journal article·2023-05-13Open access

Spatial Distribution of Cu, Zn, Pb, Cd, Co, Ni in the Soils of Ili River Delta and State Natural Reserve “Ili-Balkhash”

Azamat Madibekov, Laura Ismukhanova, Christian Opp, Zarina Saidaliyeva, Askhat Zhadi, Botakoz Sultanbekova, Meruert Kurmanova

Applied Sciences· Volume 13· Issue 10

Abstract

River delta soils are the final spatial units of the matter flow within the whole river catchment. Due to their spatial position in the catchment and due to their fine grain size composition, river delta soils are important matter sinks in general, especially for heavy metals. The article presents the results of spectrometric analysis of heavy metals in the soils of the Ili River Delta and State Natural Reserve “Ili-Balkhash” in 2021. This area is included in the list of wetlands of international importance under the Convention on Wetlands. Heavy metals in the samples were determined using the flame atomic absorption spectrometric method using the AA-7000 atomic absorption spectrophotometer. The spatial distribution of the metals was visualized in the ArcGIS 10.5 environment. Copper concentrations were measured in the soils of the dry steppe, semi-desert and desert zones with average values up to 28.5 mg kg−1 and a maximum level of 75.1 mg kg−1. The concentrations of lead are 8.0–15.9 mg kg−1. The cadmium content exceeds the standards from 2.1 to 6.5 mg kg−1 on the whole territory at MPC 2.0 mg kg−1, reaching up to 3.3 MPC (Maximum Permissible Concentration). The cobalt concentration ranges from 6.7 to 20.6 mg kg−1, and nickel ranges from 11.3 to 22.2 mg kg−1. Soil contamination due to cobalt and nickel is observed in the northern and eastern parts of the study area. The received data about pollution of the soil cover by heavy metals makes it possible to assess the degree of anthropogenic load of the unique natural environment in the Ili River Delta and natural reserve.
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Research context

OpenAlex topics: Soil and Environmental Studies · Heavy metals in environment · Water Resources and Management

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Geography and Water Security, Almaty 050010, Kazakhstan

Faculty of Geography, Philipps-Universität Marburg, D-35032 Marburg, Germany

Department of Geography and Environmental Science, The University of Reading, Reading RG6DR, UK

Department of Water Resources and Reclamation, Kazakh National Agrarian Research University, Almaty 050013, Kazakhstan

Department of Meteorology and Hydrology, Al-Farabi Kazakh National University, Almaty 050040, Kazakhstan

Funding

Committee of Science of the Ministry of Science and Higher Education of the Republic of Kazakhstan

References (63)

