journal article·2023-11

Magnetic Properties of Fe1 – xCoxCr2S4 Solid Solutions in the FeCr2S4-Rich Region

G. G. Shabunina, E. V. Busheva, P. N. Vasil’ev, N. N. Efimov, A. D. Denishchenko

Inorganic Materials· Volume 59· Issue 11
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Abstract

Abstract— The magnetic susceptibility of Fe1 – xCoxCr2S4 solid solutions in the FeCr2S4-rich part of the FeCr2S4–CoCr2S4 system has been studied by static and dynamic methods. The magnetic measurements were performed at temperatures from 5 to 300 K in static (50 Oe and 45 kOe) and ac magnetic fields (field amplitude Hac = 1 Oe; ac field frequencies ν = 100, 1000, and 10 000 Hz). We have determined the temperatures of the magnetic transformations in the system and identified their nature. The results demonstrate that the temperature of the ferrimagnetic phase transition (TC) in Fe1 – xCoxCr2S4 increases with increasing cobalt content. The materials with x = 0–0.5 have been shown to undergo a transition to a spin glass state, evidenced by a shift of maxima in temperature dependences of the imaginary part of their dynamic susceptibility.
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OpenAlex topics: Advanced Condensed Matter Physics · Magnetic and transport properties of perovskites and related materials · Multiferroics and related materials

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References (32)

