Effect of a Crystalline Admixture on the Permeability Properties of Concrete and the Resistance to Corrosion of Embedded Steel
Source abstract
Abstract
Reinforced concrete structure durability hinges on concrete permeability, which relies on the characteristics of the inner porous network. Harmful ions and gases can accelerate steel corrosion. Permeability-reducing admixtures (PRA), including crystalline admixtures (CA), are commonly used to mitigate this. This study examines a commercial CA’s impact on durability-related aspects in concrete specimens. Two concrete mixtures with matching proportions were prepared: a reference mix and another mix with a commercial crystalline admixture. Several properties were studied, such as compressive strength, density, porosity, electrical resistivity, water absorption capacity, chloride diffusion, air permeability, and corrosion resistance. The studied admixture in concrete yields several positive outcomes such as a slight reduction in mixing water, a potential 6% increase in concrete’s compressive strength and the development of a denser and less permeable structure with 3% lower porosity and water absorption than the reference mix. Electrical resistivity improves by 10%. Unidirectional chloride diffusion tests show no differences. Air permeability decreases by from 36% to 55%, and the water absorption rate diminishes by 23%. The admixture potentially reduces the scatter in corrosion initiation periods for steel reinforcements, delaying corrosion onset by around 60 days, although more extensive experiments are needed for definitive conclusions.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Concrete Corrosion and Durability · Concrete and Cement Materials Research · Corrosion Behavior and Inhibition
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Marine Science and Applied Biology, University of Alicante, P.O. Box 99, 03080 Alicante, Spain
Department of Civil Engineering, University of Alicante, P.O. Box 99, 03080 Alicante, Spain
AG Corrosión, 03006 Alicante, Spain
Funding
Spanish Agencia Estatal de Investigación
References (45)
Show source-provided references
1. Pedeferri, P., and Bertolini, L. (2000). La Durabilità del Calcestruzzo Armato (The Durability of Reinforced Concrete), Mc Graw Hill. (In Italian).
2. Kropp, J., and Hilsdorf, H.K. (1995). Performance Criteria for Concrete Durability, CRC Press.10.1201/9781482271522 ↗
3. (1996). Corrosion of Metals in Concrete (Standard No. ACI Committee 222R-96).
4. Bertolini, L., Elsener, B., Pedeferri, P., Redaelli, E., and Polder, R.B. (2013). Corrosion of Steel in Concrete: Prevention, Diagnosis, Repair, Wiley.10.1002/9783527651696 ↗
5. Oxygen Availability and Corrosion Propagation in RC Structures in the Marine Environment—Inferences from Field and Laboratory Studies10.3390/cmd3030022 ↗
6. (2015). Report on Chemical Admixtures for Concrete (Standard No. ACI Committee 212.3R).
7. A Review of Self-Healing Concrete for Damage Management of Structures10.1002/admi.201800074 ↗
8. Crystalline Coating and Its Influence on the Water Transport in Concrete
9. Integral waterproof concrete: A comprehensive review10.1016/j.jobe.2023.107718 ↗
10. An overview of a twofold effect of crystalline admixtures in cement-based materials: From permeability-reducers to self-healing stimulators10.1016/j.jobe.2021.102400 ↗
11. García Calvo, J.L., Sánchez Moreno, M., Carballosa, P., Pedrosa, F., and Tavares, F. (2019). Improvement of the Concrete Permeability by Using Hydrophilic Blended Additive. Materials, 12.10.3390/ma12152384 ↗
12. Influence of Permeability-Reducing Admixtures on Water Penetration in Concrete
13. Application of a capillary crystalline material to enhance cement grout for sealing tunnel leakage10.1016/j.conbuildmat.2019.04.095 ↗
14. Assessment of self-healing and durability parameters of concretes incorporating crystalline admixtures and Portland Limestone Cement10.1016/j.cemconcomp.2019.02.017 ↗
15. Performance of crystalline forming additive materials in concrete10.1016/j.conbuildmat.2019.117056 ↗
16. Azarsa, P., Gupta, R., Azarsa, P., and Biparva, A. (2021). Durability and Self-Sealing Examination of Concretes Modified with Crystalline Waterproofing Admixtures. Materials, 14.10.3390/ma14216508 ↗
17. Performance of Permeability-Reducing Admixtures in Marine Concrete Structures
18. (1997). Standard Test Method for Electrical Indication of Concrete’s Ability to Resist Chloride Ion Penetration (Standard No. ASTM-C1202-97).