Show source-provided references
1. Motuzova, G.V., and Karpova, Y.A. (2013). Chemical Pollution of the Biosphere and Its Ecological Consequences: Textbook, Publishing House of Moscow University.
2. Horizontal variation in trace elements and soil characteristics at Siloam and Tshipise geothermal springs, Limpopo Province, South Africa10.4314/wsa.v42i4.20 ↗
3. Seredina, V.P. (2015). Soil Pollution, Tomsk State University Publishing House.
4. Ismukhanova, L., Choduraev, T., Opp, C., and Madibekov, A. (2022). Accumulation of Heavy Metals in Bottom Sediment and Their Migration in the Water Ecosystem of Kapshagay Reservoir in Kazakhstan. Appl. Sci., 12.10.3390/app122211474 ↗
5. The Level of Anthropogenic Pollution of the Kapshagay Water Reservoir, Republic of Kazakhstan10.1007/698_2020_603 ↗
6. Panin, M.S. (2008). Ecology of Soils, Rarite.
7. FAO and UNEP (2021). Global Assessment of Soil Pollution. Summary for policy makers, United Nations Environment Programme.
8. Potential environmental pollution from copper metallurgy and methods of management10.1016/j.envres.2021.111050 ↗
9. Beier, T., Opp, C., and Hahn, J. (2022). Sink and source functions for metal(loid)s in sediments and soils of two water reservoirs of the Ore Mountains, Saxony, Germany. Appl. Sci., 12.10.3390/app12136354 ↗
10. Load on differently used soils by heavy metals within the highly contaminated area of Bitterfeld (FRG)10.1016/S0048-9697(05)80013-0 ↗
11. The Issue of transporting pollutants with atmospheric precipitation10.1088/1755-1315/107/1/012064 ↗
12. Role of the chemical composition of an atmospheric precipitation in pollution of a surface water
13. Heavy Metals in Marine Aerosols of the Azov Sea10.24057/2071-9388-2020-11 ↗
14. Heavy metal transport and evolution of atmospheric aerosols in the Antarctic region10.1016/j.scitotenv.2020.137702 ↗
15. Kulshrestha, U., and Mishra, M. (2022). Asian Atmospheric Pollution Sources, Characteristics and Impacts, Elsevier.
16. Soil particle size fraction and potentially toxic elements bioaccessibility: A review10.1016/j.ecoenv.2020.111806 ↗
17. Ugwu, I., and Anthony Igbokwe, O. (2019). Advanced Sorption Process Applications, IntechOpen.
18. (1982). Methodical Recommendations for the Hygienic Substantiation of MPC for Chemicals in Soil, Ministry of Health of the USSR.
19. Blume, H.-P., Brümmer, G.W., Fleige, H., Horn, R., Kandeler, E., Kögel-Knabner, I., Kretzschmar, R., Stahr, K., and Wilke, B.-M. (2016). Scheffer/Schachtschabel Soil Science, Springer.10.1007/978-3-642-30942-7 ↗
20. WOCAT (2021, October 10). Undated. WOCAT-Categorisation System. Available online: https://www.wocat.net/fileadmin/user_upload/documents/QT_and_QA/CategorisationSystem.pdf.
21. (2021, October 23). Convention on Wetlands of International Importance Principally as Habitat for Waterfowl. Adopted February 2, 1971. Available online: https://www.wetlands.org/wetlands/ramsar-convention.
22. (2021, February 07). State Natural Reserve “Ile-Balkhash” of the Forestry and Wildlife Committee of the Ministry of Agriculture of the Republic of Kazakhstan: Resolution of the Government of the Republic of Kazakhstan dated June 27, 2018. No. 381. Available online: https://adilet.zan.kz/rus/docs/P1800000381/info.
23. Assessment of natural hazards in the Ile-Balkhash nature reserve (Kazakhstan)10.1134/S2079096119040048 ↗
24. (2021, January 21). Available online: https://wwf.ru/resources/news/tsentralnaya-aziya/ile-balkhash-tigr-vse-blizhe/.
25. Results of AAS-measurements of atmospheric deposition of copper and lead in the snow cover of Almaty agglomeration10.1515/pac-2021-0203 ↗
26. Ismukhanova, R.L., Kulbekova, R., Amirgaliyev, N., Madibekov, A., and Zhadi, A. (2020, January 18–24). The research results of physical and chemical parameters of snow cover in the almaty agglomeration (Southeast of Kazakhstan). Proceedings of the 20th International Multidisciplinary Scientific GeoConference SGEM 2020, Albena, Bulgaria.10.5593/sgem2020/5.1/s20.084 ↗
27. Heavy metal content in the snow cover in the republic of Kazakhstan
28. Stochastic risk assessment of urban soils contaminated by heavy metals in Kazakhstan10.1016/j.scitotenv.2020.141535 ↗
29. Lin, M., Chan, I.-N., Chan, C.-Y., Wang, X.-M., and Dong, H.-Y. (2011). The Impact of Air Pollution on Health, Economy, Environment and Agricultural Sources, IntechOpen.
