journal article·2002-04

Doping Effects on the Properties of BaTiO3-Based Solid Solutions

V. N. Tsygankov, V. V. Safonov

Inorganic Materials· Volume 38· Issue 4
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Abstract

The effect of Fe2O3 additions on the electrical properties and microstructure of yttria-doped barium titanate ceramics was studied by resistivity measurements and electron microscopy. Doping with ≥0.05 mol % Fe2O3 markedly increases the resistivity of the ceramics. The Fe atoms are nonuniformly distributed between BaTiO3 and the grain-boundary phase Ba6Ti17O40 .
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Research context

OpenAlex topics: Ferroelectric and Piezoelectric Materials · Advanced ceramic materials synthesis · Intermetallics and Advanced Alloy Properties

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References (14)

Show source-provided references
1. Sheftel', I.T., Termorezistory (Thermistors), Moscow: Nauka, 1973.
2. Semiconductors Based on Barium Titanate, Okazaki, M., Ed., Tokyo: Gakkensya, 1977. Translated under the title Poluprovodniki na osnove titanata bariya, Moscow: Energoizdat, 1982.
3. Macklen, E.D., Thermistors, Ayr: Electrochemical Publishing, 1979. Translated under the title Termorezistory, Moscow: Radio i Svyaz', 1983.
4. Wiegleb, G., Sensortechnik, Berlin: Franzis, 1986. Translated under the title Datchiki. Ustroistvo i primenenie, Moscow: Mir, 1989.
5. Okazaki, K., Tekhnologiya keramicheskikh dielektrikov (Ceramic Engineering for Dielectrics), Moscow: Energiya, 1976 (translated from Japanese).
6. Toropov, N.A., Bazarnovskii, V.P., Lapin, V.V., and Kurtseva, N.N., Diagrammy sostoyaniya silikatnykh sistem: Spravochnik (Phase Diagrams of Silicate Systems: A Handbook), Leningrad: Nauka, 1969, issue 1.
7. Diagrammy sostoyaniya sistem tugoplavkikh oksidov (Phase Diagrams of Refractory Oxide Systems), Galakhov, F.Ya., Ed., Leningrad: Nauka, 1985.
8. O'Bryan, H.M., Jr. and Thomson, J., Jr., Phase Equilibria in the TiO2-Rich Region of the System BaO–TiO2, J. Am. Ceram. Soc., 1974, vol. 57, no. 12, pp. 522–526.10.1111/j.1151-2916.1974.tb10801.x ↗
9. Gindin, E.I., Kostikov, Yu.P., Motornyi, A.V., and Rubal'skii, G.D., Phase Relations in the BaO–TiO2– Ti2O3 System near the Ti: Ba = 3: 1 Section, Izv. Akad. Nauk SSSR, Neorg. Mater., 1991, vol. 27, no. 1, pp. 53–59.
10. Leikina, B.B., Kostikov, Yu.P., Teketer-Proskuryakova, G.N., et al., Barium Titanate Doped with Yttrium and Niobium: Phase Composition, Transport Properties, and Valence States of Cations, Izv. Akad. Nauk SSSR, Neorg. Mater., 1981, vol. 17, no. 10, pp. 1852–1856.
11. Kvantov, M.A., Kostikov, Yu.P., Teslenko, S.P., and Yarmarkin, V.K., Degradation of BaTiO3 and TiO2 Ceramics upon Thermal Oxidation, Izv. Akad. Nauk SSSR, Neorg. Mater., 1985, vol. 21, no. 3, pp. 480–483.
12. Chan, H.M., Harmer, M.P., and Smyth, D.M., Compensating Defects in Highly Donor-Doped BaTiO3, J. Am. Ceram. Soc., 1986, vol. 69, no. 6, pp. 507–510.10.1111/j.1151-2916.1986.tb07453.x ↗
13. Abicht, H.-P., Langhammer, H.T., and Felgner, K.-H., On the Influence of Silicon on Microstructure and Electrical Properties of La-Doped BaTiO3 Ceramics, Mater. Sci. Forum, 1990, vols. 62–64, pp. 355–356.
14. Drofenik, M., Oxygen Partial Pressure and Grain Growth in Donor-Doped BaTiO3, J. Am. Ceram. Soc., 1987, vol. 70, no. 5, pp. 311–314.10.1111/j.1151-2916.1987.tb04999.x ↗