journal article·2019-12-11Open access

Fire Properties of Acrylonitrile Butadiene Styrene Enhanced with Organic Montmorillonite and Exolit Fire Retardant

Tudor Mihai Simionescu, Alina Adriana Minea, Paulo Nobre Balbis dos Reis

Applied Sciences· Volume 9· Issue 24

Abstract

In this paper an experimental investigation on fire retardancy of a new polymer nanocomposite derived from organic montmorillonite and exolit fire retardant in an acrylonitrile- butadiene-styrene copolymer by analyzing the flammability and fire behavior is described. The samples were prepared by melting and mixing nanocomposites and fire retardant in different concentrations in an acrylonitrile-butadiene-styrene base polymer. It was found that using only one component (organic montmorillonite or fire retardant) the burning stops in 10 s on the sample. Confirmation of synergy in flammability by combining both montmorillonite and flame retardants was noticed and is discussed regarding the flame-retardant mechanisms assessed by means of the Limiting oxygen index (LOI), UL 94, and cone-calorimeter methods. The acrylonitrile- butadiene-styrene preparation with 15–20 wt% fire retardant and 1–2 wt% organic montmorillonite reached a UL-94 V-0 classification, contrasting with the pure acrylonitrile- butadiene-styrene and the acrylonitrile-butadiene-styrene with 15 wt% fire retardant and acrylonitrile-butadiene-styrene with 1–2 wt% organic montmorillonite formulations, which completely burned. Finally, the samples showed a very good synergy going to a higher reduction of the peak heat release rate and to a minimum mass reduction, as obtained from cone calorimeter tests.
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Research context

OpenAlex topics: Flame retardant materials and properties · Polymer Nanocomposites and Properties · Synthesis and properties of polymers

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Faculty of Materials Science and Engineering, Technical University “Gheorghe Asachi” of Iasi, 700050 Iasi, Romania

C-MAST, Department of Electromechanical Engineering, University of Beira Interior, Calçada Fonte do Lameiro, 6201-100 Covilhã, Portugal

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