Thermodynamic properties of III–V compounds
Source abstract
Abstract
Available thermodynamic data for III–V compounds have been systematized and critically evaluated. The results demonstrate that the enthalpies of formation Δf H 0(298 K), Gibbs energies Δf G 0(298 K), and standard entropies S 0(298 K) of some of these compounds correlate with their melting points (correlation coefficients from 0.999 to 0.94). A number of other correlations have also been revealed.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Semiconductor materials and interfaces · Electronic Packaging and Soldering Technologies · Chalcogenide Semiconductor Thin Films
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (67)
Show source-provided references
1. Regel’, A.R. and Glazov, V.M., Periodicheskii zakon i fizicheskie svoistva elektronnykh rasplavov (The Periodic Law and Physical Properties of Electronic Melts), Moscow: Nauka, 1978.
2. Ansara, I., Chatillon, C., Lukas, H.L., et al., A Binary Data Base for III–V Compounds Semiconductor Systems, CALPHAD: Comput. Coupling Phase Diagrams Thermochem., 1994, vol. 18, no. 2, pp. 177–222.10.1016/0364-5916(94)90027-2 ↗
3. Li Jingbo, Zhang Weijing, Li Changrong, and Du Zhenmin, Thermodynamic Assessments of Ternary Ga-As-P, Ga-P-Sb, In-As-P, and In-P-Sb Systems, Rare Met. (Beijing, China), 2000, vol. 19, no. 4, pp. 248–254.
4. Li, Ch., Li, J.-B., Du, Z., and Zhang, W., A Thermodynamic Assessment of the Ga-In-P System, J. Phase Equilib., 2000, vol. 21, no. 4, pp. 357–363.10.1361/105497100770339888 ↗
5. Xia, Q., Xia, H., and Ruoff, A.L., Pressure-Induced Rocksalt Phase of Aluminium Nitride: A Metastable Structure at Ambient Condition, J. Appl. Phys., 1993, vol. 73, pp. 8198–8200.10.1063/1.353435 ↗
6. Kim, K., Lambrecht, W.R.L., and Segall, B., Elastic Constants and Related Properties of Tetrahedrally Bonded BN, AlN, GaN, and InN, Phys. Rev. B: Condens. Matter Mater. Phys., 1996, vol. 53, pp. 16310–16326.10.1103/PhysRevB.53.16310 ↗
7. Kubiak, R., Röntgensgraphische Untersuchungen der intermetallische Phasen In5Bi3, In2Bi und InBi zwischen +60 und −135°C, Z. Anorg. Allg. Chem., 1977, vol. 431, pp. 261–267.10.1002/zaac.19774310129 ↗
8. Gorbov, S.I., Thermodynamics of III–V Semiconductors, Itogi Nauki Tekh., Ser.: Khim. Termodin. Ravnovesiya, 1975, vol. 3.
9. Solojenko, V.L. and Peun, T., Compression and Thermal Expansion of Hexagonal Graphite-like Boron Nitride up to 7 GPa and 1800 K, J. Phys. Chem. Solids, 1997, vol. 58, no. 9, pp. 1321–1323.10.1016/S0022-3697(97)00037-1 ↗
10. Dworkin, A.S., Sasmar, D.J., and Van Artsdalen, E.R., Thermodynamic of Boron Nitride; Low Temperature Heat Capacity and Entropy; Heat of Combustion and Formation, J. Chem. Phys., 1954, vol. 22, no. 5, pp. 837–842.10.1063/1.1740199 ↗
11. Gal’chenko, G.L., Kornilov, A.N., and Skuratov, S.M., Enthalpy of Formation of Boron Nitride, Zh. Neorg. Khim., 1960, vol. 5, no. 12, pp. 2651–2654.
12. Gal’chenko, G.L., Timofeev, B.I., and Grinberg, Ya.Kh., Enthalpy of Formation of Boron Monophosphide, Izv. Akad. Nauk SSSR, Neorg. Mater., 1972, vol. 8, no. 4, pp. 634–638.
13. Hillenbrand, D.L. and Hall, W.F., The Vaporisation Behaviour of Boron Nitride and Aluminium Nitride, J. Phys. Chem., 1963, vol. 67, pp. 888–893.10.1021/j100798a041 ↗
14. Termicheskie konstanty veshchestv: Spravochnik (Thermal Constants of Substances: A Handbook), Glushko, V.P., Ed., Moscow: VINITI, 1971, issue 5.
