journal article·2025-10-12Open access

Rare Earth Elements: A Review of Primary Sources, Applications, Business Investment, and Characterization Techniques

Fabiano Ferreira de Medeiros, Alexandre Pereira Wentz, Beatriz Almeida Santos Castro, Fabricio Dias Rodrigues, Sara Silva Alves, Maria das Graças Andrade Korn, Jefferson Bettini, Jeancarlo Pereira dos Anjos, Lílian Lefol Nani Guarieiro

Applied Sciences· Volume 15· Issue 20

Abstract

Minerals bearing rare earth elements (REEs) are formed through long geological processes, among which monazite, bastnasite, xenotime, and ionic adsorption clays are the most economically exploited. Although Brazil has one of the largest reserves of REEs on the planet, its production is still not significant on the world stage. China remains dominant, with the largest reserves of REEs and controlling more than half of world production. Due to their important application in advanced clean and low-carbon energy technologies, REEs have become fundamental to the energy transition process. Technological applications related to catalyst synthesis, ceramics production, and metallurgy have been explored. Furthermore, the use of REEs in devices of great demand today, such as computer memory, rechargeable batteries, and mobile phones, has been cited. With the growing demand for these critical minerals, large mining companies are seeking to implement cleaner production policies in their processes and save natural resources to minimize the environmental impacts of the exploration. Robust analytical techniques have made it possible to characterize these elements in multi-element geological matrices, with the increasing exploration and identification of new REE mineral reserves.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Extraction and Separation Processes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Integrated Laboratory of Applied Research in Chemistry, SENAI CIMATEC University, 1845 Orlando Gomes Avenue, Piatã, Salvador 41650-010, BA, Brazil

Institute of Chemistry, Ondina Campus, Federal University of Bahia (UFBA), Salvador 40170-110, BA, Brazil

National Institute of Science and Technology in Energy and Environment (INCT E&A), Ondina Campus, Federal University of Bahia (UFBA), Salvador 40170-110, BA, Brazil

National Nanotechnology Laboratory (LNNano), Brazilian Center for Energy and Materials Research (CNPEM), 10000 Giuseppe Máximo Scolfaro Street, Bosque das Palmeiras, Campinas 13083-100, SP, Brazil

Funding

the National Council for Scientific and Technological Development

References (100+)