Show source-provided references
1. Ramirez, A.P., Cava, R.J., and Krajewski, J., Colossal magnetoresistance in Cr-based chalcogenide spinels, Nature, 1997, vol. 386, pp. 156–159. https://doi.org/10.1038/386156a010.1038/386156a0 ↗
2. Tokura, Y. and Tomioka, Y., Colossal magnetoresistive manganites, J. Magn. Magn. Mater., 1999, vol. 200, pp. 1–23. https://doi.org/10.1016/S0304-8853(99)00352-210.1016/S0304-8853(99)00352-2 ↗
3. Tsurkan, V., Hemberger, J., Klemm, M., Klimm, S., Loidl, A., Horn, S., and Tidecks, R., Ac susceptibility studies of ferrimagnetic FeCr2S4 single crystals, J. Appl. Phys., 2001, vol. 90, no. 9, pp. 4636–4644. https://doi.org/10.1063/1.140582710.1063/1.1405827 ↗
4. Tsurkan, V., Baran, M., Szymczak, R., Szymczak, H., and Tidecks, R., Spin-glass like states in the ferrimagnet FeCr2S4, Phys. A (Amsterdam, Neth.), 2001, vol. 296, pp. 301–305. https://doi.org/10.1016/S0921-4526(00)00760-210.1016/S0921-4526(00)00760-2 ↗
5. Maurer, D., Tsurkan, V., Horn, S., and Tidecks, R., Ultrasonic study of ferrimagnetic FeCr2S4: evidence for low temperature structural transformations, J. Appl. Phys., 2003, vol. 93, pp. 9173–9176. https://doi.org/10.1063/1.157093010.1063/1.1570930 ↗
6. Tsurkan, V., Zaharko, O., Schrettle, F., Kant, C., Deisenhofer, J., Krug, Von., Nidda, H.A., Felea, V., Lemmens, P., Groza, J.R., Quach, D.V., et al., Structural anomalies and the orbital ground state in FeCr2S4, Phys. Rev. B: Condens. Matter Mater. Phys., 2010, vol. 81, pp. 1–7. https://doi.org/10.1103/PhysRevB.81.18442610.1103/PhysRevB.81.184426 ↗
7. Shen, C., Yang, Z., Tong, R., Li, G., Wang, B., Sun, Y., and Zhang, Y., Magnetic anisotropy-induced spin-reorientation in spinel FeCr2S4, J. Magn. Magn. Mater., 2009, vol. 321, pp. 3090–3092. https://doi.org/10.1016/j.jmmm.2009.05.00910.1016/j.jmmm.2009.05.009 ↗
8. Shen, C., Yang, Z., Tong, R., Li, G., Wang, B., Sun, Y., Zhang, Y., Zi, Z., Song, W., and Pi, L., Magnetic anomaly around orbital ordering in FeCr2S4, J. Appl. Phys., 2011, vol. 109, p. 07E144. https://doi.org/10.1063/1.356244910.1063/1.3562449 ↗
9. Yang, Z.R., Tan, S., and Zhang, Y.H., Abnormal temperature dependence of low-field magnetization of FeCr2–xAlxS4, Appl. Phys. Lett., 2001, vol. 79, no. 22, pp. 3645–3647. https://doi.org/10.1063/1.141903110.1063/1.1419031 ↗
10. Tsurkan, V., Lochmann, M., Krug von Nidda, H.-A., Loidl, A., Horn, S., and Tidecks, R., Electron-spin-resonance studies of the ferrimagnetic semiconductor FeCr2S4, Phys. Rev. B: Condens. Matter Mater. Phys., 2001, vol. 63, p. 125209. https://doi.org/10.1103/PhysRevB.63.12520910.1103/PhysRevB.63.125209 ↗
11. Aminov, T.G., Shabunina, G.G., Efimov, N.N., Busheva, E.V., and Novotortsev, V.M., Magnetic properties of FeCr2S4-based solid solutions in the FeCr2S4–CdCr2S4 system, Inorg. Mater., 2019, vol. 55, no. 3, pp. 210–222. https://doi.org/10.1134/S002016851903003810.1134/S0020168519030038 ↗
12. Shirane, G., Cox, D.E., and Pickart, S.J., Magnetic structures in FeCr2S4 and FeCr2O4, J. Appl. Phys., 1964, vol. 35, pp. 954–955. https://doi.org/10.1063/1.171355610.1063/1.1713556 ↗
13. Lotgering, F.K., Van Stapele, R.P., Van Der Steen, G.H.A.M., and Van Wieringen, J.S., Magnetic properties, conductivity and ionic ordering in Fe1–xCuxCr2S4, J. Phys. Chem. Solids, 1969, vol. 30, pp. 799–804. https://doi.org/10.1016/0022-3697(69)90274-110.1016/0022-3697(69)90274-1 ↗
14. Krupička, S., Physik der Ferrite und der verwandten magnetischen Oxide, Prague: Vieweg+Teubner, 1973.10.1007/978-3-322-83522-2 ↗
15. Gibart, P., Dormann, I.L., and Pellerin, Y., Magnetic properties of FeCr2S4 and CoCr2S4, Phys. Status Solidi, 1969, vol. 36, no. 2, pp. 187–194. https://doi.org/10.1002/pssb.1969036012010.1002/pssb.19690360120 ↗
16. Palmer, H.M. and Greaves, S., Structural, magnetic and electronic properties of Fe0.5Cu0.5Cr2S4, J. Mater. Chem., 1999, vol. 9, pp. 637–640. https://doi.org/10.1039/A809032G10.1039/A809032G ↗