15. Van Vechten, J.A., in Handbooks on Semiconductors, Keller, S.P., Ed., Amsterdam: North-Holland, 1980, vol. 3, pp. 1–111.
16. McChesney, J.B. and Bridenburgh, P.M., Thermal Stability of Indium Nitride at Elevated Temperature and Nitrogen Pressure, Mater. Res. Bull., 1970, vol. 5, pp. 783–782.10.1016/0025-5408(70)90028-0 ↗
17. Massalski, T., Subramanian, P.R., Okamoto, H., and Kacprzac, L., Thermodynamically Improbable Phase Diagrams, Materials Park: ASM International, 1990, 2nd ed.
18. Neugebauer, C.A. and Margrave, J.L., The Heat of Formation of Aluminum Nitride, Z. Anorg. Allg. Chem., 1957, vol. 290, nos. 1–2, pp. 82–86.10.1002/zaac.19572900109 ↗
19. Mah, A.D., King, E.G., Weller, W.W., and Christensen, A.U., Bur. Mines. Rep. Invest., 1961, no. 5716.
20. Jones, R.D. and Rose, K., Thermal Stability of InN, J. Phys. Chem. Solids, 1987, vol. 48, no. 6, pp. 587–590.10.1016/0022-3697(87)90057-6 ↗
21. Kaufman, L., Nell, J., Tatlor, K., and Hayes, F., Calculation of the Ternary Systems III–IV and II–VI Compounds Phases, CALPHAD: Comput. Coupling Phase Diagrams Thermochem., 1981, vol. 5, no. 3, pp. 185–215.10.1016/0364-5916(81)90020-1 ↗
22. Neviak, S.O. and Sandulova, A.V., Thermodynamic Properties of AlP, Izv. Akad. Nauk SSSR, Neorg. Mater., 1974, vol. 10, no. 1, pp. 146–147.
23. Kubaschewski, O. and Alcock, S.B., Metallurgical Thermochemistry, Oxford: Pergamon, 1979, 5th ed.
24. McHale, J.M., Navrotsky, A., and DiSalvo, F.J., Energetic of Ternary Nitride Formation in the (Li,Ca)-(B,Al)-N System, Chem. Mater., 1999, vol. 11, pp. 1148–1152.10.1021/cm981096n ↗
25. Martosudirdjo, S. and Pratt, J.N., Calorimetric Studies of the Heats of Formation of IIIB–VB Adamantine Phases, Thermochim. Acta, 1974, vol. 10, pp. 23–31.10.1016/0040-6031(74)85019-7 ↗
26. Yamaguchi, K., Itagaki, K., and Chang, Y.A., Thermodynamic Analysis of the In-P, Ga-As, In-As, and Al-Sb Systems, CALPHAD: Comput. Coupling Phase Diagrams Thermochem., 1996, vol. 20, no. 4, pp. 439–446.10.1016/S0364-5916(97)00006-0 ↗
27. Coughanowr, C.A., Kattner, U.R., and Anderson, T.J., Assessment of the Al-Sb System, CALPHAD: Comput. Coupling Phase Diagrams Thermochem., 1990, vol. 14, no. 2, pp. 193–202.10.1016/0364-5916(90)90020-Z ↗
28. Sharma, R.C. and Srivastava, V., Phase Equilibria Calculations of Al-Sb, Al-Ga, Al-Ga-Sb Systems, CALPHAD: Comput. Coupling Phase Diagrams Thermochem., 1992, vol. 16, pp. 387–408.10.1016/0364-5916(92)90014-O ↗
29. Balakumar, T. and Medraj, M., Thermodynamic Modeling of the Mg-Al-Sb, CALPHAD: Comput. Coupling Phase Diagrams Thermochem., 2005, vol. 29, no. 1, pp. 24–36.10.1016/j.calphad.2005.03.001 ↗
30. Zajaczkowski, A. and Botor, J., Thermodynamics of the Al-Sb System Determined by Vapor Pressure Measurements, Z. Metallkd., 1995, vol. 86, pp. 590–596.
