Correlation between composition and adhesion properties of a zinc oxide-filled, acrylate pressure sensitive adhesive: An experimental design approach
Source abstract
Abstract
A Box-Behnken response surface methodology (RSM) was adopted to provide a systematic insight on the adhesion properties of an acrylate-based, pressure sensitive adhesive (PSA) filled with nano-zinc oxide (ZnO) particles as a function of its composition. In addition to the nano-filler morphologies (needle- or plate-like) and their content (0–10 per hundred resin, phr), concentrations of triethyl citrate (TEC, 30–50 phr) plasticizer and oxalic acid (OX, 0.5–1.5 phr) crosslinking agent were also changed with respect to the base polymer. Tack and peel strength properties were measured as adhesive performance characteristics. According to the results, ZnO content and its morphology played no significant role ( P < 0.05) in adhesion performance of the compositions made. In contrast, the more plasticizer was used, the more peel strength and tack properties were achieved. OX showed an inverse effect on the tack and peel strength properties at a less statistically significant level. A removable PSA was achieved adopting the RSM methodology to develop formulations, which resulted in a removable and repositionable PSA. To understand these effects, molecular structures of the adhesive ingredients and their interactions were thoroughly discussed.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advanced Polymer Synthesis and Characterization · Silicone and Siloxane Chemistry · Polymer Nanocomposites and Properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (47)
Show source-provided references
1. Crosslinked acrylic pressure-sensitive adhesives. I. Effect of the crosslinking reaction on the peel strength10.1002/app.11529 ↗
2. Pocius · 2002
3. UV-crosslinkable acrylic pressure-sensitive adhesives for industrial application10.1007/s00289-012-0725-y ↗
4. Using of carbon nanotubes and nano carbon black for electrical conductivity adjustment of pressure-sensitive adhesives10.1016/j.ijadhadh.2012.04.004 ↗
5. Viscosity and peel strength of magnesium oxide-filled adhesive prepared from epoxidized natural rubber (ENR 25)10.1080/03602550903284289 ↗
6. Effect of zinc oxide on the viscosity, tack, and peel strength of ENR 25-based pressure-sensitive adhesives10.1002/app.26677 ↗
7. Effect of zinc oxide concentration and testing rate on shear properties of Standard Malaysian Rubber (SMR) L-based pressure-sensitive adhesives10.1177/0095244312445524 ↗
8. ZnO nanostructures for optoelectronics: material properties and device applications10.1016/j.pquantelec.2010.04.001 ↗
9. Characterization of ZnO nanopowder and antibacterial response against Staphylococcus aureus under UVA illumination10.4028/www.scientific.net/AMR.795.148 ↗
10. Benedek · 2008
11. Influence of water soluble and insoluble plasticizers on the physical and mechanical properties of acrylic resin copolymers10.1016/0378-5173(94)90180-5 ↗
12. Organic esters of plasticizers affecting the water absorption, adhesive property, glass transition temperature and plasticizer permanence of Eudragit acrylic films10.1016/S0168-3659(00)00259-5 ↗
13. Solid-state plasticization of an acrylic polymer with chlorpheniramine maleate and triethyl citrate10.1016/S0378-5173(02)00244-2 ↗
14. Plasticization and antiplasticization of an acrylic pressure sensitive adhesive by ibuprofen and their effect on the adhesion properties10.1016/j.ejpb.2013.07.005 ↗
15. Multifunctional propyleneimines-new generation of crosslinkers for solvent-based pressure-sensitive adhesives10.1016/j.ijadhadh.2004.01.005 ↗
16. Mahoney W.S., Weikel A.L., Krepski L.R., Gaddam B.N., Pressure-sensitive adhesives with acid-epoxy crosslinking systems, US Patent 9217099 B2, 2015..
17. Contact time dependence of tack for crosslinked polyacrylic pressure-sensitive adhesives with two different molecular structures10.1016/j.ijadhadh.2015.04.001 ↗
18. Ko C.U., Wouters D., Yeadon G., Mallya P., Maerki R., Dual crosslinked tackified pressure sensitive adhesive, US Patent 9321938 B2, 2016..
