Synergistic Effect and Phase Behavior of SCG-CAPB-H2O Ternary Compound System
Source abstract
Abstract
The physical properties of sodium cocoyl glycinate (SCG) and the synergistic effects within the SCG/CAPB complex system were investigated using visible–ultraviolet spectrophotometry and a surface tension meter. Analysis of the synergistic parameters of the complex system revealed that the combination of SCG and cocamidopropyl betaine (CAPB) yielded superior results compared to the individual use of SCG. Building upon this, the ternary phase behavior of the SCG/CAPB/H2O system was further explored. Different lyotropic liquid crystal phases were identified using polarized optical microscopy (POM) and small-angle X-ray scattering (SAXS). Surfactant solutions with varying mass fractions exhibited diverse phase behaviors, including the micellar phase (L1), micelle–solid mixed phase (L1-S), hexagonal phase (H), and lamellar phase (Lα), with the insoluble solid phase predominating. The investigation of the ternary phase diagram of SCG/CAPB/H2O provided valuable guidance for detergent formulation screening, enriched the understanding of sodium cocoyl glycinate complex systems, and further promoted the utilization of amino acid-based surfactants in the field of personal care products.
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Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Mesoporous Materials and Catalysis · Surfactants and Colloidal Systems
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300354, China
References (68)
Show source-provided references
1. Ghosh, S., Ray, A., and Pramanik, N. (2020). Self-assembly of surfactants: An overview on general aspects of amphiphiles. Biophys. Chem., 265.10.1016/j.bpc.2020.106429 ↗
2. Rheological behavior and microstructure of an anionic surfactant micelle solution with pyroelectric nanoparticle10.1016/j.colsurfa.2011.12.052 ↗
3. Rheology of hydrophobically modified polymers with spherical and rod-like surfactant micelles10.1016/S0927-7757(98)00741-9 ↗
4. Solubilization of disperse dyes in cationic gemini surfactant micelles10.1016/S0143-7208(00)00015-2 ↗
5. Swollen surfactant micelles: Properties and applications10.3866/PKU.WHXB201810060 ↗
6. Synthesis and properties of three series amino acid surfactants10.3139/113.110179 ↗
7. Rheological properties of lyotropic liquid crystal
8. Lyotropic liquid crystal engineering-ordered nanostructured small molecule amphiphile self-assembly materials by design10.1039/C1CS15148G ↗
9. Alkaline lyotropic silicate-surfactant liquid crystals10.1021/ja963007i ↗
10. Nanostructure templating in inorganic solids with organic lyotropic liquid crystals10.1021/ja9833725 ↗
11. Study of lyotropic liquid crystal containing nonionic surfactant of AEO-9
12. Effects of surfactant hydrophilicity on the oil solubilization and rheological behavior of a nonionic hexagonal phase10.1007/s11743-013-1465-1 ↗
13. Induction of a hexagonal phase in phospholipid-surfactant bilayers10.1007/s002490050170 ↗
14. Linear and nonlinear rheology of micellar solutions in the isotropic, cubic and hexagonal phase probed by rheo-small-angle light-scattering10.1007/BF00396557 ↗
15. Surfactant chain length effect on the hexagonal-to-cubic phase transition in mesoporous silica synthesis10.1016/j.micromeso.2011.06.021 ↗
16. X-ray diffraction study of the lamellar-hexagonal phase transition in phospholipid/surfactant mixtures10.1006/jcis.1998.5485 ↗
17. Self-assembly behaviour of alkylpolyglucosides (APG) in mixed surfactant-stabilized emulsions system10.1016/j.molliq.2010.11.015 ↗
18. Self-assembly behaviors of heterogemini surfactant in aqueous solution investigated by dissipative particle dynamics10.1080/01932691.2013.850433 ↗
19. Self-assembly of surfactant-like peptides and their applications10.1007/s11426-014-5234-4 ↗
20. Controlling surfactant self-assembly10.1016/j.cocis.2004.06.008 ↗
21. Flow regimes during surfactant flooding: The influence of phase behaviour10.1016/j.fuel.2018.08.086 ↗
22. Phase-behavior of systems of a nonionic surfactant and a nonionic polymer in aqueous-solution10.1016/0166-6622(92)80294-C ↗
23. Phase behavior of n-butanol/n-octane/water/cationic gemini surfactant system10.1080/01932690500357966 ↗
24. Amino acid-based cationic gemini surfactant-protein interactions10.1016/j.colsurfa.2014.12.022 ↗
25. Insights into the composition, structure-function relationship, and molecular organization of surfactants from spent coffee grounds10.1016/j.foodhyd.2021.107204 ↗
26. Amino acid-based surfactants10.1016/j.crci.2004.02.009 ↗
27. Dynamic surface tensions of surfactant mixtures at the water-air interface10.1016/0927-7757(94)03069-C ↗
28. Synergistic effect of mixed surfactant systems on foam behavior and surface tension10.1007/s11743-012-1422-4 ↗
29. Monitoring surfactant-induced hemolysis by surface tension measurement10.1006/jcis.2002.8621 ↗
30. Formation and characterization of microemulsion with novel anionic sodium n-lauroylsarcosinate for personal care10.1016/j.molliq.2021.117657 ↗
