Temperature Relaxation in Glass-Forming Materials under Local Fast Laser Excitations during Laser-Induced Microstructuring

The ability to control the temperature distribution T(t,r) and the rate of temperature change Rt,r inside glasses is important for their microstructuring. The lattice temperature is considered at time t, exceeding the electron–phonon thermalization time, and at a distance r from the center of the model spherical heating zone. In order to describe thermal excitations, the heat capacity of glasses must be considered as a function of time due to its long-term relaxation. A method for the analytical calculation of T(t,r) and R(t,r) for glasses with dynamic heat capacity cdyn(t) is proposed. It is shown that during laser microstructuring, the local cooling rate −R(t,r) significantly depends on the time dispersion of cdyn(t). It has been established that at the periphery of the model heating zone of the laser beam focus, the local cooling rate can reach more than 1011 K/s. Strong cooling rate gradients were found at the periphery of the heating zone, affecting the microstructure of the material. This effect is significantly enhanced by the time dispersion of cdyn(t). The effect associated with this time dispersion is significant, even well above the glass transition temperature Tg, since even short relaxation times of the dynamic heat capacity cdyn(t) are significant.