19. A new class of pressure-sensitive adhesives based on interpolymer and polymer-oligomer complexes
20. Preparation and characterization of expanded graphite intercalation compound/UV-crosslinked acrylic resin pressure sensitive adhesives10.1007/s13233-015-3064-7 ↗
21. Chemical and physical factors affecting performance of pressure-sensitive adhesives10.1080/07366578608081971 ↗
22. Akyar · 2011
23. “Design of experiments” analysis in study of solventless UV crosslinkable acrylic pressure sensitive adhesives10.1016/j.ijadhadh.2012.11.005 ↗
24. “D-optimal experimental design” analysis in preparing optimal polyisobutylene based pressure sensitive adhesives10.1016/j.ijadhadh.2017.06.005 ↗
25. A statistical experimental design approach to evaluate the influence of various penetration enhancers on transdermal drug delivery of buprenorphine10.1016/j.jare.2014.01.006 ↗
26. A measurement system analysis with design of experiments: investigation of the adhesion performance of a pressure sensitive adhesive with the probe tack test10.1016/j.ijpharm.2015.09.061 ↗
27. A sequential design approach for in situ incorporation of cellulose nanocrystals in emulsion-based pressure sensitive adhesives10.1007/s10570-020-03060-6 ↗
28. Butyl acrylate/vinyl acetate emulsion‐based pressure‐sensitive adhesives: empirical modelling of final properties10.1002/cjce.5450850309 ↗
29. Simple mass production of zinc oxide nanostructures via low-temperature hydrothermal synthesis10.1088/2053-1591/aa5dcc ↗
30. Peel adhesion of acrylic pressure-sensitive adhesives on selected substrates versus their surface energies10.1016/j.ijadhadh.2013.12.013 ↗
31. Hansen · 2007
32. The effect of plasticizers on compatibility, mechanical properties, and adhesion strength of drug-free Eudragit E films10.1023/A:1015850301214 ↗
33. Preparation and evaluation of fentanyl transdremal patches using lidocaine as a model drug and azelaic acid as a penetration enhancer
34. Effect of plasticizer on the dynamic surface tension and the free volume of Eudragit systems10.1016/S0378-5173(02)00317-4 ↗
35. Effect of dodecafluoroheptyl methacrylate (DFMA) on the comprehensive properties of acrylate emulsion pressure sensitive adhesives10.1016/j.ijadhadh.2020.102634 ↗
36. Pressure sensitive adhesives based on interpolymer complexes10.1016/j.progpolymsci.2014.10.006 ↗
37. Molecular dynamics study of the mechanical properties of polydisperse pressure-sensitive adhesives10.1016/j.ijadhadh.2019.04.006 ↗
38. Influence of iron carbide filler in carbon matrix on the adhesive properties of acrylic pressure-sensitive adhesives10.1016/j.ijadhadh.2012.07.010 ↗
39. Rheology and adhesive properties of filled PIB-based pressure-sensitive adhesives. II. Probe tack and 90° peel testing10.1080/01694243.2015.1078433 ↗
40. Rheological and adhesive properties of PIB-based pressure-sensitive adhesives with montmorillonite-type nanofillers10.1016/j.eurpolymj.2016.01.040 ↗
41. Soft polymer-silica nanocomposite particles as filler for pressure-sensitive adhesives10.1016/j.polymer.2015.06.006 ↗
42. Pressure sensitive adhesive property modification using cellulose nanocrystals10.1016/j.ijadhadh.2017.11.009 ↗
43. Acrylic pressure‐sensitive adhesives with nanodiamonds and acid–base dependence of the pressure‐sensitive adhesive properties10.1002/app.46349 ↗
44. Rheology and applications of highly filled polymers: a review of current understanding10.1016/j.progpolymsci.2016.12.007 ↗
45. Montgomery · 2001
46. Synthesis of removable and repositionable water‐borne pressure‐sensitive adhesive acrylics10.1002/app.21328 ↗
47. Simultaneous optimization of mechanical properties of steel by maximizing exponential desirability functions