30. Spatial distribution and ecotoxicological risk assessment of heavy metals in surface sediments of the southern Bohai Bay, China10.1007/s11356-012-1332-z ↗
31. Tilekova, Z.T. (2015). Environmental Assessment of Anthropogenic Impact to the Natural Environment of the Balkash Region. [Ph.D. Thesis, Abai Kazakh National Pedagogical Unirversity].
32. Assessment of contamination of recent sediments of a large reservoir in the catchment area of Arctic Ocean, Northern Europe10.24425/ppr.2021.136511 ↗
33. Heavy metal deposition through precipitation in Kazakhstan10.1016/j.heliyon.2020.e05844 ↗
34. Assessment of the environmental impact of the tailing dump of the Balkhash concentrating mill
35. The problem of technogenic pollution of the north-western coast of lake Balkhash. International ecological forum “Balkhash-2000”
36. (2018). Nature Protection. Soils. General Requirements for Sampling. Standard No. State Standard 17.4.3.01-83.
37. Lomtadze, V.D. (1972). Methods of Laboratory Studies of Physical and Mechanical Properties of Rocks (Guide to Laboratory Studies Prior to Engineering Geology), Nedra.
38. Lomtadze, V.D. (1990). Laboratory Research Methods, Nedra.
39. Comparative Case Study on the Influence of Spatial Distribution of Heavy Metals in Regional Area
40. IUSS Working Group WRB (2022). International Soil Classification System for Naming Soils and Creating Legends for Soil Maps, International Union of Soil Sciences (IUSS). [4th ed.].
41. Kudekova, T.K. (2002). The Current Ecological Condition of the Balkhash Lake Basin, Kaganat.
42. Samakova, A.B. (2003). Problems of Hydroecological Sustainability in the Balkhash Lake Basin, Publiushing house “Kaganat”.
43. (2011). Soils. Methods for Determination of Specific Electric Conductivity, pH and Solid Residue of Water Extract. Standard No. GOST 26423-85.
44. (1990). Technique for Measuring the Mass Fraction of Mobile Forms of Metals (Copper, Lead, Zinc, Nickel, Cadmium, Cobalt, Chromium, Manganese) in Soil Samples by Atomic Absorption Analysis. Standard No. GD 52.18.289-90.
45. (2006). Maximum Permissible Concentration (MPC) of Chemicals in Soi. Standard No. HS 2.1.7.2041-06.
46. Studies of heavy metal adsorption by hydrous iron and manganese oxides10.1021/ac60349a004 ↗
47. Vorobieva, L.A., Ladonin, D.V., Lopukhina, O.V., Rudakova, T.A., and Kiryushin, A.V. (2011). Chemical Analysis of Soils, Moscow State University Press.
48. Condition and ways of harmonizing hygienic standards for substances polluting the atmospheric air
49. Bastian, O., and Schreiber, K.F. (1999). Analyse und Ökologische Bewertung der Landschaft, Aufl. Spektrum Akademischer Verlag. [2nd ed.].
50. Kovalskiy, V.V., and Andrianova, G.A. (1970). Microelements in the Soils of the USSR, Nauka.
51. Alloway, B.J. (1990). Heavy Metals in Soils, John Wiley and Sons.
52. Ecological risk assessment of Cd and other heavy metals in soil-rice system in the karst areas with high geochemical background of Guangxi, China10.1007/s11430-020-9763-0 ↗
53. Vinogradov, A.P. (1967). Introduction to Ocean Geochemistry, Nauka.
54. Perelman, A.I. (1975). Landscape Geochemistry, High School.
55. Migration rows of elements in the weathering crust
56. The specific adsorption of divalent Cd, Co, Cu, Pb and Zn on goethite10.1111/j.1365-2389.1976.tb01986.x ↗
57. Bioavailability, accumulation and effects of heavy metals in sediments with special reference to United Kingdom estuaries: A review10.1016/0269-7491(92)90099-V ↗
58. Heavy metal contamination status in soil-plant system in the Upper Mersey Estuarine Floodplain, Northwest England10.1016/j.marpolbul.2019.06.026 ↗
59. Canadian Soil Quality Guidelines (2022). Carcinogenic and Other Polycyclic Aromatic Hydrocarbons (PAHs) (Environmental and Human Health Effects), Canadian Council of Ministers of the Environment (CCME). Available online: http://ceqg-rcqe.ccme.ca/.
60. Speciation of metals in soils and water: Risk assessment10.1007/s40710-018-0328-1 ↗
61. Environmental Chemistry and Ecotoxicology of Hazardous Heavy Metals: Environmental Persistence, Toxicity, and Bioaccumulation10.1155/2019/6730305 ↗
62. Bioaccumulation and transfer of zinc in soil plant and animal system: A health risk assessment for the grazing animals10.1007/s11356-021-15808-z ↗
63. Contamination features and health risk of soil heavy metals in China10.1016/j.scitotenv.2015.01.025 ↗