journal article·2025-08-29Open access

Enhancement of Mechanical Properties and Hydrogen Embrittlement Resistance of Laser-Directed Energy Deposition-Fabricated 316L Stainless Steel by Laser Shock Peening

Jeonghong Ha

Applied Sciences· Volume 15· Issue 17

Abstract

316L stainless steel offers attractive characteristics for hydrogen applications, including low hydrogen diffusivity and high hydrogen solubility. However, its use is limited by relatively low strength and resistance to hydrogen embrittlement (HE) under prolonged hydrogen exposure. Laser-directed energy deposition (L-DED) can not only increase the strength of 316L, but also induce significant tensile residual stresses that promote HE. In this study, 316L stainless steel samples produced by L-DED were post-processed by laser shock peening (LSP) to release the tensile residual stresses and refine the near-surface microstructure. LSP-treated samples showed refined grains, higher hardness, and the introduction of compressive residual stress, which led to improved tensile performance in hydrogen. Notably, after seven passes of LSP, the HE index (reduction in elongation due to hydrogen) was 12.5%, compared with 36.1% for the unpeened material. These results demonstrate that LSP is an effective approach to simultaneously increase strength and significantly improve HE resistance in additively manufactured 316L stainless steel.
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Research context

OpenAlex topics: Surface Treatment and Residual Stress · Additive Manufacturing Materials and Processes · High Entropy Alloys Studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Smart Forming Process Group, Korea Institute of Industrial Technology (KITECH), Ulsan 44776, Republic of Korea

Funding

Ministry of Science and ICT · Commercialization Promotion Agency for R&D Outcomes (COMPA) · Korea Evaluation Institute of Industrial Technology · Korean government (MOTIE) · Korea Institute of Industrial Technology

References (63)

