journal article·2020-07-30Open access

Nonlinear TeraHertz Transmission by Liquid Water at 1 THz

Fabio Novelli, Chun Yu Ma, Nidhi Adhlakha, Ellen M. Adams, Thorsten Ockelmann, Debasish Das Mahanta, Paola Di Pietro, Andrea Perucchi, Martina Havenith

Applied Sciences· Volume 10· Issue 15

Abstract

The solvation properties of liquid water originate from the transient network of hydrogen-bonded molecules. In order to probe the coupling between the different modes of this network, nonlinear terahertz (THz) spectroscopy techniques are required. Ideally, these techniques should use a minimal volume and capitalize on sensitive field-resolved detection. Here we performed open aperture z-scan transmission experiments on static liquid cells, and detect the THz fields with electro-optical techniques. We show that it is possible to quantify the nonlinear response of liquid water at ~1 THz even when large signals originate from the sample holder windows.
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Research context

OpenAlex topics: Spectroscopy and Quantum Chemical Studies · Terahertz technology and applications · Spectroscopy and Laser Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Physical Chemistry II, Ruhr University Bochum, 44801 Bochum, Germany

Elettra-Sincrotrone Trieste S.C.p.A, S.S.14 km 163.5, Basovizza, 34149 Trieste, Italy

Funding

European Research Council · Deutsche Forschungsgemeinschaft

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