journal article·2021-06-24Open access

Synthesis of Ambient Cured GGBFS Based Alkali Activated Binder Using a Sole Alkaline Activator: A Feasibility Study

Thandiwe Sithole, Nelson Tsotetsi, Tebogo Mashifana

Applied Sciences· Volume 11· Issue 13

Abstract

Utilisation of industrial waste-based material to develop a novel binding material as an alternative to Ordinary Portland Cement (OPC) has attracted growing attention recently to reduce or eliminate the environmental footprint associated with OPC. This paper presents an experimental study on the synthesis and evaluation of alkali activated Ground granulated blast furnace slag (GGBFS) composite using a NaOH solution as an alkaline activator without addition of silicate solution. Different NaOH concentrations were used to produce varied GGBFS based alkali activated composites that were evaluated for Uncofined Compressive Strength (UCS), durability, leachability, and microstructural performance. Alkali activated GGBFS composite prepared with 15 M NaOH solution at 15% L/S ratio achieved a UCS of 61.43 MPa cured for 90 days at ambient temperatures. The microstructural results revealed the formation of zeolites, with dense and non-porous morphology. Alkali activated GGBFS based composites can be synthesized using a sole alkaline activator with potential to reduce CO2 emission. The metal leaching tests revealed that there are no potential environmental pollution threats posed by the synthesized alkali activated GGBFS composites for long-term use.
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Research context

OpenAlex topics: Concrete and Cement Materials Research · Magnesium Oxide Properties and Applications · Recycling and utilization of industrial and municipal waste in materials production

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemical Engineering, University of Johannesburg, Doornfontein 2088, South Africa

Funding

National Research Foundation

References (53)

