journal article·2022-07

The effect of sodium polymethacrylate on the rheology of the positive paste and performance of the lead‐acid battery

Julian Kosacki, Dimitri Feys, Fatih Dogan

Publisher page

Abstract

Abstract Due to its rheological properties, positive lead‐acid battery paste can be difficult to spread on lead current collectors accurately and efficiently under industry machinery and setting. Sodium polymethacrylate dispersant was studied as an effective positive paste additive that could lower the yield stress of the paste without affecting paste density and battery performance. Under a four‐blade vane rheometer setup, stress growth and oscillatory amplitude strain sweep experiments evaluated the rheological properties of positive paste with the addition of varying amounts of sodium polymethacrylate. Further, the electrochemical effects of sodium polymethacrylate were also evaluated in 2V batteries by testing positive active material utilization and cycle life.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Advanced Battery Technologies Research · Advancements in Battery Materials · Advanced Battery Materials and Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Materials Science and Engineering Missouri University of Science and Technology Rolla Missouri

Department of Civil Architectural & Environmental Engineering Missouri University of Science and Technology Rolla Missouri

References (18)

Show source-provided references
1. Pillot C · 2017
2. 10.1126/science.abd335210.1126/science.abd3352 ↗
3. FaureCA.French Patent 141057.A Construction of Secondary Galvanic Battery Couples.1881.
4. PavlovDLead‐Acid Batteries: Science and Technology. Elsevier Amsterdam. 2011.https://doi.org/10.1016/C2009-0-16975-110.1016/C2009-0-16975-1 ↗
5. 10.1023/A:101791771259510.1023/A:1017917712595 ↗
6. 10.1111/ijac.1255710.1111/ijac.12557 ↗
7. 10.1111/j.1744-7402.2011.02675.x10.1111/j.1744-7402.2011.02675.x ↗
8. 10.1149/1945-7111/abe9c910.1149/1945-7111/abe9c9 ↗
9. 10.1122/1.54970910.1122/1.549709 ↗
10. 10.1122/1.54979410.1122/1.549794 ↗
11. MezgerTG SprinzC&GreenAApplied Rheology: With Joe Flow on Rheology Road. Anton Paar GmbH; 2018.
12. 10.1149/1.205007910.1149/1.2050079 ↗
13. 10.1007/BF0060891910.1007/BF00608919 ↗
14. 10.1016/0378-7753(82)80017-710.1016/0378-7753(82)80017-7 ↗
15. 10.1016/S0378-7753(96)02499-810.1016/S0378-7753(96)02499-8 ↗
16. 10.1149/1.210855510.1149/1.2108555 ↗
17. 10.1016/0378-7753(93)90020-210.1016/0378-7753(93)90020-2 ↗
18. Bullock KR · 2004 · 10910.1016/B978-044450746-4/50006-4 ↗