ion-implanted fused silica10.1063/1.1662952 ↗
40. MeV ion irradiation-induced creation and relaxation of mechanical stress in silica10.1063/1.359820 ↗
41. Origin of MeV ion irradiation-induced stress changes in SiO210.1063/1.373624 ↗
42. Self-accelerated corrosion of nuclear waste forms at material interfaces10.1038/s41563-019-0579-x ↗
43. Effects of a Combination of Beta Carotene and Vitamin A on Lung Cancer and Cardiovascular Disease10.1056/NEJM199605023341802 ↗
44. A dramatic effect of oxygen on protection of human cells against γ-radiation by lycopene10.1002/1873-3468.12134 ↗
45. Anti- and pro-oxidative mechanisms comparing the macular carotenoids zeaxanthin and lutein with other dietary carotenoids—A singlet oxygen, free-radical in vitro and ex vivo study10.1039/d0pp00120a ↗
46. Gamma radiolysis as a tool to study lipoprotein oxidation mechanisms10.1016/j.biochi.2004.10.007 ↗
47. Critical Review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (•OH/•O−) in Aqueous Solution10.1063/1.555805 ↗
48. Donoclift, T., Edge, R., Unsworth, T., Warren, K., Jenkins, A., and Ostle, L. (2018, January 18–22). Radiation Tolerance Studies of Commercial Strippa ble Coatings and Fixatives used for Decontamination. Proceedings of the Waste Management Conference, Phoenix, AZ, USA.
49. Calculation of the Yields for the Primary Species Formed from the Radiolysis of Liquid Water by Fast Neutrons at Temperatures between 25–350 °C10.1667/RR13638.1 ↗
50. Spinks, J.W.T., and Woods, R.J. (1990). An Introduction to Radiation Chemistry, Wiley-Blackwell. [3rd ed.].
51. Ashmore, C.B., Sims, H.E., Tait, P.K., and Walters, W.S. (1997). The Measurement of Water Radiolysis Product Yields at High Temperature and Pressure, AEA Technology. Progress Report AEAT—1278.
52. Low LET radiolysis escape yields for reducing radicals and H2 in pressurized high temperature water10.1016/j.radphyschem.2015.12.007 ↗
53. Low-linear energy transfer radiolysis of liquid water at elevated temperatures up to 350 °C: Monte-Carlo simulations10.1016/j.cplett.2011.04.059 ↗
54. Effects of Track Structure on the Ion Radiolysis of the Fricke Dosimeter10.1021/jp020830u ↗
55. Multi-Scale Modeling of the Gamma Radiolysis of Nitrate Solutions10.1021/acs.jpcb.6b06862 ↗
56. Comstock, R., and Motta, A. (2016, January 15–19). The role of gamma radiation on Zircaloy-4 corrosion. Proceedings of the Zirconium in the Nuclear Industry: 18th International Symposium, Hilton Head, SC, USA.
57. In situ EIS Measurements of Irradiated Zircaloy-4 Post-Transition Corrosion Kinetic Behavior10.1520/JAI101206 ↗
58. Chan, C.M. (2021). Project E1: Effect of gamma irradiation on Zirconium alloy corrosion. Understanding Hydrogen Pickup Mechanism: MUZIC-3 Advanced Materials Characterization and Testing, Electric Power Research Institute, Inc.. EPRI Report No. 3002020953.
59. A novel experimental approach to investigate radiolysis processes in liquid samples using collimated radiation sources10.1063/1.4914054 ↗
60. Radiation chemical studies with heavy ions: Oxidation of ferrous ion in the Fricke dosimeter10.1021/j100306a050 ↗
61. Introduction to Radiation Chemistry10.2307/3577852 ↗
62. Development of a kinematically focused neutron source with the p(7Li,n)7Be inverse reaction10.1016/j.nima.2013.07.061 ↗
63. (2021, August 29). JANIS—Renderer. Available online: https://www.oecd-nea.org/janisweb/book/protons/O16/MT28.
64. The Impact of Neutrons in Clinical Proton Therapy