Pull-Out Properties of Nano-Processed Para-Aramid Fabric Materials in Soft Ballistic: An Experimental Analysis
Source abstract
Abstract
Single and multiple pull-out properties of a nano-processed para-aramid fabric structure were investigated. The nano pull-out behavior exhibited three distinct regions, namely crimp extension, interlacement rupture, and stick-slip. Multiple yarn pull-out tests demonstrated a significantly higher pull-out force compared to single-yarn pull-out, primarily attributed to the incorporation of nanoparticles. Furthermore, it was observed that an increase in fabric length resulted in an approximately linear increase in both yarn crimp extension and pull-out force. The highest pull-out force was obtained in the nano-hexagonal boron carbide (nh-B4C, 0.3%) para-aramid structure, followed by multiwalled carbon nanotube (MWCNT, 0.3%) para-aramids. This is because of the enhancement of filament-to-filament friction, especially in the interlacement zone of fabric, alongside the cumulative frictional interactions among the nanoparticles. Additionally, the findings highlight an improvement in crimp extension energy absorption facilitated by nanoparticle incorporation in soft fabric. Notably, the improvement in the energy absorption capacity of yarns within the fabric, without disintegration, is considered significant at this stage. These results indicate a promising potential for performance enhancement in prospective soft ballistic applications.
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Research context
OpenAlex topics: Fiber-reinforced polymer composites · Polymer crystallization and properties · Carbon Nanotubes in Composites
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Nanotechnology Application and Research Centre (ERNAM), Erciyes University, Talas 38039, Kayseri, Turkey
Department of Nanoscience and Nanotechnology, Graduate School of Natural and Applied Sciences, Erciyes University, Talas 38039, Kayseri, Turkey
Faculty of Engineering, Nano/Microfiber Preform Design and Composite Laboratory, Department of Textile Engineering, Erciyes University, Talas 38039, Kayseri, Turkey
Funding
Erciyes University Scientific Research Unit (EUBAP)
References (69)
Show source-provided references
1. An overview of yarn pull-out behavior of woven fabrics10.1177/0040517517741156 ↗
2. Two dimensional (2D) fabrics and three dimensional (3D) preforms for ballistic and stabbing protection: A review10.1177/0040517516669075 ↗
3. Optimization of soft armor: The response of homogenous and hybrid multi-ply para-aramid and ultra-high molecular weight polyethylene fabrics under ballistic impact10.1177/00405175231194365 ↗
4. Sarianna, P., Vuorinen, J., Noordermeer, J.W.M., and Sarlin, E. (2020). Development in Additive Methods in Aramid Fiber Surface Modification to Increase Fiber-Matrix Adhesion: A Review. Coatings, 10.10.3390/coatings10060556 ↗
5. Functionalized Aramid Fibers and Composites for Protective Applications: A Review10.1021/acs.iecr.8b04903 ↗
6. Surface modification and characterization of aramid fibers with hybrid coating10.1016/j.apsusc.2014.09.196 ↗
7. Modifying friction between ultra-high molecular weight polyethylene (UHMWPE) yarns with plasma enhanced chemical vapour deposition (PCVD)10.1016/j.apsusc.2017.02.109 ↗
8. Surface modification of Kevlar by grafting carbon nanotubes10.1002/app.34703 ↗
9. Significance of ballistic parameters and nanohybridization in the development of textile-based body armor: A review10.1016/j.ijimpeng.2023.104700 ↗
10. Ballistic resistance capacity of carbon nanotubes10.1088/0957-4484/18/47/475701 ↗
