journal article·2023-03

Thermomigration suppression in Sn3.5Ag solder joints by hot-end FeCoNiMn alloy

Yu-An Shen, Yun-Xuan Lin, Fan-Yi Ouyang, Hiroshi Nishikawa, Ming-Hung Tsai

Intermetallics· Volume 154
Publisher page

Abstract

Temperature gradient is inevitable in solder joints in advanced electronic packaging; it induces thermomigration (TM), critically affecting the reliability of micro solder joints. Although a FeCoNiMn alloy (FCNM) can resist thermal aging in solder joints, its TM resistance has seldom been examined. Thus, this study investigated the TM in Cu/Sn3.5Ag (SA3.5)/FCNM solder joints between a cold end (50 °C) and a hot end (200 °C) at different times. A multielement intermetallic compound (MEIMC), (Cu, Mn, Fe, Co, Ni) 6Sn 5, is formed at the SA3.5/FCNM interface in the reflowed and aged solder joints. A (Fe, Co, Ni, Mn)Sn 2 MEIMC also formed, but it was very thin. The (Cu, Mn, Fe, Co, Ni) 6Sn 5 was completely decomposed by TM from the hot-end FCNM. In contrast, the (Cu, Mn, Fe, Co, Ni) 6Sn 5 MEIMC thickened as the rapid TM flux of Cu from the hot-end Cu cap; however, the low chemical flux from FCNM hindered its formation, which was replaced by Cu 6Sn 5 formation near the Cu/SA3.5 interface. The findings demonstrate that FCNM providing a very low chemical flux is a remarkably promising diffusion barrier for TM in micro solder joints.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Electronic Packaging and Soldering Technologies · Intermetallics and Advanced Alloy Properties · High Temperature Alloys and Creep

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (40)