Show source-provided references
1. Hydrogen storage: Materials, methods and perspectives10.1016/j.rser.2015.05.011 ↗
2. Hydrogen embrittlement characteristics of tempered martensitic steels under electrochemical and high-pressure hydrogen environments10.3365/KJMM.2023.61.11.807 ↗
3. Effect of nb addition and pre-strain on hydrogen embrittlement of low-carbon steels with ferrite-pearlite structure10.3365/KJMM.2020.58.11.752 ↗
4. Srinivasan, S., Demirocak, D.E., Kaushik, A., Sharma, M., Chaudhary, G.R., Hickman, N., and Stefanakos, E. (2020). Reversible hydrogen storage using nanocomposites. Appl. Sci., 10.10.3390/app10134618 ↗
5. Abreu Araujo, L., Rebolledo Ramos, N., Torres Martín, J.E., Chinchón-Payá, S., Sánchez Montero, J., Lample Carreras, R.M., Vera-Agullo, J., and Jimenez-Vicaria, J.D. (2024). Concrete gas permeability: Implications for hydrogen storage applications. Appl. Sci., 14.10.3390/app14156408 ↗
6. Reda, R., Ataya, S., Ayman, M., Saad, K., Mostafa, S., Elnady, G., Khan, R., and Elshaghoul, Y.G. (2025). Additively manufactured 316L stainless steel: Hydrogen embrittlement susceptibility and electrochemical gas production. Appl. Sci., 15.10.3390/app15115824 ↗
7. Hydrogen embrittlement of steels10.1146/annurev.ms.08.080178.001551 ↗
8. Hydrogen embrittlement understood10.1007/s11661-015-2836-1 ↗
9. Hydrogen embrittlement of additively manufactured austenitic stainless steel 316 L10.1016/j.corsci.2021.109790 ↗
10. Mechanistic and fractographic aspects of stress corrosion cracking10.1515/corrrev-2012-0501 ↗
11. On the formation and nature of quasi-cleavage fracture surfaces in hydrogen embrittled steels10.1016/j.actamat.2010.11.024 ↗
12. Hydrogen effect against hydrogen embrittlement10.1007/s11661-010-0275-6 ↗
13. Hydrogen embrittlement in different materials: A review10.1016/j.ijhydene.2018.09.201 ↗
14. Effect of additive manufacturing and subsequent heat and/or surface treatment on the hydrogen embrittlement sensitivity of 316L austenitic stainless steel10.1016/j.ijhydene.2023.05.215 ↗
15. Formation of strain-induced martensite in selective laser melting austenitic stainless steel10.1016/j.msea.2018.10.121 ↗
16. Dynamic mechanical properties of 316L stainless steel fabricated by an additive manufacturing process10.1016/j.jmrt.2020.12.097 ↗
17. 316L stainless steel mechanical and tribological behavior—A comparison between selective laser melting, hot pressing and conventional casting
18. Additive manufacturing of multi-scale heterostructured high-strength steels10.1080/21663831.2021.1904299 ↗
19. Laser shock peening of laser based directed energy deposition and powder bed fusion additively manufactured parts: A review10.1007/s12540-022-01334-1 ↗
20. On the effect of the thermal cycle during the directed energy deposition application to the in-situ production of a ti-mo alloy functionally graded structure
21. Effects of laser peening on tensile properties and martensitic transformation of aisi 316L stainless steel in a hydrogen-rich environment10.1016/j.msea.2020.139543 ↗
22. Structural components manufactured by selective laser melting and investment casting—Impact of the process route on the damage mechanism under cyclic loading10.1016/j.jmatprotec.2017.04.026 ↗
23. Improving the surface quality and mechanical properties by shot-peening of 17-4 stainless steel fabricated by additive manufacturing10.1016/j.matdes.2016.08.037 ↗
24. Effect of combined treatment of laser shock peening and shot peening on fatigue performance of laser-powder-bed-fusioned gh4169 nickel-based alloy10.1016/j.optlastec.2024.112141 ↗
25. Investigation on mechanical properties and surface strengthening mechanism of the cemented carbide processed by laser shock peening10.1016/j.jmrt.2025.01.188 ↗
26. Effect of shot peening on hydrogen embrittlement of high strength steel10.1007/s12613-016-1279-z ↗
27. Influence of cold deformation and annealing on hydrogen embrittlement of cold hardening bainitic steel for high strength bolts10.1016/j.msea.2016.03.104 ↗
28. Effect of hot isostatic pressing (hip) on microstructure and mechanical properties of ti6al4v alloy fabricated by cold spray additive manufacturing
29. Hydrogen embrittlement susceptibility of additively manufactured 316L stainless steel: Influence of post-processing, printing direction, temperature and pre-straining
30. Numerical analysis of hydrogen transport into a steel after shot peening10.1016/j.rinp.2018.08.030 ↗
31. Characterization of fatigue crack of hydrogen-charged austenitic stainless steel by electromagnetic and ultrasonic techniques10.1016/j.ijhydene.2022.07.105 ↗
32. Surface modifications induced in 316L steel by laser peening and shot-peening. Influence on pitting corrosion resistance10.1016/S0921-5093(99)00698-X ↗
