Real Fluid Modeling and Simulation of the Structures and Dynamics of Condensation in CO2 Flows Shocked Inside a de Laval Nozzle, Considering the Effects of Impurities

Because of the currently changing climate, Carbon Capture and Storage (CCS) is increasingly becoming an important contemporary topic. However, this technique still faces various challenges. For the compression of CO2 to its supercritical condition for efficient transport, one of the important challenges is mastering the two-phase flow in the pump. Indeed, phase changes that appear on the blade tips of an impeller or rotor in such pumps can lead to performance and stability issues. Moreover, these phase change phenomena (vaporization and condensation) can be significantly modified by the presence of impurities (N2, O2, H2S, etc.) whose nature depends on the source of the CO2 production. In this work, we focus on analyzing the high pressure flow behavior of CO2 mixed with varying levels of impurities in a de Laval nozzle, for which experimental results are available. Numerical simulations are performed using a real-fluid model (RFM) implemented in the CONVERGE CFD solver. In this model, a tabulation approach is used to provide the thermodynamic and transport properties of the mixture of CO2 with the impurities. The study is carried out with different inlet conditions, and the results are in good agreement with the available experimental data. In addition, the results provide insights on the interaction of the shock wave with the observed condensation phenomenon, as well as its impact on the amount of condensation and other thermodynamic variables. The research indicates that the presence of impurities mixed with CO2 significantly affects the observed condensation in gas streams, which is a crucial factor that cannot be overlooked when implementing CCS systems.