Show source-provided references
1. Thermomigration and electromigration in Sn58Bi solder joints10.1063/1.3125458 ↗
2. Thermomigration in solder joints10.1016/j.mser.2012.11.001 ↗
3. Effects of Ni modified MWCNTs on the microstructural evolution and shear strength of Sn-3.0Ag-0.5Cu composite solder joints10.1016/j.matchar.2020.110287 ↗
4. Effect of Co addition into Ni film on shear strength of solder/Ni/Cu system: experimental and theoretical investigations10.1016/j.msea.2020.139589 ↗
5. Influences of mono-Ni(P) and dual-Cu/Ni(P) plating on the interfacial microstructure evolution of solder joints10.1007/s11661-018-4983-7 ↗
6. Quasi-in-situ observation on diffusion anisotropy dominated asymmetrical growth of Cu-Sn IMCs under temperature gradient10.1016/j.actamat.2021.117168 ↗
7. The effect of temperature gradient on interfacial Cu6Sn5 growth during thermal compression bonding
8. Full intermetallic joints for chip stacking by using thermal gradient bonding10.1016/j.actamat.2016.04.046 ↗
9. Tailoring magnetic behavior of CoFeMnNiX (X = Al, Cr, Ga, and Sn) high entropy alloys by metal doping10.1016/j.actamat.2017.03.013 ↗
10. Influence of thermomigration on lead-free solder joint mechanical properties10.1115/1.3068296 ↗
11. Determination of solid–liquid interfacial energy of Ni3Sn2 phase by grain boundary groove method in a temperature gradient10.1016/j.jallcom.2018.12.301 ↗
12. Effects of Sn grain orientation on substrate dissolution and intermetallic precipitation in solder joints under electron current stressing10.1016/j.scriptamat.2014.02.010 ↗
13. Effect of Sn grain orientation on reliability issues of Sn-rich solder joints10.3390/ma15145086 ↗
14. 3D integration technologies: an overview
15. Reliability challenges in 3D IC packaging technology10.1016/j.microrel.2010.09.031 ↗
16. Asymmetrical precipitation of Ag3Sn intermetallic compounds induced by thermomigration of Ag in Pb-free microbumps during solid-state aging10.1007/s11664-015-3983-2 ↗
17. Interfacial reaction issues for lead-free electronic solders
18. Effects of graphene nanosheets on interfacial reaction of Sn–Ag–Cu solder joints10.1016/j.jallcom.2015.08.018 ↗
19. Improvement of thermomigration resistance in lead-free Sn3.5Ag alloys by Ag interlayer10.1016/j.jallcom.2020.156429 ↗
20. Suppressed growth of (Fe, Cr, Co, Ni, Cu)Sn2 intermetallic compound at interface between Sn-3.0Ag-0.5Cu solder and FeCoNiCrCu0.5 substrate during solid-state aging10.1038/s41598-019-46757-w ↗
21. Effect of Cu on the interfacial reaction between Sn-based solders and FeCoNiCu alloys10.1016/j.intermet.2022.107530 ↗
22. Growth of the nano-phase intermetallic compounds and its effect on mechanical behavior of Au80Sn20/CrMnFeCoNi solder joints during isothermal aging
23. Extremely thin interlayer of multi-element intermetallic compound between Sn-based solders and FeCoNiMn high-entropy alloy10.1016/j.apsusc.2021.149945 ↗
24. Effects of the replacement of Co with Ni on the microstructure, mechanical properties, and age hardening of AlCo1−xCrFeNi1+x high-entropy alloys10.3390/ma14102665 ↗
25. On the phase constituents of four CoCrFeNiX (X = Y, Ti, Zr, Hf) high-entropy alloys after prolonged annealing10.1016/j.jmrt.2020.07.056 ↗
26. High-entropy alloys10.1038/s41578-019-0121-4 ↗
27. Alloy design strategies and future trends in high-entropy alloys
28. Shear strength and fracture behavior of locally-melted hybrid Cu/Sn3.0Ag0.5Cu/Sn58Bi/Cu joints under different loading rates
29. Effects of crystalline and amorphous Pd layers on initial interfacial reactions at Sn-3.0Ag-0.5Cu/thin-Au/Pd/Ni(P) solder joints10.1016/j.apsusc.2019.144339 ↗
30. The effect of stress migration on electromigration in dual damascene copper interconnects10.1063/1.3531393 ↗
31. Microstructure and grain orientation evolution in SnPb/SnAgCu interconnects under electrical current stressing at cryogenic temperature10.3390/ma12101593 ↗
32. Effect of Sn grain orientation on growth of Cu-Sn intermetallic compounds during thermomigration in Cu-Sn2.3Ag-Ni microbumps10.1016/j.matlet.2018.10.112 ↗
33. Role of diffusion anisotropy in β-Sn in microstructural evolution of Sn-3.0Ag-0.5Cu flip chip bumps undergoing electromigration10.1016/j.actamat.2015.08.037 ↗
34. Microstructural study of interfacial reactions between liquid Sn and electroless Fe-Ni alloys10.1007/s11664-012-2199-y ↗
35. Growth of Cu-Zn5 and Cu5Zn8 intermetallic compounds in the Sn-9Zn/Cu joint during liquid state aging10.4028/www.scientific.net/AMR.173.90 ↗
36. Investigation of FeCoNiCu properties: thermal stability, corrosion behavior, wettability with Sn-3.0Ag-0.5Cu and interlayer formation of multi-element intermetallic compound10.1016/j.apsusc.2021.148931 ↗
37. Thermomigration in Co/SnAg/Co and Cu/SnAg/Co sandwich structure10.1016/j.microrel.2019.03.005 ↗
38. Thermomigration induced microstructure and property changes in Sn-58Bi solders10.1016/j.matdes.2019.107619 ↗
39. New challenges of miniaturization of electronic devices: electromigration and thermomigration in lead-free solder joints10.1016/j.matdes.2020.108726 ↗
40. Phase field simulation of microstructural evolution and thermomigration-induced phase segregation in Cu/Sn58Bi/Cu interconnects under isothermal aging and temperature gradient10.1016/j.microrel.2018.11.007 ↗