Adsorption of Anionic Dyes from Wastewater onto Magnetic Nanocomposite Powders Synthesized by Combustion Method
Source abstract
Abstract
In the present study, new magnetic nanocomposites were successfully prepared by combustion method, characterized by X-ray diffraction, Fourier transform infrared spectroscopy, magnetic measurements, N2 adsorption–desorption thermal analysis, and scanning electron microscopy, and tested as adsorbents for the removal of anionic dyes (Acid Yellow 42 and Acid Red 213) from aqueous solutions. The influence of process variables solution pH, adsorbent dose, initial dye concentration and temperature on the adsorption was evaluated. The best kinetic model that fitted with experimental data was a pseudo-second order model, and the equilibrium data were correlated by Langmuir isotherm model for the investigated dyes. Maximum removal efficiencies of 98.54% and 97.58% was obtained for Acid Yellow 42 and Acid Red 213, respectively, indicating the superior adsorption capacity of the new synthesized magnetic nanocomposites. The thermodynamic parameters indicated the spontaneous and endothermic nature of the adsorption process.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Adsorption and biosorption for pollutant removal · Nanomaterials for catalytic reactions · Graphene research and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
“Coriolan Drăgulescu” Institute of Chemistry, 24 Mihai Viteazu, 300223 Timisoara, Romania
Faculty of Industrial Chemistry and Environmental Engineering, Politehnica University Timișoara, 6 Pârvan Blv., 300223 Timisoara, Romania
Faculty of Pharmacy, “Victor Babes” University of Medicine and Pharmacy Timișoara, Eftimie Murgu Squareno.2, RO-300041 Timișoara, Romania
References (76)
Show source-provided references
1. Bharagava, R.N., and Chowdhary, P. (2019). Chapter 11: Textile Wastewater Dyes: Toxicity Profile and Treatment Approaches. Emerging and Eco-Friendly Approaches for Waste Management, Springer Nature Singapore Pte Ltd.10.1007/978-981-10-8669-4 ↗
2. Recent advances in the treatment of dye-containing wastewater from textile industries: Overview and perspectives10.1016/j.psep.2020.05.034 ↗
3. Effects of textile dyes on health and the environment and bioremediation potential of living organisms10.1016/j.biori.2019.09.001 ↗
4. Malik, A., and Grohmann, E. (2012). Chapter 4: Dyes—Environmental Impact and Remediation. Environmental Protection Strategies for Sustainable Development, Strategies for Sustainability, Springer Science + Business Media B.V.10.1007/978-94-007-1591-2 ↗
5. Al Prol, A.E. (2019). Study of Environmental Concerns of Dyes and Recent Textile Effluents Treatment Technology: A Review. Asian J. Fish. Aquat. Res., 1–18.10.9734/ajfar/2019/v3i230032 ↗
6. Textile Industry’s Environmental Effects and Approaching Cleaner Production and Sustainability: An Overview
7. Enhancement removal of crystal violet dye using magnetic calcium ferrite nanoparticle: Study in single- and binary-solute systems10.1016/j.cherd.2014.10.013 ↗
8. Significantly enhanced dye removal performance of hollow tin oxide nanoparticles via carbon coating in dark environment and study of its mechanism10.1186/1556-276X-9-442 ↗
9. Adsorption of food dyes from aqueous solution by glutaraldehyde cross-linked magnetic chitosan nanoparticles10.1016/j.jfoodeng.2013.11.014 ↗
10. Health and Environmental Impacts of Dyes: Mini Review
11. Manzoor, J., and Sharma, M. (2020). Chapter 8: Impact of Textile Dyes on Human Health and Environment. Impact of Textile Dyes on Public Health and the Environment, IGI Global.10.4018/978-1-7998-0311-9.ch008 ↗
12. Pollution, Toxicity and Carcinogenicity of Organic Dyes and their Catalytic Bio-Remediation10.2174/1381612825666191021142026 ↗
13. Efficiency of various recent wastewater dye removal methods: A review10.1016/j.jece.2018.06.060 ↗
14. Removal of Colored Organic Pollutants from Wastewaters by Magnetite/Carbon Nanocomposites: Single and Binary Systems10.1155/2018/6249821 ↗
15. Kuang, Y., Zhang, X., and Zhou, S. (2020). Adsorption of Methylene Blue in Water onto Activated Carbon by Surfactant Modification. Water, 12.10.3390/w12020587 ↗