33. Effect of hydrogen embrittlement on mechanical characteristics of dlc-coating for hydrogen valves of fcevs10.1038/s41529-024-00460-y ↗
34. Influence of laser peening on the hydrogen embrittlement resistance of 316L stainless steel10.1016/j.surfcoat.2017.08.037 ↗
35. Dynamic response and residual stress fields of ti6al4v alloy under shock wave induced by laser shock peening10.1088/1361-651X/aa7a46 ↗
36. Laser shock processing of aluminium alloys. Application to high cycle fatigue behaviour10.1016/0921-5093(95)10084-9 ↗
37. Microstructure and residual stress modulation of 7075 aluminum alloy for improving fatigue performance by laser shock peening10.1016/j.ijmachtools.2022.103979 ↗
38. Physical study of laser-produced plasma in confined geometry10.1063/1.346783 ↗
39. Effects of scanning path and overlapping rate on residual stress of 316L stainless steel blade subjected to massive laser shock peening treatment with square spots10.1016/j.apsusc.2019.03.093 ↗
40. Laser-shock processing of aluminium-coated 55c1 steel in water-confinement regime, characterization and application to high-cycle fatigue behaviour10.1023/A:1004331205389 ↗
41. Shock waves from a water-confined laser-generated plasma10.1063/1.366113 ↗
42. Li, Y., Li, Y., Wang, X., Xu, W., Qiao, F., and Wang, S. (2017, January 6–12). Effect of nanosecond pulse laser shock peening on the microstructure and performance of welded joint of 316L stainless steel. Proceedings of the Chinese Materials Conference, Yinchuan, China.10.1007/978-981-13-0107-0_11 ↗
43. Evaluation of laser shock peening process parameters incorporating almen strip deflections10.1016/j.surfcoat.2022.128158 ↗
44. On the evolution of microstructure and defect control in 316L ss components fabricated via directed energy deposition10.1016/j.msea.2019.138243 ↗
45. Cyclic creep process in aisi 316L stainless steel in terms of dislocation patterns and internal stresses10.1016/j.actamat.2004.03.011 ↗
46. On the origin of the tensile flow stress in the stainless steel aisi 316L at 300 k: Back stress and effective stress10.1016/S1359-6454(99)00222-0 ↗
47. Correlation between processing parameters and strain-induced martensitic transformation in cold worked aisi 301 stainless steel10.1016/j.matchar.2008.03.004 ↗
48. Effects of alloy composition and strain hardening on tensile fracture of hydrogen-precharged type 316 stainless steels10.1016/j.ijhydene.2007.10.046 ↗
49. Temperature and residual stress distribution of fgm parts by ded process: Modeling and experimental validation10.1007/s00170-020-05673-4 ↗
50. Effects of residual stress on orientation dependent fatigue crack growth rates in additively manufactured stainless steel10.1016/j.ijfatigue.2022.107489 ↗
51. Correlation between full width at half maximum (fwhm) of xrd peak with residual stress on ground surfaces10.1080/14786435.2012.704429 ↗
52. Effect of shot peening coverage on hardness, residual stress and surface morphology of carburized rollers10.1016/j.surfcoat.2019.125273 ↗
53. Influence of process parameters of ultrasonic shot peening on surface nanocrystallization and hardness of pure titanium10.1007/s00170-016-9181-4 ↗
54. Assessment of surface hardening effects from shot peening on a ni-based alloy using electron backscatter diffraction techniques10.1016/j.actamat.2011.04.025 ↗
55. Investigation on the effect of shot peening coverage on the surface integrity10.1016/j.apsusc.2019.05.281 ↗
56. Effect of strain-induced martensite on the formation of nanocrystalline 316L stainless steel after cold rolling and annealing10.1016/j.msea.2009.04.038 ↗
57. Alam, M.T., Ahmad, T., Alshoaibi, A.M., Aziz, A., Husain, D., and Ahmad, S. (2024). Comprehensive study on the properties of az91/x-si3n4 composites for their prospective application. Appl. Sci., 14.10.3390/app14114444 ↗
58. Effect of hydrogen charging on mechanical twinning, strain hardening, and fracture of ‹111› and ‹144› hadfield steel single crystals10.1134/S1029959918030116 ↗
59. Hydrogen-induced softening and embrittlement in 316L stainless steel fabricated using laser-powder bed fusion10.1016/j.actamat.2024.119959 ↗
60. Improvement of hydrogen embrittlement resistance of 2205 duplex stainless steel by laser peening10.1016/j.ijhydene.2023.01.354 ↗
61. Hydrogen-assisted failure in a twinning-induced plasticity steel studied under in situ hydrogen charging by electron channeling contrast imaging10.1016/j.actamat.2013.04.030 ↗
62. Permeability, solubility and diffusivity of hydrogen isotopes in stainless steels at high gas pressures10.1016/j.ijhydene.2006.05.008 ↗
63. Effects of hydrogen on tensile properties and fracture surface morphologies of type 316L stainless steel10.1016/j.ijhydene.2013.12.099 ↗