31. Insight into the low-rank coal flotation using amino acid surfactant as a promoter10.1016/j.fuel.2021.121810 ↗
32. Godek, E., Grzadka, E., Maciolek, U., and Bastrzyk, A. (2021). Influence of zwitterionic CAPB on flocculation of the aqueous cationic guar gum/glauconite suspensions at various pH. Int. J. Mol. Sci., 22.10.3390/ijms222212157 ↗
33. Solubility limits and phase diagrams for fatty acids in anionic (SLES) and zwitterionic (CAPB) micellar surfactant solutions10.1016/j.jcis.2011.12.036 ↗
34. An insight into thermodynamic and association behaviours of cocamidopropyl betaine (CAPB) surfactant in water and water-alcohol mixed media10.1007/s42452-020-2504-y ↗
35. Experimental and theoretical study of sodium cocoyl glycinate as corrosion inhibitor for mild steel in hydrochloric acid medium10.1016/j.molliq.2022.119988 ↗
36. Antireflection cum photocatalytic with superhydrophilic based durable single layer mesoporous TiO2-ZrO2 coating surface for efficient solar photovoltaic application
37. Studies on the wetting behaviour of polymer melts on solid surfaces using the wilhelmy balance method10.1016/0927-7757(96)03624-2 ↗
38. Dynamic surface tension measurement with a dynamic wilhelmy plate technique10.1006/jcis.1999.6270 ↗
39. Effect of surface tension on the measurement of surface energy components of asphalt binders using the wilhelmy plate method10.1016/j.conbuildmat.2015.08.125 ↗
40. Phase behavior of binary mixture of 1-dodecyl-3-methylimidazolium bromide and water revealed by differential scanning calorimetry and polarized optical microscopy10.1016/j.jcis.2006.12.063 ↗
41. Aqueous phase behavior of ionic liquid-related gemini surfactant revealed by differential scanning calorimetry and polarized optical microscopy10.1007/s00396-010-2333-4 ↗
42. Phase structure in blends of polypropylene with ethylene-propylene rubber: A study by small angle X-ray scattering
43. Gels of semifluorinated alkanes: Structural investigations by small angle X-ray scattering10.1002/bbpc.19981021125 ↗
44. Fluid behavior at supercritical states studied by small-angle X-ray scattering10.1016/S0896-8446(98)00045-X ↗
45. Phase segregation of crosslinked polyurethane by small angle X-ray scattering10.1295/polymj.31.120 ↗
46. Micellar structure and transformations in sodium alkylbenzenesulfonate (NaLAS) aqueous solutions: Effects of concentration, temperature, and salt10.1039/D0SM00982B ↗
47. Green synthesis, composition analysis and surface active properties of sodium cocoyl glycinate10.4236/ajac.2013.49056 ↗
48. Preparation of environmentally friendly amino acid-based anionic surfactants and characterization of their interfacial properties for detergent products formulation10.1002/jsde.12051 ↗
49. Mixed solutions of anionic and zwitterionic surfactant (betaine): Surface-tension isotherms, adsorption, and relaxation kinetics10.1021/la049576i ↗
50. Cocamidopropyl betaine can behave as a cationic surfactant and electrostatically associate with polyacids of high molecular weight10.1016/j.colsurfa.2022.130123 ↗
51. Micellar and sub-micellar chromatography with a cocamidopropyl betaine surfactant10.1016/j.chroma.2022.463442 ↗
52. Properties and applications of amphoteric surfactant: A concise review10.1002/jsde.12542 ↗
53. Rheology of mixed solutions of sulfonated methyl esters and betaine in relation to the growth of giant micelles and shampoo applications10.1016/j.cis.2019.102062 ↗
54. Effect of sodium chloride on the surface and wetting properties of aqueous solutions of cocamidopropyl betaine10.1007/s11743-014-1644-8 ↗
55. Adsorption behavior of cocamidopropyl betaine under conditions of high temperature and high salinity10.1002/app.40424 ↗
56. Adsorption properties for aqueous solution of binary mixture of cocamidopropyl betaine-sodiumdodecyl sulfate surfactants on air-liquid interface
57. Thermodynamics of mixed micellization. Pseudo-phase separation models10.1021/i100010a015 ↗
58. Pseudo-phase separation model for thermodynamic calculations on micellar solutions110.1021/j100810a001 ↗
59. Micellization and synergistic interaction of binary surfactant mixtures based on sodium nonylphenol polyoxyethylene ether sulfate10.1016/j.jcis.2007.09.084 ↗
60. A new classification of isotherms for gibbs adsorption of gases on solids10.1016/S0378-3812(99)00074-6 ↗
61. Gibbs adsorption isotherm for concentration as variable10.1142/S0218625X05007190 ↗
62. Classification of gibbs adsorption isotherms10.1016/S0001-8686(98)00044-X ↗
63. Rosen, M.J., and Kunjappu, J.T. (2004). Surfactants and Interfacial Phenomena, Wiley. [4th ed.].10.1002/0471670561 ↗
64. Theory of self-assembly of hydrocarbon amphiphiles into micelles and bilayers
65. Micelle shape and size10.1021/j100665a018 ↗
66. Nonideal multicomponent mixed micelle model10.1021/j100234a030 ↗
67. Mixed Micelle Solutions
68. The characterization of molecular organization of multilamellar emulsions containing pseudoceramide and type iii synthetic ceramide10.1046/j.1523-1747.2003.12470.x ↗