Preparation and Electron-Beam Surface Modification of Novel TiNi Material for Medical Applications
Source abstract
Abstract
A new approach to fabricate TiNi surfaces combining the advantages of both monolithic and porous materials for implants is used in this work. New materials were obtained by depositing a porous TiNi powder onto monolithic TiNi plates followed by sintering at 1200 °C. Then, further modification of the material surface with a high-current-pulsed electron beam (HCPEB) was carried out. Three materials obtained (one after sintering and two after subsequent beam treatment by 30 pulses with different pulse energy) were studied by XRD, SEM, EDX, surface profilometry, and by means of electrochemical measurements, including OCP and EIS. Structural and compositional changes caused by HCPEB treatment were investigated. Surface properties of the samples during their storage in saline for 10 days were studied and a model experiment with cell growth (MCF-7) was carried out for the unmodified sample with an electron beam to detect cell appearance on different surface locations.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Shape Memory Alloy Transformations · Metal and Thin Film Mechanics · Hydrogen Storage and Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Siberian Physical-Technical Institute, National Research Tomsk State University, 634050 Tomsk, Russia
Research Institute of Science and Technology, Tokai University, Kanagawa 259-1292, Japan
School of Natural Sciences, Far Eastern Federal University, 690091 Vladivostok, Russia
Tomsk Scientific Center, Siberian Branch of Russian Academy of Sciences, 634055 Tomsk, Russia
Research School of High-Energy Physics, National Research Tomsk Polytechnic University, 634050 Tomsk, Russia
Funding
Russian Science Support Foundation
References (40)
Show source-provided references
1. Effect of low-temperature phase changes on the mechanical properties of alloys near composition TiNi10.1063/1.1729603 ↗
2. Physical metallurgy of Ti-Ni based shape memory alloys10.1016/j.pmatsci.2004.10.001 ↗
3. Otsuka, K., and Waymann, C.M. (1999). Ti-Ni shape memory alloys. Shape Memory Materials, Cambridge University Press.
4. Effective parameters on the final properties of NiTi-based alloys manufactured by powder metallurgy methods: A review10.1016/j.pmatsci.2020.100739 ↗
5. Saber, O., Ansari, S.A., and Alshoaibi, A. (2020). Development of Ti/Ni nanolayered structures to be a new candidate for energy storage applications. Appl. Sci., 10.10.3390/app10196935 ↗
6. A review of shape memory alloy research, applications and opportunities10.1016/j.matdes.2013.11.084 ↗
7. Carpegna, G., Alovisi, M., Salvatore Paolino, D., Marchetti, A., Gibello, U., Scotti, N., Pasqualini, D., Scattina, A., Chiandussi, G., and Berutti, E. (2020). Evaluation of pressure distribution against root canal walls of NiTi rotary instruments by finite element analysis. Appl. Sci., 10.10.3390/app10082981 ↗
8. The importance of antibacterial surfaces in biomedical applications10.1016/bs.abl.2018.05.001 ↗
9. Critical overview of Nitinol surfaces and their modifications for medical applications10.1016/j.actbio.2008.01.013 ↗
10. Microstructures and properties of laser cladding NiTi alloy with W for biomedical applications10.1016/j.matlet.2011.06.040 ↗
11. Processing of porous TiNi shape memory alloy from elemental powders by Ar-sintering10.1016/j.matlet.2004.02.017 ↗
12. Bartolo, P.J., and Bidanda, B. (2008). Bio-Materials and Prototyping Applications in Medicine, Springer Publishing.10.1007/978-0-387-47683-4 ↗
13. Chua, C.K., Leong, K.F., and Lim, C.S. (2010). Rapid Prototyping: Principles and Applications, World Scientific Publishing Co. Pte. Ltd.. [2nd ed.].10.1142/6665 ↗
14. Surface laser sintering of exothermal powder compositions: The thermal and SEM/EDX study10.1007/s10973-007-8353-8 ↗
