Understanding the Origin and Mixing of Deep Fluids in Shallow Aquifers and Possible Implications for Crustal Deformation Studies: San Vittorino Plain, Central Apennines
Source abstract
Abstract
Expanding knowledge about the origin and mixing of deep fluids and the water–rock–gas interactions in aquifer systems can represent an improvement in the comprehension of crustal deformation processes. An analysis of the deep and meteoric fluid contributions to a regional groundwater circulation model in an active seismic area has been carried out. We performed two hydrogeochemical screenings of 15 springs in the San Vittorino Plain (central Italy). Furthermore, we updated the San Vittorino Plain structural setting with a new geological map and cross-sections, highlighting how and where the aquifers are intersected by faults. The application of Na-Li geothermometers, coupled with trace element and gas analyses, agrees in attributing the highest temperatures (>150 °C), the greatest enrichments in Li (124.3 ppb) and Cs (>5 ppb), and traces of mantle-derived He (1–2%) to springs located in correspondence with high-angle faults (i.e., S5, S11, S13, and S15). This evidence points out the role of faults acting as vehicles for deep fluids into regional carbonate aquifers. These results highlight the criteria for identifying the most suitable sites for monitoring variations in groundwater geochemistry due to the uprising of deep fluids modulated by fault activity to be further correlated with crustal deformation and possibly with seismicity.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: earthquake and tectonic studies · Geological and Geochemical Analysis · Geological and Geophysical Studies Worldwide
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Earth Sciences Department, Sapienza University of Rome, 00185 Rome, Italy
Department of Chemistry, Life Sciences and Environmental Sustainability, University of Parma, 43124 Parma, Italy
National Institute of Geophysics and Volcanology, 90146 Palermo, Italy
Department of Chemistry and Pharmacy, University of Sassari, 07100 Sassari, Italy
References (100+)
Show source-provided references
1. Residence time indicators in groundwater: The East Midlands Triassic sandstone aquifer10.1016/S0883-2927(99)00079-7 ↗
2. Review: Thermal water resources in carbonate rock aquifers10.1007/s10040-010-0611-3 ↗
3. Hydrochemical Changes Before and After Earthquakes Based on Long-Term Measurements of Multiple Parameters at Two Sites in Northern Iceland—A Review10.1029/2018JB016757 ↗
4. Chemical signature detection of groundwater and geothermal waters for evidence of crustal deformation along fault zones10.1016/j.jhydrol.2019.124459 ↗
5. Veining and post-nappe transtensional faulting in the SW Helvetic Alps (Switzerland)10.1007/s00015-015-0199-7 ↗
6. Fluid pressure cycles, variations in permeability, and weakening mechanisms along low-angle normal faults: The Tellaro detachment, Italy10.1130/B31203.1 ↗
7. Agosta, F., and Kirschner, D.L. (2003). Fluid conduits in carbonate-hosted seismogenic normal faults of central Italy: Fluid conduits in seismogenic normal faults. J. Geophys. Res., 108.10.1029/2002JB002013 ↗
8. Cardello, G.L. (2013). The Rawil Depression: Its Structural History from Cretaceous to Neogene. [Ph.D. Thesis, ETH Zurich].
9. The role of trapped fluids during the development and deformation of a carbonate/shale intra-wedge tectonic mélange (Mt. Massico, Southern Apennines, Italy)10.1016/j.jsg.2020.104086 ↗
10. Permeability as a toggle switch in fluid-controlled crustal processes10.1016/S0012-821X(00)00263-6 ↗
11. Geochemical evidence of melt intrusions along lithospheric faults of the Southern Apennines, Italy: Geodynamic and seismogenic implications10.1029/2000JB900047 ↗
12. Chiodini, G., Cardellini, C., Amato, A., Boschi, E., Caliro, S., Frondini, F., and Ventura, G. (2004). Carbon dioxide Earth degassing and seismogenesis in central and southern Italy: Carbon dioxide earth degassing and seismogenesis. Geophys. Res. Lett., 31.10.1029/2004GL019480 ↗
13. Helium and carbon isotopes in the dissolved gases of Friuli Region (NE Italy): Geochemical evidence of CO2 production and degassing over a seismically active area10.1016/j.chemgeo.2009.05.022 ↗
14. Fault on–off versus coseismic fluids reaction10.1016/j.gsf.2013.08.004 ↗
15. Crustal-scale fluid circulation and co-seismic shallow comb-veining along the longest normal fault of the central Apennines, Italy10.1016/j.epsl.2018.06.013 ↗
16. Beyond Byerlee friction, weak faults and implications for slip behavior. Earth Planet