Show source-provided references
1. Patel, K.S., Sharma, S., Maity, J.P., Martín-Ramos, P., Fiket, Ž., Bhattacharya, P., and Zhu, Y. (2023). Occurrence of Uranium, Thorium and Rare Earth Elements in the Environment: A Review. Front. Environ. Sci., 10.10.3389/fenvs.2022.1058053 ↗
2. Rare Earth Elements Resources and Beneficiation: A Review10.1016/j.mineng.2024.109011 ↗
3. Jiang, Y., Li, J., Geng, Y., Ye, X., Ma, S., Hao, X., Xin, W., and Chai, Y. (J. Rare Earths, 2025). A Review of the Main Rare Earth Ore Smelting Processes in the World: From Traditional Methods to New Technologies, J. Rare Earths, In Press.10.1016/j.jre.2025.07.027 ↗
4. Zhang, J., Zhao, B., and Schreiner, B. (2016). Separation Hydrometallurgy of Rare Earth Elements, Springer International Publishing.10.1007/978-3-319-28235-0 ↗
5. Takehara, L., Shintaku, I., Rabelo, D.M., and Silveira, F.V. (2015). Avaliação do Potencial de Terras Raras no Brasil.
6. Mineral monazita, fonte de elementos terras raras, numa jazida importante da Paraíba
7. Selection of Extractant in Rare Earth Solvent Extraction System: A Review
8. A Comprehensive Review on Solvent Extraction Technologies of Rare Earth Elements from Different Acidic Media: Current Challenges and Future Perspectives10.1016/j.jiec.2024.04.042 ↗
9. Enhanced Solvent Extraction of Rare Earth Elements in Ultra-High Phase Ratio with Pore-Throat Microchannels10.1016/j.seppur.2024.128513 ↗
10. Predicting the Distribution Coefficient in the Solvent Extraction of Rare Earth Elements10.1016/j.seppur.2025.134382 ↗
11. Selection of a Hydrometallurgical Process for Rare Earths Extraction from a Brazilian Monazite10.1016/j.hydromet.2021.105556 ↗
12. Development of Solvent Extraction Methods for Recovering Rare Earth Metals10.1134/S004057951605002X ↗
13. Solvent Extraction of Rare-Earth Elements with Ionic Liquids: Toward a Selective and Sustainable Extraction of These Valuable Elements10.1016/j.cogsc.2020.100428 ↗
14. Effect of Polar Molecular Organic Solvents on Non-Aqueous Solvent Extraction of Rare-Earth Elements10.1016/j.seppur.2022.121197 ↗
15. Atanassova, M., Kukeva, R., and Kurteva, V. (2023). New Sustainable Solvent Extraction Pathways for Rare Earth Metals via Oximes Molecules. Molecules, 28.10.3390/molecules28227467 ↗
16. Selective Recovery of Rare Earth Elements from Acetic Leachate of NdFeB Magnet by Solvent Extraction10.1016/j.seppur.2024.126701 ↗
17. Delić, M., Ristić, M., Đolić, M., Perić-Grujić, A., and Onjia, A. (2025). Dispersive Liquid–Liquid Chelate Microextraction of Rare Earth Elements: Optimization and Greenness Evaluation. Metals, 15.10.3390/met15010052 ↗
18. Solvent Extraction Systems for Selective Isolation of Light Rare Earth Elements with High Selectivity for Sm and La10.1007/s12598-024-03019-7 ↗
19. U.S. Geological Survey (2023). Mineral Commodity Summaries 2023.
20. The Evolving Impact of Renewable Energy Investment on the Rare Earth Trade Network: An Industrial Chain Perspective10.1016/j.energy.2025.137195 ↗
21. Yuan, W., Wang, H., Sun, D., Yan, F., Liu, C., Zhang, X., and Dong, L. (2025). Analysis of Slope Stability in Ion-Adsorption Rare Earth Mine Under In Situ Leaching Condition. Appl. Sci., 15.10.3390/app15126677 ↗
22. Behrsing, T., Blair, V.L., Jaroschik, F., Deacon, G.B., and Junk, P.C. (2024). Rare Earths—The Answer to Everything. Molecules, 29.10.3390/molecules29030688 ↗
23. Keith, M., Hayes, S.M., Ciobanu, C.L., Fougerouse, D., and Reich, M. (2023). Editorial: Micro-to Nano-Analytical Challenges towards Trace Element Characterization of Ore Minerals: New Perspectives and Applications for Sustainable Georesources. Front. Earth Sci., 11.10.3389/feart.2023.1227737 ↗