16. Dye and its removal from aqueous solution by adsorption: A review10.1016/j.cis.2014.04.002 ↗
17. Garrido-Cardenas, J.A., Esteban-García, B., Agüera, A., Sánchez-Pérez, J.A., and Manzano-Agugliaro, F. (2019). Wastewater Treatment by Advanced Oxidation Process and Their Worldwide Research Trends. Int. J. Environ. Res. Public Health, 17.10.3390/ijerph17010170 ↗
18. Lin, L., Jiang, W., Chen, L., Xu, P., and Wang, H. (2020). Treatment of Produced Water with Photocatalysis: Recent Advances, Affecting Factors and Future Research Prospects. Catalysts, 10.10.3390/catal10080924 ↗
19. Synthetic reactive dye wastewater treatment by using nano-membrane filtration10.1080/19443994.2014.912964 ↗
20. Effective Catalytic Degradation of Organic Dyes by Nickel Supported on Hydroxyapatite-Encapsulated Cobalt Ferrite (Ni/HAP/CoFe2O4) Magnetic Novel Nanocomposite10.1007/s11270-020-4409-1 ↗
21. Coagulation/flocculation process for dye removal using water treatment residuals: Modelling through artificial neural networks10.1080/19443994.2016.1165150 ↗
22. Experimental study of dye removal from industrial wastewater by membrane technologies of reverse osmosis and nanofiltration10.1186/1735-2746-9-17 ↗
23. Biodegradation of synthetic dyes of textile effluent by microorganisms: An environmentally and economically sustainable approach10.1556/1886.2019.00018 ↗
24. Advantages and disadvantages of techniques used for wastewater treatment10.1007/s10311-018-0785-9 ↗
25. Chapter1: Wastewater Treatment: An Overview10.1007/978-3-319-92111-2_1 ↗
26. A Review on Adsorption of Cationic Dyes using Activated Carbon10.1051/matecconf/201814402022 ↗
27. Adsorption Removal of Safranin Dye Contaminants from Water Using Various Types of Natural Zeolite10.1007/s12633-018-9980-3 ↗
28. Mesoporous magnetic nanocomposites: A promising adsorbent for the removal of dyes from aqueous solutions10.1007/s10934-019-00821-y ↗
29. Nistor, M.A., Muntean, S.G., Maranescu, B., and Visa, A. (2020). Phosphonate metal–organic frameworks used as dye removal materials from wastewaters. Appl. Organomet. Chem., 34.10.1002/aoc.5939 ↗
30. The dye removal from aqueous solution using polymer composite films10.1007/s13201-018-0856-x ↗
31. Dye sequestration using agricultural wastes as adsorbents10.1016/j.wri.2015.09.002 ↗
32. Ge, M., Xi, Z., Zhu, C., Liang, G., Hu, G., Jamal, L., and Alam, S.M.J. (2019). Preparation and Characterization of Magadiite–Magnetite Nanocomposite with Its Sorption Performance Analyses on Removal of Methylene Blue from Aqueous Solutions. Polymers, 11.10.3390/polym11040607 ↗
33. Combustion synthesis of iron oxide/carbon nanocomposites, efficient adsorbents for anionic and cationic dyes removal from wastewaters10.1016/j.jallcom.2018.01.240 ↗
34. Liu, Y., Huang, Y., Xiao, A., Qiu, H., and Liu, L. (2019). Preparation of Magnetic Fe3O4/MIL-88A Nanocomposite and Its Adsorption Properties for Bromophenol Blue Dye in Aqueous Solution. Nanomaterials, 9.10.3390/nano9010051 ↗
35. Combustion synthesis of Fe3O4/Ag/C nanocomposite and application for dyes removal from multicomponent systems10.1016/j.apsusc.2019.03.161 ↗
36. Metal oxides nanoparticles via sol–gel method: A review on synthesis, characterization and applications10.1007/s10854-020-02994-8 ↗
37. Preparation and Dye Degradation Performances of Self-Assembled MXene-Co3O4 Nanocomposites Synthesized via Solvothermal Approach10.1021/acsomega.9b00231 ↗
38. One-step hydrothermal synthesis of hydrophilic Fe3O4/carbon composites and their application in removing toxic chemicals10.1039/C6RA01408A ↗
39. Cobalt–carbon/silica nanocomposites prepared by pyrolysis of a cobalt 2,2′-bipyridine terephthalate complex for remediation of cationic dyes10.1039/D0RA02752A ↗
40. Magnetite nanoparticles synthesized by co-precipitation method: The effects of various iron anions on specifications10.1016/j.matchemphys.2016.09.058 ↗
41. Effective removal of methylene blue from aqueous solution using a new magnetic iron oxide nanosorbent prepared by combustion synthesis
42. Magnetite/carbon nanocomposites prepared by an innovative combustion synthesis technique—Excellent adsorbent materials10.1016/j.ceramint.2014.05.092 ↗