11. Bizao, R.A., Machado, L.D., de Sousa, J.M., Pugno, N.M., and Galvao, D.S. (2018). Scale effects on the ballistic penetration of graphene sheets. Sci. Rep., 8.10.1038/s41598-018-25050-2 ↗
12. Comprehensive Review of Graphene-Based Nanomaterials for Ballistic and Impact Resistance in Defence Applications
13. Ultrathin broadband terahertz metamaterial based on single-layer nested patterned graphene10.1016/j.physleta.2025.130262 ↗
14. In-fiber photoelectric device based on graphene-coated tilted fiber grating10.29026/oes.2023.230012 ↗
15. Reviewe article: Transparent glass–ceramics for ballistic protection: Materials and challenges10.1016/j.jmrt.2019.05.006 ↗
16. Boron Carbide: Structure, Properties, and Stability under Stress10.1111/j.1551-2916.2011.04865.x ↗
17. Synthesis and Consolidation of Boron Carbide: A Review10.1179/095066009X12506721665211 ↗
18. Boron carbide—A comprehensive review10.1016/0955-2219(90)90048-K ↗
19. A review on current status and development possibilities of soft armour panel assembly10.1007/s10853-023-08961-y ↗
20. A review of fibrous materials for soft body armour applications10.1039/C9RA06447H ↗
21. Nanometre diameter fibres of polymer, produced by electrospinning10.1088/0957-4484/7/3/009 ↗
22. Review of the mechanical properties of carbon nanofiber/polymer composites10.1016/j.compositesa.2011.08.005 ↗
23. Fabrication of aramid nanofiber-wrapped graphene fibers by coaxial spinning10.1016/j.carbon.2020.04.072 ↗
24. Ballistic impact into fabric and compliant composite laminates10.1016/S0263-8223(03)00029-1 ↗
25. Recent progress in developing ballistic and anti-impact materials: Nanotechnology and main approaches10.1016/j.dt.2022.06.007 ↗
26. 3 dimensional fabrics for ballistic impact response: A Critical Evalution10.1007/s12008-022-01140-4 ↗
27. Effects of architecture on ballistic resistance of textile fabrics: Numerical study10.1177/1056789513495246 ↗
28. Review of ballistic protection materials: Propeties and performances10.1177/07316844221137920 ↗
29. Yarn pull-out as a mechanism for dissipating impact energy in Kevlar KM-2 fabric Part I: Quasi-static characterization of yarn pull-out10.1177/004051750407401012 ↗
30. Yarn pull-out as a mechanism for dissipating impact energy in Kevlar KM-2 fabric Part II: Predicting ballistic performance10.1177/004051750407401012 ↗
31. Properties of yarn pull-out in para-aramid fabric structure and analysis by statistical model10.1016/j.compositesa.2011.08.018 ↗
32. Testing and modeling of yarn pull-out in plain Kevlar fabrics10.1016/j.compositesa.2009.04.019 ↗
33. Dissipation of energy by bulletproof aramid fabric10.1023/A:1018674528993 ↗
34. Stick-Slip Behavior of Para-Aramid (Twaron®) Fabric in Yarn Pull-Out10.1177/0040517512449052 ↗
35. Experiments and simulations for dynamic yarn pull-out response of Kevlar® fabrics10.1016/j.compositesa.2024.108147 ↗
36. Frictional behaviour of high performance fibrous tows: Friction experiments10.1016/j.compositesa.2012.08.024 ↗
37. Origin of tensile strength of a woven sample cut in bias directions10.1098/rsos.140499 ↗
38. A numerical investigation of the influence of friction on energ absorption by a high-strength fabric subjected to ballistic impact10.1016/j.ijimpeng.2004.11.005 ↗
39. Enhancement of the quasi-static stab resistance of Kevlar fabrics impregnated with shear thickening fluid10.1016/j.jmrt.2022.04.052 ↗
40. The bias-extension test for the analysis of in-plane shear properties of textile composite reinforcements and prepregs: A review
41. Energy analysis of fabric impregnated by shear thickening fluid in yarn pullout test10.1016/j.compositesb.2019.106901 ↗
