Physico-Chemical Compatibility of an Aqueous Colloidal Dispersion of Silica Nano-Particles as Binder for Chromatic Reintegration in Wall Paintings
Source abstract
Abstract
Paint loss is one of the main forms of deterioration in historical wall paintings, generally restored by the application of chromatic reintegration. In the specific case of outdoor exposed paintings, it is essential to find a binder that will withstand diverse weather conditions. Since chromatic reintegrations have to be compatible with the original painting, fresco paint mock-ups were manufactured and compared to chromatic reintegrations made with an aqueous colloidal dispersion of silica nanoparticles as binder. The physical compatibility was studied by colour spectrophotometry and measurements of static contact angle, gloss, and roughness values, together with a peeling test, stereomicroscopy, and polarised light microscopy. They were also characterised from a mineralogical, chemical, and molecular point of view using X-ray diffraction, X-ray fluorescence and Fourier-transform infrared spectroscopy. The microtexture was studied by scanning electron microscopy with energy-dispersive X-ray spectroscopy. Chromatic reintegrations showed similar roughness and lower gloss values than frescoes, and the nano-silica binder ensured the natural breathability of the wall. Overall, the chemical nature of pigments was highly influential. The reintegrations with silicate-based pigments were more homogenous, with hardly any fissures, while those carried out with sulphide- or oxide-based pigments were severely cracked. The use of verdigris is discouraged due to the lack of affinity between the binder and the pigment.
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Research context
OpenAlex topics: Building materials and conservation · Cultural Heritage Materials Analysis · Literature, Language, and Rhetoric Studies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
CINTECX, GESSMin Group, Department of Natural Resources and Environmental Engineering, Faculty of Mining and Energy Engineering, University of Vigo, 36310 Vigo, Spain
Department of Mineralogy and Petrology, Faculty of Science, University of Granada, 18071 Granada, Spain
Department of Painting, Faculty of Fine Arts, University of Granada, 18071 Granada, Spain
Funding
MICIU/AEI/10.13039/501100011033
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