journal article·2023-08

Direct observation of the 12R transition structure during the C15→C14 phase transformation in Zr(Fe, Cr)2 Laves structured nanoparticles in Zircaloy-4

Wenbin Guo, Geping Li, Jie Ren, Muhammad Ali, Jianan Hu, Qichen Wang, Fusen Yuan, Yingdong Zhang, Fuzhou Han

Intermetallics· Volume 159
Publisher page

Abstract

The presence of 12 R long-period stacking-ordered (LPSO) structure and the associated C15→12 R→C14 phase transformation of Zr(Fe, Cr) 2 secondary phase particle (SPP) in Zircaloy-4 (Zr-4) were investigated by using transmission electron microscopy. Results revealed that the 12 R structure, acting as a transition state, played a critical role in the C15→C14 phase transformation. The C15→12 R and 12 R→C14 phase transformations were realized via the gliding of 1 6 [ 1 ‾ 1 ‾ 2 ‾ ] partials on every four ( 11 1 ‾ ) C15 planes and the motion of 1 6 [ 1 ‾ 1 ‾ 2 ‾ ] partials on every four ( 11 1 ‾ ) 12R atomic layers, respectively. The above two transition processes together constitute the C15→C14 phase transformation, viz. the gliding of 1 6 [ 1 ‾ 1 ‾ 2 ‾ ] partials on every other ( 11 1 ‾ ) C15 planes. The knowledge attained from the present study, shedding lights on the 12 R LPSO transition structure, would also benefit the understanding of the C15→C14 phase transformation.
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Research context

OpenAlex topics: Nuclear Materials and Properties · Fusion materials and technologies · Radioactive element chemistry and processing

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (25)

Show source-provided references
1. Materials challenges in nuclear energy10.1016/j.actamat.2012.11.004 ↗
2. Deformation mechanism and cyclic stress response of Zircaloy-4 alloy cladding tube during low cycle fatigue at room temperature10.1016/j.ijfatigue.2022.106875 ↗
3. Irradiation creep and growth of zirconium alloys: a critical review10.1016/j.jnucmat.2019.04.021 ↗
4. The corrosion of Zr(Fe, Cr)2 and Zr2Fe secondary phase particles in Zircaloy-4 under 350 °C pressurised water conditions10.1016/j.corsci.2017.09.014 ↗
5. Effects of local stress on the stability of tetragonal phase in ZrO2 film10.1016/j.jallcom.2006.07.102 ↗
6. Evolution of “Spinodal decomposition”-like structures during the oxidation of Zr(Fe, Nb)2 under subcritical environment10.1016/j.scriptamat.2020.06.018 ↗
7. Intermetallic precipitates in zircaloy-410.1016/0022-3115(85)90398-8 ↗
8. The formation and stacking faults of Fe and Cr containing Laves phase in Zircaloy-4 alloy10.1016/j.matlet.2016.12.062 ↗
9. Effects of ion irradiation on microstructure and properties of zirconium alloys—a review10.1016/j.net.2014.12.015 ↗
10. Polytype structures in Zr-Cr-Fe laves phase10.1016/0022-5088(86)90078-0 ↗
11. Stacking faults in Zr(Fe, Cr)2 Laves structured secondary phase particle in Zircaloy-4 alloy10.1039/C7NR08963E ↗
12. Polytypic transformations in Laves phases10.1016/j.intermet.2004.02.017 ↗
13. The kinetics of a polytypic Laves phase transformation in TiCr210.1016/j.intermet.2010.11.027 ↗
14. Dislocations in complex materials10.1126/science.1105962 ↗
15. Ab initiocalculation of the phase stability, mechanical properties and electronic structure of ZrCr2 Laves phase compounds10.1080/14786430410001720345 ↗
16. The mechanical properties and the deformation microstructures of the C15 Laves phase Cr2Nb at high temperatures10.1016/j.actamat.2006.10.048 ↗
17. Electron microscopic studies of the laves phases TiCr2 and TiCo210.1002/pssa.2210090127 ↗
18. Stress-induced C14→C15 phase transformation in a Zr(Fe, Cr)2 Laves structured nanophase10.1107/S1600576719015103 ↗
19. High-pressure hydrogen storage performances of ZrFe2 based alloys with Mn, Ti, and V addition10.1016/j.ijhydene.2019.11.242 ↗
20. Theory of the hcp-fcc transition in metals10.1103/PhysRevLett.55.214 ↗
21. Theory of the martensitic transformation in cobalt
22. The interaction of deformation twins with long-period stacking ordered precipitates in a magnesium alloy subjected to shock loading10.1016/j.actamat.2020.01.064 ↗
23. A TEM study of the C15 type Zr(Cr, Fe)2 laves phase in zircaloy-410.1016/0022-3115(85)90033-9 ↗
24. A 12R long-period stacking-ordered structure in a Mg-Ni-Y alloy10.1016/j.jmst.2018.06.015 ↗
25. A novel long-period stacking/order structure in Mg-Ni-Y alloys10.1016/j.jallcom.2019.02.219 ↗