42. Tuning the Frictional Properties of Carbon Fabrics Using Boron Carbide Particles10.1007/s12221-019-8493-z ↗
43. Effects of ZnO nanowire and silica coatings on the inter-yarn friction and ballistic properties of Kevlar fabrics10.1016/j.ijimpeng.2023.104637 ↗
44. Aramid nanofiber-functionalized graphene nanosheets for polymer reinforcement10.1039/c2nr31907a ↗
45. Isolation of Aramid Nanofibers for High Strength and Toughness Polymer Nanocomposites
46. Aramid-multiwalled carbon nanotube nanocomposites: Effect of compatibilization through oligomer wrapping of the nanotubes10.1002/pi.5176 ↗
47. Modeling crimp in woven fabrics subjected to ballistic impact10.1016/j.ijimpeng.2005.06.008 ↗
48. Shear deformation and energy absorption analysis of flexible fabric in yarn pullout test. Compos10.1016/j.compositesa.2019.105678 ↗
49. Modeling the effects of yarn material properties and friction on the ballistic impact of a plain-weave fabric10.1016/j.compstruct.2008.11.012 ↗
50. A method for inter-yarn friction coefficient calculation for plain weave of aramid fibers10.1016/j.mechrescom.2016.04.004 ↗
51. (2024, July 11). Nanografi Inc., Ankara, Turkey. Available online: https://nanografi.com/nanoparticles/boron-carbide-b4c-nanopowder-nanoparticles-purity-99-5-size-40-60-nm-hexagonal/.
52. Nanothinx Inc. (2024, January 10). Institute of Chemical Engineering and High Temperature Chemical Processes (ICE-HT) in Patras, Greece. Available online: http://www.nanothinx.com/raw-cnts-in-powder-form/.
53. Evaluating the characteristics of multiwall carbon nanotubes: Review10.1016/j.carbon.2011.03.028 ↗
54. Bhattacharya, M. (2016). Polymer nanocomposites-A comparison between carbon nanotubes, graphene, and clay as nanofillers. Materials, 9.10.3390/ma9040262 ↗
55. Hearle, J.W.S. (2001). High Performance Fibers, Woodhead Publishing Limited and CRC Press LLC.
56. (2024, August 11). US Research Nanomaterials, Inc.. Available online: https://www.us-nano.com/inc/sdetail/479.
57. (2010). Textiles-Yarns Form Packages-Determination of Single-End Breaking Force and Elongation at Break (Standard No. TS EN ISO 2062).
58. Microsoft Corporation (2025, January 22). Microsoft Excel (Version 2016) [Computer software]. Available online: https://office.microsoft.com/excel.
59. Python Software Foundation (2024, July 15). Python Language Reference, Version 3.12.4. Available online: http://www.python.org.
60. (1989). Textiles-Woven Fabrics-Construction-Methods of the Determination of Shrinkage of Yarns from Woven Fabrics (Standard No. TS 254 ISO 7211-3).
61. (1998). Textiles-Determination of Thickness of Textiles and Textile Products (Standard No. TS 7128 EN ISO 5084).
62. (1991). Determination of Mass Per Unit Length and Mass Per Unit Area of Woven Fabrics (Standard No. TS 251 (ISO 3801)).
63. Single and multiple yarn pull-outs on aramid woven fabric structures10.1177/0040517510391703 ↗
64. Yarn pull-out behaviour of plain woven Kevlar fabrics: Effect of yarn sizing, pullout rate, and fabric pre-tension10.1016/j.compstruct.2013.02.018 ↗
65. Multilayered and multidirectional stitched aramid woven fabric structures: Experimental characterization of ballistic performance by considering yarn pull–out test10.1177/0040517510365954 ↗
66. Fracture toughness and failure mechanism of graphene based epoxy composites10.1016/j.compscitech.2014.03.014 ↗
67. Experimental determination of fabric shear by yarn pull-out method10.1177/0040517511431318 ↗
68. Hearle, J.W.S., Grosberg, P., and Backer, S. (1969). Structural Mechanics of Fibres, Yarn and Fabrics, Wiley Interscience.
69. Lord, P.R., and Mohamed, M.H. (1992). Weaving: Conversion of Yarn to Fabric, Merrow Publishing Company.