journal article·2020-10-13Open access

High Performance of Salt-Modified–LTO Anode in LiFePO4 Battery

Agus Purwanto, Soraya Ulfa Muzayanha, Cornelius Satria Yudha, Hendri Widiyandari, Arif Jumari, Endah Retno Dyartanti, Muhammad Nizam, Muhamad Iqbal Putra

Applied Sciences· Volume 10· Issue 20

Abstract

Highly crystalline “zero-strain” Li4Ti5O12 (LTO) has great potential as an alternative material for the anodes in a lithium ion battery. In this research, highly crystalline LTO with impressive electrochemical characteristics was synthesized via a salt-assisted solid-state reaction using TiO2, LiOH, and various amounts of NaCl as a salt additive. The LTO particles exhibited a cubic spinel structure with homogenous micron-sized particles. The highest initial specific discharge capacity of LTO was 141.04 mAh/g with 4 wt % NaCl addition, which was tested in a full-cell (LTO/LiFePO4) battery. The battery cell showed self-recovery ability during the cycling test at 10 C-rate, which can extend the cycle life of the cell. The salt-assisted process affected the crystallinity of the LTO particles, which has a favorable effect on its electrochemical performance as anodes.
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Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemical Engineering, Faculty of Engineering, Universitas Sebelas Maret, Jl. Ir. Sutami 36 A, Surakarta, Central Java 57126, Indonesia

Centre of Excellence for Electrical Energy Storage Technology, Universitas Sebelas Maret, Jl. Slamet Riyadi 435, Surakarta, Central Java 57146, Indonesia

Research & Technology Center, PT. Pertamina (Persero), Jl Raya Bekasi km 20, Pulogadung, Jakarta 19320, Indonesia

Department of Physics, Faculty of Mathematic and Natural Science, Universitas Sebelas Maret, Jl. Ir. Sutami 36 A, Surakarta, Central Java 57126, Indonesia

Department of Electrical Engineering, Faculty of Engineering, Universitas Sebelas Maret, Jl. Ir. Sutami 36 A, Surakarta, Central Java 57126, Indonesia

Funding

Kementerian Riset Teknologi Dan Pendidikan Tinggi Republik Indonesia

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