17. Evidences of the role of seismicity on degassing of volatile through the crust
18. New Applications in Gas Geochemistry10.1155/2020/4976190 ↗
19. Long-term geochemical monitoring and extensive/compressive phenomena: Case study of the Umbria Region (Central Apennines, Italy)
20. Geochemical monitoring of cold waters during seismicity: Implications for earthquake-induced modification in shallow aquifers10.3319/TAO.2005.16.4.709(GIG) ↗
21. Hydrogeochemical changes before and during the 2016 Amatrice-Norcia seismic sequence (central Italy)10.1038/s41598-017-11990-8 ↗
22. CO2 Inflow and Elements Desorption Prior to a Seismic Sequence, Amatrice-Norcia 2016, Italy10.1029/2018GC008117 ↗
23. Stabilization of fault slip by fluid injection in the laboratory and in situ10.1126/sciadv.aau4065 ↗
24. Post-seismic hydrochemical changes in regional groundwater flow systems in response to the 2016 Mw 7.0 Kumamoto earthquake10.1016/j.jhydrol.2019.124340 ↗
25. Groundwater trace elements change induced by M5.0 earthquake in Yunnan10.1016/j.jhydrol.2019.124424 ↗
26. Hydrogeological and Gasgeochemical Earthquake Precursors? A Review for Application10.1007/s11069-004-2072-2 ↗
27. Hydrothermal CO2 degassing in seismically active zones during the late Quaternary10.1016/j.chemgeo.2009.05.011 ↗
28. Heterogeneous strength and fault zone complexity of carbonate-bearing thrusts with possible implications for seismicity10.1016/j.epsl.2014.10.021 ↗
29. The role of fluid pressure in induced vs. triggered seismicity: Insights from rock deformation experiments on carbonates10.1038/srep24852 ↗
30. CO2 Degassing over Seismic Areas: The Role of Mechanochemical Production at the Study Case of Central Apennines10.1007/s00024-007-0291-7 ↗
31. Determining the origin of carbon dioxide and methane in the gaseous emissions of the San Vittorino plain (Central Italy) by means of stable isotopes and noble gas analysis10.1016/j.apgeochem.2013.02.015 ↗
32. Radiogenic helium degassing and rock fracturing: A case study of the southern Apennines active tectonic region10.1002/2014JB011462 ↗
33. Tracing deep fluid source contribution to groundwater in an active seismic area (central Italy): A combined geothermometric and isotopic (δ13C) perspective10.1016/j.jhydrol.2019.124495 ↗
34. Alps vs. Apennines: The paradigm of a tectonically asymmetric Earth10.1016/j.earscirev.2012.02.004 ↗
35. Schema Idrogeologico Dell’Italia Centrale
36. Correlation between tectonic CO2 Earth degassing and seismicity is revealed by a 10-year record in the Apennines, Italy10.1126/sciadv.abc2938 ↗
37. Madonia, P., Cangemi, M., Oliveri, Y., and Germani, C. (2020). Hydrogeochemical Characters of Karst Aquifers in Central Italy and Relationship with Neotectonics. Water, 12.10.3390/w12071926 ↗
38. Interaction between deep and shallow groundwater systems in areas affected by Quaternary tectonics (Central Italy): A geochemical and isotope approach10.1007/s12665-010-0663-7 ↗
39. Petitta, M. (2009). Idrogeologia della media valle del fiume velino e della piana di s. Vittorino (Rieti, Italia centrale) / hydrogeology of the middle valley of the velino river and of the s. Vittorino plain (Rieti, Central Italy). Ital. J. Eng. Geol. Environ., 157–181.
40. The San Vittorino Sinkhole Plain: Relationships between bedrock structure, sinking processes, seismic events and hydrothermal springs
41. A new Italian carbonatite occurrence at Cupaello (Rieti) and its genetic significance10.1007/s004100050127 ↗
42. Peccerillo, A. (2005). Plio-Quaternary Volcanism in Italy, Springer.
43. Groundwater mixing in the discharge area of San Vittorino Plain (Central Italy): Geochemical characterization and implication for drinking uses10.1007/s12665-017-6719-1 ↗
44. A proposal for the kinematic modelling of W-dipping subductions—possible applications to the Tyrrhenian-Apennines system10.1111/j.1365-3121.1991.tb00172.x ↗
45. Geology of the southern Apennines
46. Slab bending, syn-subduction normal faulting, and out-of-sequence thrusting in the Central Apennines: Effects of slab bending in the Apennines10.1002/2013TC003386 ↗
47. Tettonica e sedimentazione (Lias-Pleistocene) nella media Valle del Salto (Rieti, Italia Centrale)
48. From Mesozoic rifting to Apennine orogeny: The Gran Sasso range (Italy)10.1016/j.gr.2014.09.009 ↗
49. From a deformed Peri-Tethyan carbonate platform to a fold-and-thrust-belt: An example from the Central Apennines (Italy)10.1016/j.jsg.2004.10.005 ↗
50. Deiana, G., Pasqualini, L., Salvucci, R., Stroppa, P., and Tondi, E. (1995). Il sistema dei sovrascorrimenti dei Monti Reatini: Analisi geometrica e cinematica. Stud. Geol. Camerti, 199–206.