17. Spender, M.S. and Morrish, L.E., Mössbauer study of the ferrimagnetic spinel FeCr2S4, Can. J. Phys., 1972, vol. 50, no. 1, pp. 1125–1138. https://doi.org/10.1139/p72-15510.1139/p72-155 ↗
18. Van Diepen, A.M. and Van Stapele, R.P., Ordered local distortions in cubic FeCr2S4, Solid State Commun., 1973, vol. 13, no. 10, pp. 1651–1653. https://doi.org/10.1016/0038-1098(73)90258-510.1016/0038-1098(73)90258-5 ↗
19. Ito, M., Nagi, Y., Kado, N., Urakawa, S., et al., Magnetic properties of spinel FeCr2S4 in high magnetic field, J. Magn. Magn. Mater., 2011, vol. 323, pp. 3290–3293. https://doi.org/10.1016/j.jmmm.2011.07.04110.1016/j.jmmm.2011.07.041 ↗
20. Aminov, T.G., Busheva, E.V., Shabunina, G.G., and Novotortsev, V.M., Magnetic phase diagram of solid solutions in the CoCr2S4–Cu0.5Ga0.5Cr2S4 system, Russ. J. Inorg. Chem., 2018, vol. 63, no. 4, pp. 519–529. https://doi.org/10.1134/S003602361804002210.1134/S0036023618040022 ↗
21. Aminov, T.G., Busheva, E.V., Shabunina, G.G., and Novotortsev, V.M., Magnetic properties of (Cu0.5In0.5)1 – x-FexCr2S4 (x = 0–0.3) solid solutions, Inorg. Mater., 2018, vol. 54, no. 10, pp. 998–1008. https://doi.org/10.1134/S002016851810001110.1134/S0020168518100011 ↗
22. Delgado, G.E. and Sagredo, V., Structural analysis of the chalcogenide spinel system CoIn(2 – 2x)Cr(2x)S4, Chalcogen. Lett., 2009, vol. 6, no. 12, pp. 641–645. https://chalcogen.ro/641_Delgado.pdf.
23. Ahrenkiel, R.K., Lee, T.H., Lyu, S.L., and Moser, F., Giant magneto-reflectance of CoCr2S4, Solid. State Commun., 1973, vol. 12, pp. 1113–1115. https://doi.org/10.1016/0038-1098(73)90124-510.1016/0038-1098(73)90124-5 ↗
24. Ahrenkiel, R.K. and Coburn, T.J., Hot-pressed CoCr2S4: a magneto-optical memory material, Appl. Phys. Lett., 1973, vol. 22, no. 7, p. 340. https://doi.org/10.1063/1.165466310.1063/1.1654663 ↗
25. Feiner, F., Unified description of the cooperative Jahn–Teller effect in FeCr2S4 and impurity Jahn–Teller effect in CoCr2S4–Fe, J. Phys. C: Solid State Phys., 1982, vol. 15, no. 7, pp. 1515–1524. https://doi.org/10.1088/0022-3719/15/7/01710.1088/0022-3719/15/7/017 ↗
26. Marais, A., Porte, M., Goldstein, I., and Gibart, P., Magnetocrystalline anisotropy of the ferrimagnetic semiconductor CoCr2S4, J. Magn. Magn. Mater., 1980, vols. 15–18, no. 3, pp. 1287–1288. https://doi.org/10.1016/0304-8853(80)90292-910.1016/0304-8853(80)90292-9 ↗
27. Kim, C.S., Ha, M.Y., Ko, H.M., Oh, Y.J., Lee, S.Y., Lee, H.S., Sur, J.C., and Park, J.Y., Crystallographic and magnetic properties of CoxFe1–xCr2S4, J. Appl. Phys., 1994, vol. 75, no. 10, pp. 6078–6080. https://doi.org/10.1063/1.35546310.1063/1.355463 ↗
28. Noda, R., Kamihara, Y., and Matoba, M., Magnetic properties of Fe1 – xCoxCr2S4, J. Appl. Phys., 2006, vol. 99, p. 08F712. https://doi.org/10.1063/1.217741310.1063/1.2177413 ↗
29. Tretinger, L., Gobel, H., and Pink, H., Magnetic semiconducting spinel in the mixed system Co1–xFexCr2S4, Mater. Res. Bull., 1976, vol. 11, pp. 1375–1379. https://doi.org/10.1016/0025-5408(76)90048-910.1016/0025-5408(76)90048-9 ↗
30. Aminov, T.G., Shabunina, G.G., and Busheva, E.V., Dynamic susceptibility of thiochromite FeCr2S4, Russ. J. Inorg. Chem., 2020, vol. 65, no. 2, pp. 193–198. https://doi.org/10.1134/S003602362002002310.1134/S0036023620020023 ↗
31. Mydosh, J.A., Spin glasses: redux: an updated experimental/materials survey, Rep. Prog. Phys., 2015, vol. 78, p. 052501. https://doi.org/10.1088/0034-4885/78/5/05250110.1088/0034-4885/78/5/052501 ↗
32. Benka, G., Bauer, A., Schmakat, P., Säubert, S., Seifert, M., Jorba, P., et al., Interplay of itinerant magnetism and spin-glass behavior in FexCr1–x , Phys. Rev. Mater., 2022, vol. 6, p. 044407. https://doi.org/10.1103/PhysRevMaterials.6.04440710.1103/PhysRevMaterials.6.044407 ↗