31. Unlande, J., Onderka, B., Davidov, A., and Schmid-Fetzer, R., Thermodynamics and Phase Stability in the Ga-N System, J. Cryst. Growth, 2003, vol. 256, pp. 33–51.10.1016/S0022-0248(03)01352-6 ↗
32. Leitner, J., Stejskal, J., and Vonka, P., Thermodynamic Aspects of the GaN Deposition from the Gaseous Phase, Mater. Lett., 1996, vol. 28, pp. 197–201.10.1016/0167-577X(96)00057-2 ↗
33. Karpinski, J. and Porowski, S., 1. Equilibrium Pressure of N2 over GaN and Pressure Solution Growth of GaN; 2. High Pressure Thermodynamics of GaN, J. Cryst. Growth, 1984, vol. 66, pp. 1–20.10.1016/0022-0248(84)90070-8 ↗
34. Madar, R., Jacob, G., Hallais, J., and Fruchart, R., High Pressure Solution Growth of GaN, J. Cryst. Growth, 1975, vol. 31, pp. 197–203.10.1016/0022-0248(75)90131-1 ↗
35. Furtado, M. and Jacob, G., Study of the Influence of Annealing Effects in GaN VPE, J. Cryst. Growth, 1983, vol. 64, no. 2, pp. 257–267.10.1016/0022-0248(83)90132-X ↗
36. Ranade, M.R., Tessier, F., Navrotsky, A., and Marchand, R., Calorimetric Determination of InN and Comparison with AlN and GaN, J. Mater. Res., 2001, vol. 16, no. 10, pp. 2824–2831.10.1557/JMR.2001.0389 ↗
37. Davydov, A. and Anderson, T.J., in III–V Materials and Processes III, Moustakas et al., Eds., Pennington: Electrochem. Soc., 1999, vol. 98–18, pp. 38–48.
38. Tmar, M., Gabriel, C., Chatillon, C., and Ansara, J., Critical Analysis and Optimisation of the Thermodynamic Properties and Phase Diagrams in the III–V Compounds: the In-P and Ga-P Systems, J. Cryst. Growth, 1984, vol. 68, pp. 557–580.10.1016/0022-0248(84)90464-0 ↗
39. Ilegams, M., Panish, M.B., and Arthur, J.R., Phase Equilibria and Vapor Pressure in the Ga-P System, J. Chem. Thermodyn., 1974, vol. 6, pp. 157–177.10.1016/0021-9614(74)90259-6 ↗
40. Davydov, A.V. and Zlomanov, V.P., Optimization of the Thermodynamic Properties and Phase Diagram of the Ga-As System, Neorg. Mater., 1994, vol. 30, no. 3, pp. 325–331 [Inorg. Mater. (Engl. Transl.), vol. 30, no. 3, pp. 309–315].
41. Chatillon, C., Ansara, I., Watson, A., and Argent, B.B., Re-assessment of the Thermodynamic Properties and Phase Diagram of the Ga-As and In-As Systems, CALPHAD: Comput. Coupling Phase Diagrams Thermochem., 1990, vol. 14, pp. 203–204.10.1016/0364-5916(90)90021-Q ↗
42. Itagaki, K. and Yamaguchi, K., High Temperature Heat Contents of III–V Semiconductor System, Thermochim. Acta, 1990, vol. 163, pp. 1–12.10.1016/0040-6031(90)80374-8 ↗
43. Yamaguchi, Itagaki, K., Iazawa, A., et al., Measurements Heat of Formation of GaP, InP, GaS, InAs, and InSb, Mater. Trans., JIM, 1994, vol. 35, no. 9, pp. 596–602.10.2320/matertrans1989.35.596 ↗
44. Yu, T.-C. and Brebrick, R.F., Thermodynamic Analysis of the In-Ga-Sb System, Metall. Trans. A, 1994, vol. 25, pp. 2331–2340.10.1007/BF02648854 ↗
45. Brebrick, R.F., Quantitative Fits to the Liquidus Line and High Temperature Thermodynamic Data for InSb, GaSb, InSb, and GaAs, Metall. Trans. A, 1977, vol. 8, pp. 403–415.10.1007/BF02661749 ↗
46. Abbasov, A.S., Mustafaev, F.M., and Suleimenov, D.M., Thermodynamic Properties of Indium Phosphide, Izv. Akad. Nauk AzSSR, Ser. Fiz.-Tekh. Nauk, 1974, no. 4, pp. 65–66.
47. Onderka, B., Unlande, J., and Schmid-Fetzer, R., Thermodynamics and Phase Stability in the In-N System, J. Mater. Res., 2002, vol. 17, no. 12, pp. 3065–3083.10.1557/JMR.2002.0445 ↗
48. Vorob’ev, A.M., Evseeva, G.V., and Zenkevich, L.V., Vapor Pressure over Indium Nitride, Zh. Fiz. Khim., 1971, vol. 45, no. 10, pp. 1501–1504.
