journal article·2019-03-20Open access

Methods for Sampling Biogas and Biomethane on Adsorbent Tubes after Collection in Gas Bags

Karine Arrhenius, Andreas Fischer, Oliver Büker

Applied Sciences· Volume 9· Issue 6

Abstract

Biogas is a renewable energy source with many different production pathways and numerous excellent opportunities for use; for example, as vehicle fuel after upgrading (biomethane). Reliable analytical methodologies for assessing the quality of the gas are critical for ensuring that the gas can be used technically and safely. An essential part of any procedure aimed at determining the quality is the sampling and transfer to the laboratory. Sampling bags and sorbent tubes are widely used for collecting biogas. In this study, we have combined these two methods, i.e., sampling in a gas bag before subsequent sampling onto tubes in order to demonstrate that this alternative can help eliminate the disadvantages associated with the two methods whilst combining their advantages; with expected longer storage stability as well as easier sampling and transport. The results of the study show that two parameters need to be taken into account when transferring gas from a bag on to an adsorbent; the water content of the gas and the flow rate used during transfer of the gas on to the adsorbent.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Odor and Emission Control Technologies · Vehicle emissions and performance · Carbon Dioxide Capture Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

RISE Research Institutes of Sweden, 501 15 Borås, Sweden

Funding

VINNOVA

References (26)

Show source-provided references
1. House, D. (2010). The Complete Biogas Handbook, OCLC. Alternative House Information.
2. Aebiom (2010). A Biogas Road Map for Europe, European Biomass Association. Annual Report 2009.
3. Arrhenius, K., and Johansson, U. (2012). Characterization of Contaminations in Biogas before and after Upgrading to Vehicle Gas, SGC. SGC Report No. 246.
4. (2016). EN 16723-1:2016-Natural Gas and Biomethane for Use in Transport and Biomethane for Injection in the Natural Gas Network–Part 1: Specifications for Biomethane for Injection in the Natural Gas Network, DIN.
5. (2016). EN 16723-2:2017-Natural Gas and Biomethane for Use in Transport and Biomethane for Injection in the Natural Gas Network–Part 2: Automotive Fuels Specification, DIN.
6. Suitability of vessels and adsorbents for the short-term storage of biogas/biomethane for the determination of impurities–siloxanes, sulphur compounds, halogenated hydrocarbons, BTEX10.1016/j.biombioe.2017.06.025 ↗
7. Suitability of different containers for the sampling and storage of biogas and biomethane for the determination of trace-level impurities—A review10.1016/j.aca.2015.10.039 ↗
8. Polman, E.A., Top, H., Gerritsen, B., and Rekers, A. (2015). Development of Existing and New Measurement Technologies for Determination of the Gas Composition, Energy Delta Gas Research (EDGaR). EDGaR project number 100201910, GT15-0029.
9. Suitability of Tedlar gas sampling bags for siloxane quantification in landfill gas10.1016/j.talanta.2010.04.001 ↗
10. Comparison between sampling and analytical methods in characterization of pollutants in biogas10.1016/j.talanta.2012.07.074 ↗
11. Development of on-line measurement techniques for siloxanes and other trace compounds in biogas10.1016/j.wasman.2009.11.030 ↗
12. Ghosh, A., Seeley, S.K., Nartker, S.R., and Seeley, J.V. (2014). Analysis of siloxanes in hydrocarbon mixtures using comprehensive two-dimensional gas chromatography. J. Chromatogr. A, 1360.10.1016/j.chroma.2014.07.062 ↗
13. Narros, A., Del Peso, M.I., Mele, G., Vinot, M., Fernandez, E., and Rodriguez, M.E. (2009). Determination of siloxanes in landfill gas by adsorption on Tenax tubes and TD-GCMS. Sardinia 2009, Proceedings of the 12th International Waste Management and Landfill Symposium, S. Margherita di Pula, Cagliari, Italy, 5–9 October 2009, CISA Publisher.
14. Trace compounds of biogas from different biogas production plants10.1016/j.energy.2006.10.018 ↗
15. Quantitative Analysis of volatile methylsiloxanes in waste-to energy landfill biogases using Direct APCI-MS/MS10.1021/es902741k ↗
16. Development of measurement techniques for determination main and hazardous components in biogas utilized for energy purposes10.1016/j.enconman.2013.01.011 ↗
17. The effects of adsorption on the reusability of Tedlar Air sampling bags
18. Rasi, S., Lehtinen, J., and Rintala, J. (2010). Determination of organic silicon compounds in biogas from wastewater treatments plants, landfills, and co-digestion plants. Renew. Energy, 35.10.1016/j.renene.2010.04.012 ↗
19. Determination of siloxanes by solid-phase adsorption on activated carbon10.5012/bkcs.2013.34.8.2353 ↗
20. Raich-Montiu, J., Ribas-Font, C., de Arespacochaga, N., Roig-Torres, E., Broto-Puig, F., Crest, M., Bouchy, L., and Cortina, J.L. (2014). Analytical methodology for sampling and analysing eight siloxanes and trimethylsilanol in biogas from different wastewater treatment plants in Europe. Anal. Chim. Acta, 812.10.1016/j.aca.2013.12.027 ↗
21. Evaluation of adsorbents for volatile methyl siloxanes sampling based on the determination of their breakthrough volume10.1016/j.talanta.2013.06.045 ↗
22. Collection and analysis of trace organic vapour pollutants in ambient atmospheres. The performance of Tenax-GC adsorbent tube10.1016/S0021-9673(00)89698-3 ↗
23. (1990). MDHS 40(rev) Toluene in—Laboratory Method Using Pumped Porous Polymer Adsorbent Tubes, Thermal Desorption and Gas Chromatography, HIS Inc.
24. Calculation of Flame Ionization Detector Relative Response factors using the Effective Carbon Number Concept10.1093/chromsci/23.8.333 ↗
25. Stabilities of 58 volatile organic compounds in fused-silica-lined and SUMA polished canisters under various humidified conditions10.1039/b209210g ↗
26. Stability of trace-level volatile organic compounds stored in canisters and Tedlar Bags10.4209/aaqr.2003.06.0003 ↗