24. From Mantle to Critical Zone: A Review of Large and Giant Sized Deposits of the Rare Earth Elements10.1016/j.gsf.2015.12.006 ↗
25. Martins, C., Lima, P.C.R., Teixeira, L.S., Teixeira, M.P., and de Queiroz Filho, A.P. (2014). Minerais Estratégicos e Terras-Raras, Edições Câmara.
26. Early-Stage Application of Process Mineralogy Methodologies for Mineral Tracking in Flotation of Rare Earth Elements (REE)-Bearing Minerals from a Deposit in Norway10.1016/j.mineng.2023.108268 ↗
27. Pathapati, S.V.S.H., Free, M.L., and Sarswat, P.K. (2023). A Comparative Study on Recent Developments for Individual Rare Earth Elements Separation. Processes, 11.10.3390/pr11072070 ↗
28. Julapong, P., Numprasanthai, A., Tangwattananukul, L., Juntarasakul, O., Srichonphaisarn, P., Aikawa, K., Park, I., Ito, M., Tabelin, C.B., and Phengsaart, T. (2023). Rare Earth Elements Recovery from Primary and Secondary Resources Using Flotation: A Systematic Review. Appl. Sci., 13.10.3390/app13148364 ↗
29. Ralph, J. (2023, September 13). Database of Minerals, Rocks, Meteorites and Their Locations. Available online: https://www.mindat.org/.
30. Thermodynamics of Bastnaesite: A Major Rare Earth Ore Mineral10.2138/am-2016-5565 ↗
31. Crystal Structures, Surface Stability, and Water Adsorption Energies of La-Bastnäsite via Density Functional Theory and Experimental Studies10.1021/acs.jpcc.6b04747 ↗
32. Rare Earth Element Concentrations in Brazilian Benchmark Soils
33. Global Rare Earth Elements Projects: New Developments and Supply Chains10.1016/j.oregeorev.2023.105428 ↗
34. Molecular-Level Understanding of Metal Ion Retention in Clay-Rich Materials10.1038/s43017-022-00301-z ↗
35. The Role of Clay Minerals in Formation of the Regolith-Hosted Heavy Rare Earth Element Deposits10.2138/am-2020-7061 ↗
36. Adsorption of Rare Earth Elements in Regolith-Hosted Clay Deposits10.1038/s41467-020-17801-5 ↗
37. A Green and Efficient Technology to Recover Rare Earth Elements from Weathering Crusts10.1038/s41893-022-00989-3 ↗
38. Rock-to-Metal Ratios of the Rare Earth Elements10.1016/j.jclepro.2023.136958 ↗
39. Identification and Recovery of Rare Earth Elements from Electronic Waste: Material Characterization and Recovery Strategies10.1016/j.mtcomm.2023.106921 ↗
40. The Recent Progress of Ion Exchange for the Separation of Rare Earths from Secondary Resources—A Review10.1016/j.hydromet.2023.106047 ↗
41. U.S. Geological Survey (2025). Mineral Commodity Sumaries 2025.
42. Rare Earths: Periodic Table, Discovery, Exploration in Brazil and Applications
43. (2023, September 03). Brasil Brasil Pode Se Tornar Um dos Cinco Maiores Produtores de Terras Raras do Mundo Nos Próximos Anos, Available online: https://www.gov.br/mme/pt-br/assuntos/noticias/brasil-pode-se-tornar-um-dos-cinco-maiores-produtores-de-terras-raras-do-mundo-nos-proximos-anos.
44. Global Rare Earth Element Resources: A Concise Review10.1016/j.apgeochem.2024.106158 ↗
45. Takehara, L., Silveira, F.V., and Santos, R.V. (2015). Potentiality of Rare Earth Elements in Brazil. Rare Earths Industry: Technological, Economic, and Environmental Implications, Elsevier Inc.10.1016/B978-0-12-802328-0.00004-8 ↗
46. Brasil (2019). Sumário Mineral 2017.
47. Brasil (2013). Sumário Mineral 2013.10.20336/rbs.184 ↗
48. Rare Earth Mining in Brazil: Building a Better Future
49. Critical Materials and Dissipative Losses: A Screening Study10.1016/j.scitotenv.2013.05.040 ↗
50. Challenges in Metal Recycling10.1126/science.1217501 ↗
51. Du, X., and Graedel, T.E. (2011). Uncovering the Global Life Cycles of the Rare Earth Elements. Sci. Rep., 1.10.1038/srep00145 ↗