43. Combustion synthesis of some iron oxides used as adsorbents for phenol and p-chlorophenol removal from wastewater10.1007/s10973-012-2750-3 ↗
44. Highly crystalline porous magnetite and vacancy-ordered maghemite microcrystals of rhombohedral habit10.1016/j.jcrysgro.2013.06.003 ↗
45. Use of Magnetic Activated Carbon in a Solid Phase Extraction Procedure for Analysis of 2,4-dichlorophenol in Water Samples10.1007/s11270-020-04610-1 ↗
46. Development of a reusable and sustainable biocatalyst by immobilization of soybean peroxidase onto magnetic adsorbent10.1016/j.ijbiomac.2018.03.136 ↗
47. X-ray Diffraction (XRD) and Energy Dispersive Spectroscopy (EDS) Analysis of Silver Nanoparticles Synthesized from Erythrina Indica Flowers10.15226/2374-8141/5/1/00152 ↗
48. Mineralogical notes. An infrared absorption analysis of magnetite
49. Formation and surface modification of Fe3O4 nanoparticles by co-precipitation and sol–gel method
50. Deposition of Magnetite Nanoparticles in Activated Carbons and Preparation of Magnetic Activated Carbons10.1063/1.2776712 ↗
51. Infrared Spectroscopy of Carbon Materials: A Quantum Chemical Study of Model Compounds10.1021/jp027482g ↗
52. IR spectroscopy applied to metal oxide surfaces: Adsorbate vibrations and beyond
53. Infrared and Raman spectroscopic studies on iron oxide magnetic nano-particles and their surface modifications10.1016/j.jmmm.2011.11.065 ↗
54. Method of Infrared Spectra Registration of Activated Carbons in Potassium Bromide Pellets10.19261/cjm.2015.10(1).16 ↗
55. Infrared spectroscopy in surface chemistry of carbons
56. Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report)10.1515/pac-2014-1117 ↗
57. Adsorptive removal of anionic dyes from aqueous solutions using spent mushroom waste10.1007/s13201-020-01268-2 ↗
58. Adsorption of selected azo dyes from an aqueous solution by activated carbon derived from Monotheca buxifolia waste seeds10.17221/59/2019-SWR ↗
59. Dye adsorbed on copolymer, possible specific sorbent for metal ions removal10.1039/C4RA02918F ↗
60. Evaluation of a functionalized copolymer as adsorbent on direct dyes removal process: Kinetics and equilibrium studies10.1002/app.38017 ↗
61. Investigation of aggregation behavior using computational methods and absorption spectra for trisazo direct dyes10.1007/s11224-015-0705-6 ↗
62. Investigation of the aggregation of three disazo direct dyes by UV-Vis Spectroscopy and mathematical analysis
63. Zur theorie der sogenannten adsorption geloster stoffe
64. Pseudo-second order model for sorption processes10.1016/S0032-9592(98)00112-5 ↗
65. Over the Adsorption in Solution
66. The Adsorption of Gases on Plane Surfaces of Glass, Mica and Platinum10.1021/ja02242a004 ↗
67. Efficient removal of Eriochrome black-T from aqueous solution using NiFe2O4 magnetic nanoparticles10.1186/s40201-014-0112-8 ↗
68. Removal of anionic dyes using magnetic Fe@graphite core-shell nanocomposite as an adsorbent from aqueous solutions10.1016/j.jcis.2017.03.008 ↗
69. Functionalization of magnetic chitosan with graphene oxide for removal of cationic and anionic dyes from aqueous solution10.1016/j.carbpol.2016.06.045 ↗
70. Synthesis, characterization, and adsorption properties of magnetic Fe3O4@graphene nanocomposite10.1016/j.cej.2011.12.017 ↗
71. Removal of methylene blue and acid orange 7 from aqueous solutions by activated carbon coated with zinc oxide (ZnO) nanoparticles: Equilibrium, kinetic, and thermodynamic study10.1080/19443994.2014.914449 ↗
72. Direct dyes removal using modified magnetic ferrite nanoparticle10.1186/2052-336X-12-96 ↗
73. Magnetic nanopowder as effective adsorbent for the removal of Congo Red from aqueous solution
74. Adsorption of anionic dye onto magnetic Fe3O4/CeO2 nanocomposite: Equilibrium, kinetics, and thermodynamics10.1177/0263617418819164 ↗
75. Equilibrium, kinetics and thermodynamic adsorption studies of acid dyes on adsorbent developed from kenaf core fiber10.1177/0263617417715532 ↗
76. Synthesis and properties of Fe3O4-activated carbon magnetic nanoparticles for removal of aniline from aqueous solution: Equilibrium, kinetic and thermodynamic studies10.1186/1735-2746-10-19 ↗