51. A new view of Italian seismicity using 20 years of instrumental recordings10.1016/j.tecto.2004.09.013 ↗
52. Complete seismic release of tectonic strain and earthquake recurrence in the Apennines (Italy)10.1002/2014GL059230 ↗
53. Extensional basins in the tectonically bimodal central Apennines fold-thrust belt, Italy: Response to corner flow above a subducting slab in retrograde motion10.1130/0091-7613(1999)027<0955:EBITTB>2.3.CO;2 ↗
54. Centamore, E., Nisio, S., and Rossi, D. (2004, January 20–21). Aspetti geologico-strutturali in relazione alla formazione della ‘sinkhole plain’ di S. Vittorino. Proceedings of the State of the Art on the Study of Sinkhole Phenomena and Role of the National and Local Government in the Territory Administration, Rome, Italy.
55. I terrazzi della medio-bassa Valle del Fiume Velino
56. The jurassic-lower pliocene history of the Ancona-Anzio Line (Central Italy)
57. Structural inheritance in mountain belts: An Alpine–Apennine perspective10.1016/j.jsg.2006.09.006 ↗
58. Pre-existing cross-structures and active fault segmentation in the northern-central Apennines (Italy)10.1016/j.tecto.2009.03.018 ↗
59. Il ruolo dei sollevamenti tettonici a largo raggio nella genesi del rilievo appenninico
60. Tectonic setting and Sinkhole Features: Case histories from western Central Italy
61. Effects of uplift and tilting in the Central-Northern Apennines (Italy)10.1016/S1040-6182(02)00092-7 ↗
62. Interactions between mantle upwelling, drainage evolution and active normal faulting: An example from the central Apennines (Italy)10.1046/j.1365-246X.2001.00539.x ↗
63. Long-term trend and fluctuations of karst spring discharge in a Mediterranean area (central-southern Italy)10.1007/s12665-014-3946-6 ↗
64. Sorgenti lineari e valutazione dell’infiltrazione efficace in alcuni bacini dell’Italia Centrale
65. Advective heat transport associated with regional Earth degassing in central Apennine (Italy)10.1016/j.epsl.2013.04.009 ↗
66. Near-surface gas geochemistry techniques to assess and monitor CO2 geological sequestration sites10.1007/1-4020-4471-2_13 ↗
67. Development of collapse sinkholes in areas of groundwater discharge10.1016/S0022-1694(02)00062-8 ↗
68. Annunziatellis, A., Beaubien, S.E., Ciotoli, G., Lombardi, S., Nisio, S., and Nolasco, F. (2004, January 20–21). Studio dei parametri geologici e geochimici per la comprensione dei meccanismi genetici degli sprofondamenti nella piana di S. Vittorino (Rieti). Proceedings of the State of the Art on the Study of Sinkhole Phenomena and Role of the National and Local Government in the Territory Administration, Rome, Italy.
69. American Public Health Association, American Water Works Association, and Water Environment Federation (2017). Standard Methods for the Examination of Water and Wasterwater, American Public Health Association. [23rd ed.].
70. Application of boron and tritium isotopes for tracing landfill contamination in groundwater10.1016/j.gexplo.2016.10.011 ↗
71. Variation of O18 content of waters from natural sources10.1016/0016-7037(53)90051-9 ↗
72. On-line technique for preparing and measuring stable carbon isotope of total dissolved inorganic carbon in water samples (d13CTDIC)
73. Outgassing of Mantle Volatiles in Compressional Tectonic Regime Away From Volcanism: The Role of Continental Delamination10.1029/2018GC008046 ↗
74. A simple method for the determination of dissolved gases in natural waters. An application to thermal waters from Vulcano Island10.1016/S0883-2927(97)00109-1 ↗
75. Parkhurst, D.L., and Appelo, C.A.J. (2020, April 10). Description of Input and Examples for PHREEQC Version 3—A Computer Program for Speciation, Batch-Reaction, One-Dimensional Transport, and Inverse Geochemical Calculations, (USGS), Available online: https://pubs.usgs.gov/tm/06/a43/.