Show source-provided references
1. Limestone calcined clay cement as a low-carbon solution to meet expanding cement demand in emerging economies10.1016/j.deveng.2017.06.001 ↗
2. Ambient-Cured geopolymer concrete with single alkali activator
3. Study of synergy between a natural volcanic pozzolan and a granulated blast furnace slag in the production of geopolymeric pastes and mortars10.1016/j.conbuildmat.2017.09.092 ↗
4. High volume Portland cement replacement: A review10.1016/j.conbuildmat.2020.120445 ↗
5. Habert, G. (2014). Assessing the environmental impact of conventional and ‘green’cement production. Eco-Efficient Construction and Building Materials, Woodhead Publishing.10.1533/9780857097729.2.199 ↗
6. Use of an agricultural by-product, nano sized palm oil fuel ash as a supplementary cementitious material10.1016/j.conbuildmat.2018.06.156 ↗
7. Naqi, A., and Jang, J.G. (2019). Recent progress in green cement technology utilizing low-carbon emission fuels and raw materials: A review. Sustainability, 11.10.3390/su11020537 ↗
8. Shubbar, A.A., Sadique, M., Shanbara, H.K., and Hashim, K. (2020). The development of a new low carbon binder for construction as an alternative to cement. Advances in Sustainable Construction Materials and Geotechnical Engineering, Springer.10.1007/978-981-13-7480-7_18 ↗
9. Mechanical properties and structure of fly ash modified basic oxygen furnace slag based geopolymer masonry blocks10.5276/JSWTM/2020.372 ↗
10. Sanjuán, M.Á., Andrade, C., Mora, P., and Zaragoza, A. (2020). Carbon dioxide uptake by cement-based materials: A Spanish case study. Appl. Sci., 10.10.3390/app10010339 ↗
11. (2013). Cement Sustainability Initiative. Technology Roadmap: Low-Carbon Technology for the INDIAN Cement Industry, World Business Council for Sustainable Development and International Energy Agency.
12. Geopolymers as an alternative to Portland cement: An overview10.1016/j.conbuildmat.2019.117455 ↗
13. Development of lightweight construction blocks by alkaline activation of bof slag10.5276/JSWTM/2019.175 ↗
14. Geopolymer bricks made from less active waste materials10.1016/j.conbuildmat.2020.118441 ↗
15. Geosynthesis of building and construction materials through alkaline activation of granulated blast furnace slag10.1016/j.conbuildmat.2020.120712 ↗
16. Recovery of silicon dioxide from waste foundry sand and alkaline activation of desilicated foundry sand10.1007/s40831-020-00303-5 ↗
17. Abdullah, M.M., Ming, L.Y., Yong, H.C., and Tahir, M.F. (2018). Clay-Based materials in geopolymer technology. Cement Based Materials, InTech.10.5772/intechopen.74438 ↗
18. Bong, S.H., Nematollahi, B., Nazari, A., Xia, M., and Sanjayan, J. (2019). Efficiency of different superplasticizers and retarders on properties of one-part’ fly ash-slag blended geopolymers with different activators. Materials, 12.10.3390/ma12203410 ↗
19. High temperature behaviour of ambient cured alkali-activated materials based on ladle slag10.1016/j.cemconres.2012.09.011 ↗
20. Effects of slag substitution on physical and mechanical properties of fly ash-based alkali activated binders (AABs)10.1016/j.cemconres.2019.05.003 ↗
21. Influence of calcium compounds on the mechanical properties of fly ash geopolymer pastes10.1016/j.jhazmat.2008.12.121 ↗
22. Rice husk ash and spent diatomaceous earth as a source of silica to fabricate a geopolymeric binary binder10.1016/j.jclepro.2016.01.057 ↗
23. Effectiveness of new silica fume alkali activator10.1016/j.cemconcomp.2005.07.004 ↗
24. Investigating the possibility of utilizing pumice-type natural pozzonal in production of geopolymer cement
25. Sustainable solidification of ferrochrome slag through geopolymerisation: A look at the effect of curing time, type of activator and liquid solid ratio10.1186/s42834-019-0022-7 ↗
26. Recycling zeolitic tuff and marble waste in the production of eco-friendly geopolymer concretes10.1016/j.jclepro.2020.122298 ↗
27. The effect of type and concentration of activators on flowability and compressive strength of natural pozzolan and slag-based geopolymers10.1016/j.conbuildmat.2016.02.086 ↗
28. Preparation of cleaner one-part geopolymer by investigating different types of commercial sodium metasilicate in China10.1016/j.jclepro.2018.08.060 ↗
29. Falayi, T. (2019). A comparison between fly ash-and basic oxygen furnace slag-modified gold mine tailings geopolymers. Int. J. Energy Environ. Eng., 1–11.10.1007/s40095-019-00328-x ↗
30. Micromechanics constitutive modelling and optimization of strain hardening geopolymer composite10.1016/j.ceramint.2017.01.138 ↗
31. An overview on the influence of various factors on the properties of geopolymer concrete derived from industrial by-products10.1016/j.conbuildmat.2014.12.065 ↗
32. Effect of synthesis parameters on compressive strength of fly ash-slag blended geopolymer10.1016/j.conbuildmat.2018.03.026 ↗
33. Influence of solids-to-liquid and activator ratios on calcined kaolin cement powder10.1016/j.phpro.2011.11.049 ↗
34. Effect of solids-to-liquids, Na2SiO3-to-NaOH and curing temperature on the palm oil boiler ash (Si + Ca) geopolymerisation system10.3390/ma8052227 ↗
35. Microstructure and microhardness property of the interface between a metakaolin/GGGBFS-based geopolymer paste and granite aggregate10.1016/j.conbuildmat.2019.06.090 ↗
36. Desilication of fly ash and development of lightweight construction blocks from alkaline activated desilicated fly ash10.1504/IJEWM.2017.087152 ↗
37. Imtiaz, L., Rehman, S.K.U., Ali Memon, S., Khizar Khan, M., and Faisal Javed, M. (2020). A review of recent developments and advances in eco-friendly geopolymer concrete. Appl. Sci., 10.10.3390/app10217838 ↗
38. The effect of different parameters on the development of compressive strength of oil palm shell geopolymer concrete10.1155/2014/898536 ↗
39. Fresh, strength and microstructure properties of geopolymer concrete incorporating lime and silica fume as replacement of fly ash10.1016/j.jobe.2020.101780 ↗
40. Development of ceramic tile waste geopolymer binders based on pre-targeted chemical ratios and ambient curing10.1016/j.conbuildmat.2020.120297 ↗
41. Effect of phosphate addition on room-temperature-cured fly ash-metakaolin blend geopolymers10.1016/j.conbuildmat.2020.121486 ↗
42. High calcium fly ash geopolymer stabilized lateritic soil and granulated blast furnace slag blends as a pavement base material10.1016/j.jhazmat.2017.07.067 ↗
43. Fly ash and zinc slag blended geopolymer: Immobilization of hazardous materials and development of paving blocks10.1016/j.jhazmat.2019.121673 ↗
44. Effects of epoxy resin on the mechanical performance and thickening properties of geopolymer cured at low temperature10.1016/j.matdes.2016.07.003 ↗
45. A critical review of geopolymer properties for structural fire-resistance applications10.1016/j.conbuildmat.2019.06.076 ↗
46. Effect of polyacrylic resin on mechanical properties of granulated blast furnace slag based geopolymer10.1016/j.jnoncrysol.2017.07.003 ↗
47. Development of self-compacting geopolymer concrete as a sustainable construction material10.1016/j.serj.2018.08.004 ↗
48. Influence of different curing temperatures and alkali activators on properties of GGBFS geopolymer mortars containing fly ash and palm-oil fuel ash10.1016/j.conbuildmat.2016.08.153 ↗
49. Synthesis and characterization of geopolymers containing blends of unprocessed steel slag and metakaolin: The role of slag particle size10.1016/j.ceramint.2017.12.131 ↗
50. Development of cleaner one-part geopolymer from lithium slag10.1016/j.jclepro.2020.125241 ↗
51. Formulation of sludge incineration residue based geopolymer and stabilization performance on potential toxic elements10.1016/j.wasman.2018.04.022 ↗
52. Valorisation of glass wastes for the development of geopolymer composites—Durability, thermal and microstructural properties: A review10.1016/j.conbuildmat.2019.06.169 ↗
53. (2013). ASTM Standard C642-13. Standard Test Method for Density‚ Absorption‚ and Voids in Hardened Concrete, ASTM International.