15. Effect of quenching media on the properties of TiNi shape memory alloys fabricated by powder metallurgy10.1016/j.jallcom.2020.155931 ↗
16. Engineering the porosity and superelastic behaviors of NiTi alloys prepared by an electro-assisted powder metallurgical route in molten salts10.1016/j.jallcom.2019.04.166 ↗
17. Characterization of high-strength Ti-Ni shape memory alloys prepared by hot pressed sintering10.1016/j.jallcom.2020.157159 ↗
18. Master sintering curves of nickel-titanium and nickel-titanium open-cell foams fabricated by spark plasma sintering10.1007/s10853-019-04226-9 ↗
19. Samal, S., Molnarova, O., Prusa, F., Kopecek, J., Heller, L., Sittner, P., Skodova, M., Abate, L., and Blanco, I. (2021). Net-shape NiTi shape memory alloy by spark plasma sintering method. Appl. Sci., 11.10.3390/app11041802 ↗
20. Densification and microstructural evolution of spark plasma sintered NiTi shape memory alloy10.1016/j.apt.2018.06.026 ↗
21. Plasma surface modification of NiTi shape memory alloy10.1016/j.surfcoat.2006.02.022 ↗
22. Corrosion resistance of NiTi shape memory alloy after hybrid surface treatment using low-temperature plasma10.1016/j.vacuum.2016.12.034 ↗
23. Ion implantation of titanium based biomaterials10.1016/j.pmatsci.2011.03.002 ↗
24. Surface characterization and wear behavior of ion implanted NiTi shape memory alloy10.1016/j.vacuum.2009.01.068 ↗
25. Surface characterizations of laser modified biomedical grade NiTi shape memory alloys10.1016/j.msec.2015.01.085 ↗
26. Study on the junction zone of NiTi shape memory alloy produced by selective laser melting via a stripe scanning strategy10.1016/j.intermet.2020.106947 ↗
27. The effect of energy input on reaction, phase transition and shape memory effect of NiTi alloy by selective laser melting10.1016/j.jallcom.2019.153288 ↗
28. Structural decomposition and phase changes in TiNi surface layer modified by low-energy high-current pulsed electron beam10.1016/j.jallcom.2019.06.322 ↗
29. Hu, J. (2008). Corrosion behavior of NiTi alloys used in orthopedic implants and prosthetic devices. Recent Advances in Biomaterials Research, Transworld Research Network.
30. Structural and morphological features of TiNi-based powder manufactured by the method of hybrid-calcium reduction10.1007/s11182-018-1456-9 ↗
31. A PИTM-CП facility for the surface alloying10.1134/S0020441211050149 ↗
32. Influence of stress aging process on variants of nano-Ni4Ti3 precipitates and martensitic transformation temperatures in NiTi shape memory alloy10.1016/j.matdes.2018.01.024 ↗
33. A comparative study of elastic constants of Ti-Ni based alloys prior to martensitic transformation10.1016/S0921-5093(00)01876-1 ↗
34. Ni4Ti3-precipitation during aging of NiTi shape memory alloys and its influence on martensitic phase transformations10.1016/S1359-6454(02)00257-4 ↗
35. Structural-phase condition, unelastic and plastic behavior and nanohardness of the TiNi surface layers modified by an ion- and electron irradiation10.1016/j.msea.2006.02.104 ↗
36. Effect of applied stress on the shape memory behavior of TiNi-based alloys with different consequences of martensitic transformations10.1016/j.physb.2003.08.128 ↗
37. Effect of inclusions on cratering behavior in TiNi shape memory alloys irradiated with a low-energy, high-current electron beam10.1016/j.surfcoat.2016.06.036 ↗
38. Microstructural characterization of Ti-Ta-based surface alloy fabricated on TiNi SMA by additive pulsed electron-beam melting of film/substrate system10.1016/j.jallcom.2017.09.238 ↗
39. In vitro corrosion study by EIS of an equiatomic NiTi alloy and an implant quality AISI 316 stainless steel10.1002/jbm.b.30545 ↗
40. Electrochemical and corrosion behaviors of sputtered TiNi shape memory films10.1088/0964-1726/25/3/035039 ↗