19. Investigation of the Mechanical Properties and Durability of Concretes Produced with Microsilica and Crystalline Admixtures
20. (1999). Concrete, Mortar and Cement-Based Repair Materials: Chloride Migration Coefficient from Non-Steady-State Migration Experiments (Standard No. NT Build 492).
21. (2016). Concrete—Specification, Performance, Production and Compliance (Standard No. EN 206-1).
22. Using the Karsten tube to estimate water transport parameters of porous building materials10.1617/s11527-012-9975-2 ↗
23. A two chamber vacuum cell for measuring the coefficient of permeability to air of the concrete cover on site10.1007/BF02472595 ↗
24. Beltrán-Cobos, R., Tavares-Pinto, F., and Sánchez-Moreno, M. (2021). Analysis of the Influence of Crystalline Admixtures at Early Age Performance of Cement-Based Mortar by Electrical Resistance Monitoring. Materials, 14.10.3390/ma14195705 ↗
25. A self-healing cementitious composite with mineral admixtures and built-in carbonate10.1016/j.cemconcomp.2018.05.013 ↗
26. Ministerio de Fomento (2016). Instrucción Española de Recepción de Cementos (RC-16), Ministerio de Fomento. (Spanish Code for Cements).
27. (2020). Ensayos de Hormigón Fresco. Parte 2: Ensayo de Asentamiento (Fresh Concrete Tests. Part 2: Setting Test, Spanish Standard) (Standard No. UNE-EN 12350-2:2020).
28. (2003). Ensayos de Hormigón Endurecido. Parte 3: Determinación de la Resistencia a Compresión de Probetas (Hardened Concrete Tests. Part 3: Compressive Strenght Test, Spanish Standard) (Standard No. UNE-EN 12390-3).
29. (2021). Standard Test Method for Density, Absorption, and Voids in Hardened Concrete (Standard No. ASTM-C642).
30. Comparison of ASTM saturation techniques for measuring the permeable porosity of concrete10.1016/j.cemconres.2004.09.017 ↗
31. A test method for measuring chloride diffusion coefficients through non-saturated concrete. Part I: The instantaneous plane source diffusion case10.1016/S0008-8846(02)00750-0 ↗
32. Efficacy of Surface hydrophobic agents in reducing water and chloride ion penetration in concrete10.1617/s11527-006-9218-5 ↗
33. (2014). Testing Hardened Concrete. Determination of the Chloride Resistance of Concrete, Unidirectional Diffusion (Standard No. EN 12390-11:2015).
34. Recommendation of RILEM TC 178-TMC: Testing and Modelling Chloride Penetration in Concrete. Methods for obtaining dust samples by means of grinding concrete in order to determine the chloride concentration profile10.1617/s11527-012-9968-1 ↗
35. Analysis of acid-soluble chloride in cement, mortar, and concrete by potentiometric titration without filtration steps10.1016/S0008-8846(99)00063-0 ↗
36. Generalization of the possibility of eliminating the filtration step in the determination of acid-soluble chloride content in cement and concrete by potentiometric titration10.1016/j.cemconres.2004.04.012 ↗
37. Recommendation of RILEM TC 189-NEC: Comparative test—Part I—Comparative test of “penetrability” methods10.1007/BF02482256 ↗
38. The determination of the permeability of concrete to oxygen by the Cembureau method—A recommendation10.1007/BF02472192 ↗
39. Recommendation of RILEM TC 154-EMC: Test methods for on-site measurement of resistivity of concrete10.1007/BF02480599 ↗
40. Ministerio de Transportes, Movilidad y Agenda Urbana (2021). Instrucción Española de Hormigón Estructural (EHE-21), Ministerio de Transportes, Movilidad y Agenda Urbana. (Spanish Code for Structural Concrete).
41. Electrical resistivity of concrete for durability evaluation. A review10.1155/2017/8453095 ↗
42. La resistividad eléctrica como parámetro de control del hormigón y de su durabilidad (The electrical resistivity as a control parameter of concrete and its durability)10.21041/ra.v1i2.8 ↗
43. (2022). Standard Test Method for Corrosion Potentials of Uncoated Reinforcing Steel in Concrete (Standard No. ASTM-C876-22B).
44. Andrade, C., Alonso, C., and González, J. (1990). An Initial Effort to Use the Corrosion Rate Measurement for Estimating Rebar Durability. Corrosion Rates of Steel in Concrete, American Society for Testing and Materials ASTM STP 1065.10.1520/STP25013S ↗
45. Test methods for on-site reinforcement corrosion rate measurement of steel reinforcement in concrete by means of the Polarization Resistance method. RILEM Recommendation of TC-154 Electrochemical Techniques for measuring metallic corrosion10.1007/BF02483292 ↗