journal article·2025-07-01Open access

Formation Kinetics and Morphology Characteristics of Natural Gas Hydrates in Sandstone Fractures

Chaozheng Ma, Xiaoxu Hu, Hongxiang Si, Jiyao Wang, Juntao Pan, Tingting Luo, Tao Han, Aowang Wang

Applied Sciences· Volume 15· Issue 13

Abstract

Fractures in marine sediments are critical zones for hydrate formation. The kinetics and morphological characteristics of hydrates within sandstone fractures are comprehensively investigated in this study by employing a high-pressure visualization reaction vessel to examine their formation, dissociation, and reformation processes. The results are presented below: (1) In 3 mm Type I fractures, the induction time is longer than that observed in the other two fracture widths. Hydrates predominantly form on the fracture walls and gradually expand toward both sides of the fracture. (2) Gas enters the fracture from multiple directions, causing the hydrate in Type X fractures to expand toward the center from all sides, which shortens the induction time and increases the quantity of hydrate formation. (3) An increase in fracture roughness promotes nucleation of the hydrate at surface protrusions but inhibits the total quantity of hydrate formation. (4) Hydrate dissociation typically propagates from the fracture wall into the interior, exhibiting a wavy surface morphology. Gas production is influenced by the fracture width, with the highest gas production observed in a 3 mm fracture. (5) Due to the memory effect, the hydrate induction time for reformation is significantly shorter, though the quantity of hydrate formed is lower than that of the first formation. This study aims to provide micro-level insights into the distribution of hydrates in sandstone fractures, thereby facilitating more efficient and safe extraction of hydrates from fractures.
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Research context

OpenAlex topics: Methane Hydrates and Related Phenomena · Hydrocarbon exploration and reservoir analysis · CO2 Sequestration and Geologic Interactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Intelligent Construction and Healthy Operation & Maintenance of Deep Underground Engineering, School of Mechanics and Civil Engineering, China University of Mining and Technology, Xuzhou 221116, China

Xinwen Mining Group Co., Ltd., Tai’an 271233, China

Key Laboratory of Coalbed Methane Resources and Reservoir Formation Process of the Ministry of Education, School of Resources and Geosciences, China University of Mining and Technology, Xuzhou 221116, China

Funding

Graduate Innovation Program of China University of Mining and Technology · Postgraduate Research & Practice Innovation Program of Jiangsu Province

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