52. Rare Earth Metals from Secondary Sources: Review of Potential Supply from Waste and Byproducts10.1016/j.resconrec.2020.105213 ↗
53. Forecasting Revenue from Primary and Secondary Sources of Rare Earth Elements10.1016/j.resconrec.2024.107612 ↗
54. Recycling Rare Earths: Perspectives and Recent Advances10.1557/s43577-022-00301-w ↗
55. Life Cycle Assessment and Circular Economy in the Production of Rare Earth Magnets: An Updated and Comprehensive Review10.1007/s10098-024-02935-7 ↗
56. Rare Earth Elements: Overview of Mining, Mineralogy, Uses, Sustainability and Environmental Impact10.3390/resources3040614 ↗
57. Assessing Rare Earth Element Mineral Deposit Types and Links to Environmental Impacts10.1179/1743275813Y.0000000036 ↗
58. Nassar, N.T., and Fortier, S.M. (2021). Methodology and Technical Input for the 2021 Review and Revision of the U.S. Critical Minerals List.10.3133/ofr20211045 ↗
59. Rare Earth Elements: A Review of Applications, Occurrence, Exploration, Analysis, Recycling, and Environmental Impact10.1016/j.gsf.2018.12.005 ↗
60. Review on Progress of Rare Earth Science and Technology in 202410.1016/j.jre.2025.08.003 ↗
61. A Comparative State-of-Technology Review and Future Directions for Rare Earth Element Separation10.1016/j.rser.2021.110917 ↗
62. Nemova, G. (2024). Brief Review of Recent Developments in Fiber Lasers. Appl. Sci., 14.10.3390/app14062323 ↗
63. Development Status of Rare Earth Luminescence Material10.1016/j.jallcom.2025.182399 ↗
64. Magnesium Alloys with Rare-Earth Elements: Research Trends Applications, and Future Prospect10.1016/j.jma.2025.07.012 ↗
65. Ren, Z., Yu, H., Tong, X., Zhang, J., Wang, Y., Xu, S., Li, X., and Chen, B. (2025). Blue Light-Excited Zero-Thermal-Quenching near-Infrared Garnet CaY2Sc2Al2SiO12:Cr3+/Yb3+ Phosphors for Pc-LED Application. Spectrochim. Acta A Mol. Biomol. Spectrosc., 343.10.1016/j.saa.2025.126581 ↗
66. Regulating the Broadband Near-Infrared Emission of Eu2+-Doped Ca3Sc2Si3O12 Phosphors through Constructing Defect for Diversified Applications10.1016/j.cej.2024.154360 ↗
67. Pioneering Sustainable Energy Solutions with Rare-Earth Nanomaterials: Exploring Pathways for Energy Conversion and Storage10.1016/j.ijhydene.2024.10.299 ↗
68. Recent Advances in Rare Earth Oxides Applied to Energy Conversion: A Short Review10.1016/j.ceramint.2024.12.021 ↗
69. Organic-Inorganic Upconversion Nanoparticles Hybrid in Dye-Sensitized Solar Cells10.1016/j.ccr.2021.213805 ↗
70. Peelman, S., Sun, Z.H.I., Sietsma, J., and Yang, Y. (2016). Leaching of Rare Earth Elements: Review of Past and Present Technologies. Rare Earths Industry, Elsevier.10.1016/B978-0-12-802328-0.00021-8 ↗
71. Shayan, M.E., Najafi, G., Ghobadian, B., Gorjian, S., Mazlan, M., Samami, M., and Shabanzadeh, A. (2022). Flexible Photovoltaic System on Non-Conventional Surfaces: A Techno-Economic Analysis. Sustainability, 14.10.3390/su14063566 ↗
72. The Role and Challenges of Rare Earths in the Energy Transition10.1016/j.resourpol.2023.104137 ↗
73. Hydrogen and Value-Added Products Yield from Hybrid Water Electrolysis: A Critical Review on Recent Developments10.1016/j.rser.2023.113227 ↗
74. Technological Perspectives and Economic Aspects of Green Hydrogen in the Energetic Transition: Challenges for Chemistry
75. Revolutionizing Water Splitting: The Role of Light Rare Earth Elements (LREEs) in Photoelectrochemical and Electrochemical Advances10.1016/j.ccr.2025.216917 ↗
76. Leveraging Heavy Rare Earth Elements (H-REEs) in Electrodes to Boost the Efficiency of Photoelectrochemical and Electrochemical Water Splitting10.1016/j.ijhydene.2025.151569 ↗
