Application of a Phosphazene Derivative as a Flame Retardant for Cotton Fabric using Conventional Method and Supercritical CO 2
Source abstract
Abstract
Conventional pad-dry-cure (non-scCO 2 ) and supercritical carbon dioxide (scCO 2 ) application methods were used to study the effectiveness of a newly synthesized phosphazene derivative as a flame retardant on cotton fabric. The 1,1′,4,5-tetrahydrotrispiro[1,3,2-diazaphosphole-2,2′-[1,3,5,2,4,6]triazatriphosphinine-4′,6”-dibenzo[d, f][1,3,2] dioxaphosphepine-6′,6”′-dibenzo[d, f][1,3,2]dioxaphosphepine] (2), was synthesized in two steps, in high overall yield, and applied onto cotton fabrics. The flame retardant properties of the treated fabrics were examined by 45° angle flammability test, limiting oxygen index test (LOI), microscale combustion calorimetry (MCC), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). The results indicate that fabrics treated with 2 are flame resistant; however, non-scCO 2 fabrics performed better than scCO 2 fabrics in a preliminary durability study.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Flame retardant materials and properties · Synthesis and properties of polymers · Synthesis and characterization of novel inorganic/organometallic compounds
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
USDA-ARS-SRRC
References (48)
Show source-provided references
1. Shaw S.D. · Review of Environmental Health · 2010 · 25 · 261
2. 10.1177/073490410808948510.1177/0734904108089485 ↗
3. 10.1002/app.2152210.1002/app.21522 ↗
4. Allen C.W., Hernandez-Rubio D. The Use of Phosphazenes as Flame Retardants. In Phosphazenes: A Worldwide Insight; Nova Science Publishers Inc.: Hauppauge, NY, USA, 2004; pp 485–503.
5. 10.1080/0040500080256367710.1080/00405000802563677 ↗
6. 10.1002/fam.81006010410.1002/fam.810060104 ↗
7. Barker R.H. · 1985 · 423
8. 10.1021/am300843c10.1021/am300843c ↗
9. 10.1021/ie400180f10.1021/ie400180f ↗
10. 10.1021/ie300964g10.1021/ie300964g ↗
11. 10.1177/00405175680380030710.1177/004051756803800307 ↗
12. 10.1002/jps.260064100310.1002/jps.2600641003 ↗
13. Zeronian S.H. · 1985 · 138
14. 10.1002/3527606726.ch1010.1002/3527606726.ch10 ↗
15. Kraft G. · Lenzinger Berichte · 2004 · 83 · 117
16. 10.1007/s10853-011-5480-110.1007/s10853-011-5480-1 ↗
17. 10.1016/j.supflu.2005.11.00510.1016/j.supflu.2005.11.005 ↗
18. 10.1007/978-94-017-0245-4_310.1007/978-94-017-0245-4_3 ↗
19. 10.1007/978-94-017-0245-4_810.1007/978-94-017-0245-4_8 ↗
20. Makower J. Color It Green: Nike to Adopt Waterless Textile Dyeing, 2012, http://www.greenbiz.com/blog/2012/02/07/color-it-green-nike-adopt-waterless-textile-dyeing (accessed November 2013).
21. Huntsman J. M. Innovative Dyes and Process Technology from Huntsman Textile Effects and Dyecoo Eliminates the Use of Water in the Textile Dyeing Process, 2012, http://www.huntsman.com/corporate/a/Innovation/DyeCoo%20delivers%20sustainable%20textiles (accessed December 2013).
22. Ferris D. Nike and Adidas Want to Dye Your Shirt with No Water, 2012, http://www.forbes.com/sites/davidferris/2012/08/30/nike-adidas-want-to-color-your-shirt-with-no-water/ (accessed November 2013).
23. 10.1016/j.supflu.2013.10.00310.1016/j.supflu.2013.10.003 ↗
24. 10.1016/j.supflu.2011.10.00810.1016/j.supflu.2011.10.008 ↗
25. Chang S., Condon B., Smith J. Proceedings, Supercritical Fluids International Symposium, San Francisco, CA, 2012; pp 1–4.
26. Halford B. · Chemical and Engineering News · 2011 · 89 · 24
27. Annual Book of ASTM Standards, Vol. 7.01, West Conshohocken, PA, USA, 2010, pp 262–268.
28. Annual Book of ASTM Standards, Vol. 8.01, West Conshohocken, PA, USA, 2013, pp 1–13.
29. Annual Book of ASTM Standards, Vol. 8.03, West Conshohocken, PA, USA, 2013, pp 1–11.
30. AATCC Test Method 124-2011, Smoothness Appearance of Fabrics after Repeated Home Laundering; AATCC: Research Triangle Park, NC, USA, 2011.
31. 10.1021/ma001735r10.1021/ma001735r ↗
32. 10.1021/ma951830d10.1021/ma951830d ↗
33. 10.1016/S0378-3812(03)00022-010.1016/S0378-3812(03)00022-0 ↗
34. 10.1016/j.supflu.2012.11.01710.1016/j.supflu.2012.11.017 ↗
35. 10.1016/B978-0-08-045329-3.00003-210.1016/B978-0-08-045329-3.00003-2 ↗
36. 10.1021/je60087a01810.1021/je60087a018 ↗
37. Easson M. · AATCC Review · 2011 · 11 · 60
38. Schartel B. · 2010 · 387
39. 10.1039/C1JM14682C10.1039/C1JM14682C ↗
40. 10.1016/j.jaap.2011.01.01210.1016/j.jaap.2011.01.012 ↗
41. Yoshioka-Tarver M. · AATCC Review · 2012 · 12 · 52
42. 10.1021/bk-2012-1118.ch01710.1021/bk-2012-1118.ch017 ↗
43. Shafizadeh F. · 1985 · 266
44. Ayeni N.A. · Bayero Journal of Pure and Applied Sciences · 2012 · 5 · 51
45. 10.1016/j.materresbull.2013.08.03310.1016/j.materresbull.2013.08.033 ↗
46. 10.1016/j.firesaf.2013.09.00910.1016/j.firesaf.2013.09.009 ↗
47. 10.1016/j.apsusc.2012.12.13910.1016/j.apsusc.2012.12.139 ↗
48. 10.1007/s10973-012-2473-510.1007/s10973-012-2473-5 ↗