76. Bethke, C. (2008). Geochemical and Biogeochemical Reaction Modeling, Oxford University Press. [2nd ed.].10.1017/CBO9780511619670 ↗
77. Rate of diffuse carbon dioxide Earth degassing estimated from carbon balance of regional aquifers: The case of central Apennine, Italy10.1029/1999JB900355 ↗
78. An interactive code (NETPATH) for modeling net geochemical reactions along a flow path, version 2.0
79. Parkhurst, D.L., and Charlton, S.R. (2008). NetpathXL—An Excel Interface to the Program NETPATH, U.S. Geological Survey Techniques and Methods 6–A26.10.3133/tm6A26 ↗
80. Seismic signature of active intrusions in mountain chains10.1126/sciadv.1701825 ↗
81. Measuring and interpreting CO 2 fluxes at regional scale: The case of the Apennines, Italy10.1144/jgs2017-169 ↗
82. Chemiostratigrafia e petrografia della formazione dolomitica triassica di Antrodoco (Rieti, Lazio settentrionale)
83. OriginLab (2018). Origin User Guide, OriginLab Corporation.
84. Capotorti, F., Fumanti, F., and Mariotti, G. (1996). Carta geologica del settore compreso tra il M. Nuria, il M. Gabbia e l’alta valle del F. Velino (Appennino Centrale)—scala 1: 50000. Stud. Geol. Camerti, Available online: http://193.204.8.201:8080/jspui/handle/1336/763.
85. A graphic procedure in the geochemical interpretation of water-analyses10.1029/TR025i006p00914 ↗
86. Ozima, M., and Podosek, F.A. (2002). Noble Gas Geochemistry, Cambridge University Press. [2nd ed.].10.1017/CBO9780511545986 ↗
87. An introductory note on statistical analysis of physio-chemical characteristics of natural waters. Application to some Central Apennines spring waters. Atti della Accademia Nazionale dei Lincei. Classe di Scienze Fisiche, Matematiche e Naturali
88. Governa, M.E., Masciocco, L., Riba, M., Zuppi, G.M., and Lombardi, S. (1989). Karst and geothermal water circulation in the Central Apennines (Italy). Isotope Techniques in the Study of the Hydrology of Fractured and Fissured Rocks, International Atomic Energy Agency.
89. The recharge-discharge process of the Peschiera spring system (central Italy)
90. Mechanisms of Earthquake-Induced Chemical and Fluid Transport to Carbonate Groundwater Springs After Earthquakes10.1029/2017WR022097 ↗
91. Multicomponent Geothermometry Applied to a Medium-low Enthalpy Carbonate-evaporite Geothermal Reservoir10.1016/j.egypro.2014.10.389 ↗
92. New geothermometers for carbonate—evaporite geothermal reservoirs10.1016/0375-6505(86)90030-1 ↗
93. Geothermometry on fluids circulating in a carbonate reservoir in north-central Italy10.1016/0377-0273(88)90020-0 ↗
94. Chemical geothermometry and geobarometry in hydrothermal aqueous solutions: A theoretical investigation based on a mineral-solution equilibrium model10.1016/0016-7037(91)90438-B ↗
95. Theoretical geothermometers and PCO2 indicators for aqueous solutions coming from hydrothermal systems of medium-low temperature hosted in carbonate-evaporite rocks. Application to the thermal springs of the Etruscan Swell, Italy10.1016/0883-2927(95)00006-6 ↗
96. Use of two new Na/Li geothermometric relationships for geothermal fluids in volcanic environments10.1016/j.chemgeo.2014.09.011 ↗
97. Ford, D., and Williams, P.W. (2007). Karst Hydrogeology and Geomorphology, John Wiley & Sons.10.1002/9781118684986 ↗
98. Hydrochemistry and multi-isotope study of the waters from Hanlé-Gaggadé grabens (Republic of Djibouti, East African Rift System): A low-enthalpy geothermal resource from a transboundary aquifer10.1016/j.geothermics.2020.101805 ↗
99. Low temperature geothermal systems in carbonate-evaporitic rocks: Mineral equilibria assumptions and geothermometrical calculations. Insights from the Arnedillo thermal waters (Spain)10.1016/j.scitotenv.2017.09.269 ↗
100. Franchini, S., Agostini, S., Barberio, M.D., Barbieri, M., Billi, A., Boschetti, T., Pennisi, M., and Petitta, M. (2020). HydroQuakes, central Apennines, Italy: Towards a hydrogeochemical monitoring network for seismic precursors and the hydro-seismo-sensitivity of boron. J. Hydrol., 125754.10.1016/j.jhydrol.2020.125754 ↗