49. Gordienko, S.P. and Fenochka, B.V., Vapor Pressure over Indium Nitride, Zh. Fiz. Khim., 1977, vol. 51, no. 2, pp. 530–531.
50. Jones, R.D. and Rose, K., Thermal Stability of InN, J. Phys. Chem. Solids, 1987, vol. 48, no. 6, pp. 587–590.10.1016/0022-3697(87)90057-6 ↗
51. Leitner, J. and Stejskal, J., Thermodynamic Aspects of the Ga1−x InxN Growth by MOCVD, Mater. Lett., 1998, vol. 35, pp. 85–89.10.1016/S0167-577X(97)00225-5 ↗
52. Grzegory, I., Jun, J., Krukowski, S., et al., Crystal Growth of Group III Nitrides under High Nitrogen Pressure, Phys. B (Amsterdam, Neth.), 1993, vol. 185, pp. 99–102.10.1016/0921-4526(93)90221-Q ↗
53. Tmar, M. and Chatillon, C., Refinement of the Vapor Pressure in Equilibrium with InP and InAs by Mass Spectrometry, J. Chem. Thermodyn., 1987, vol. 19, pp. 1053–1063.10.1016/0021-9614(87)90016-4 ↗
54. Pool, M.J., personal communication, 1972 (cited in [25] and [38]).
55. Therpilowski, J., Ratajczak, E., Zaleska, E., and Josiak, J., Thermodynamic Characteristics of the AIIBVI and AIIIBV Type Compounds, Pol. J. Chem., 1982, vol. 56, pp. 627–639.
56. Boom, R., Vendel, P.C.M., and De Boer, F.R., Thermodynamic Properties of Compounds in the Indium-Bismuth System, Acta Metall., 1973, vol. 21, no. 6, pp. 807–812.10.1016/0001-6160(73)90045-X ↗
57. Kalashnikov, Ya.A., Fizicheskaya khimiya veshchestv pri vysokikh davleniyakh (Physical Chemistry of Substances at High Pressures), Moscow: Vysshaya Shkola, 1987.
58. Gurvich, L.V., Veyts, I.V., and Alcock, C.B., Thermodynamic Properties of Individual Substances, New York: Hemisphere, 1989, 4th ed, vol. 1.
59. Schlesinger, M.E., The Thermodynamic Properties of the Phosphorus and Solid Binary Phosphides, Chem. Rev., 2002, vol. 102, pp. 4267–4301.10.1021/cr000039m ↗
60. Vasil’ev, V.P., Nikol’skaya, A.V., and Gerasimov, Ya.I., Thermodynamic Properties of Higher Thallium Sulfides and Some Common Aspects of Group IIIA Monochalcogenides, Dokl. Akad. Nauk SSSR, 1971, vol. 199, no. 5, pp. 1094–1098.
61. Piesbergen, U., Die durchschnittlichcn Atomwärmen der A3B5 Halbleiter AlSb, GaAs, GaSb, InP, InAs, InSb und die Atomwarme des Elements Germanium zwischen 12–273 K, Naturwissenschaften, 1963, vol. 18a, no. 2, pp. 141–147.
62. Demidenko, A.F., Koshchenko, V.I., Sabanova, L.D., and Gran, Yu.M., Low-Temperature Heat Capacity, Entropy, and Enthalpy of Aluminum and Gallium Nitrides, Zh. Fiz. Khim., 1975, vol. 49, no. 6, pp. 1585–1586.
63. Koshchenko, V.I., Demidenko, A.F., Sabanova, L.D., et al., Thermodynamic Properties of Gallium Nitride from 5 to 300 K, Izv. Akad. Nauk SSSR, Neorg. Mater., 1979, vol. 15, no. 9, pp. 1686–1687.
64. Pauling File Binaries Edition, Inorganic Materials: Database and Design System, Villars, P., Ed., 2002.
65. Sychev, V.V., Vasserman, A.A., Kozlov, A.D., et al., Termodinamicheskie svoistva azota (Thermodynamic Properties of Nitrogen), Moscow: Nauka, 1972.
66. Dinsdale, A.T., S.G.T.E. Data for Pure Elements, CALPHAD: Comput. Coupling Phase Diagrams Thermochem., 1991, vol. 15, no. 4, pp. 317–425.10.1016/0364-5916(91)90030-N ↗
67. Pasynkov, V.V. and Sorokin, V.S., Materialy elektronnoi tekhniki (Electronic Materials), Moscow: Lan’, 2004.