77. Review of the Research on Oxides in Low-Temperature Magnetic Refrigeration10.1016/j.jeurceramsoc.2023.07.063 ↗
78. High-Throughput Search for Caloric Materials: The CaloriCool Approach10.1088/1361-6463/aa9bd0 ↗
79. Field-Induced Slow Magnetic Relaxation and Magnetocaloric Effects in an Oxalato-Bridged Gadolinium(iii)-Based 2D MOF10.1039/D1DT00462J ↗
80. Gd(iii)-Based Inorganic Polymers, Metal–Organic Frameworks and Coordination Polymers for Magnetic Refrigeration10.1039/D1CE01633D ↗
81. Highly Stable Rare Earth Metal-Organic Frameworks for Proton Conduction and Magnetic Refrigeration10.1016/j.molstruc.2024.139645 ↗
82. Effect of Cation Dopant Radius on the Hydrothermal Stability of Tetragonal Zirconia: Grain Boundary Segregation and Oxygen Vacancy Annihilation10.1016/j.actamat.2015.12.051 ↗
83. Rare Earth Doped Zirconia: Structure, Physicochemical Properties and Recent Advancements in Technological Applications10.1016/j.progsolidstchem.2025.100524 ↗
84. Unveiling the Effects of Rare-Earth Substitutions on the Structure, Mechanical, Optical, and Imaging Features of ZrO2 for Biomedical Applications10.1021/acsbiomaterials.8b01570 ↗
85. Rare-Earth-Doped Materials for Applications in Quantum Information Storage and Signal Processing10.1016/j.jlumin.2010.12.015 ↗
86. High-Resolution Laser Spectroscopy of Rare-Earth Doped Insulators: A Personal Perspective10.1016/S0022-2313(02)00450-7 ↗
87. Emerging Rare-Earth Doped Material Platforms for Quantum Nanophotonics10.1515/nanoph-2019-0185 ↗
88. Recent Advances in Rare Earth Doped Inorganic Crystalline Materials for Quantum Information Processing10.1002/zaac.201700425 ↗
89. High-Resolution Spectroscopic Techniques for Studying Rare-Earth Ions in Nanoparticles10.1016/j.jlumin.2023.119743 ↗
90. Ruskuc, A. (2024). Single Rare-Earth Ions in Solid-State Hosts: A Platform for Quantum Networks, California Institute of Technology (Caltech).
91. Multiplexed Entanglement of Multi-Emitter Quantum Network Nodes10.1038/s41586-024-08537-z ↗
92. Aharonovich, I., Soci, C., and Sheldon, M.T. (2024, January 18–23). Single Rare-Earth Ions Coupled to a Dense Nuclear Spin Bath: A Challenge and a Resource. Proceedings of the Quantum Nanophotonic Materials, Devices, and Systems, San Diego, CA, USA.
93. CRIRSCO (2019). Exploration Targets, Exploration Results, Mineral Resources and Mineral Reserves, ICMM. Available online: https://crirsco.com/wp-content/uploads/2023/10/The-CRIRSCO-International-Reporting-Template.pdf.
94. Monitoring the Effects of Open-Pit Mining on the Eco-Environment Using a Moving Window-Based Remote Sensing Ecological Index10.1007/s11356-020-08054-2 ↗
95. Recycling of the Rare Earth Elements10.1016/j.cogsc.2018.02.008 ↗
96. Yun, Y., Stopic, S., and Friedrich, B. (2020). Valorization of Rare Earth Elements from a Steenstrupine Concentrate Via a Combined Hydrometallurgical and Pyrometallurgical Method. Minerals, 10.10.3390/min10030248 ↗
97. China Northern Rare Earth Group High-Tech Co., Ltd (2023, October 22). About China Northern. Available online: https://www.reht.com/.
98. (2025, October 08). International Organization for Standardization ISO 9000 Family–Quality Management. Available online: https://www.iso.org/standards/popular/iso-9000-family.
99. (2025, October 08). International Organization for Standardization ISO 14000 Family–Environmental Management. Available online: https://www.iso.org/standards/popular/iso-14000-family.
100. China Rare Earth Resources and Technology Co., Ltd (2023, November 05). About China Rare Earth. Available online: http://www.cmreltd.com/index.html.