journal article·2021-07-30Open access

Physical-Mechanical Properties of Cupola Slag Cement Paste

Carlos Thomas, José Sainz-Aja, Israel Sosa, Jesús Setién, Juan A. Polanco, Ana Cimentada

Applied Sciences· Volume 11· Issue 15

Abstract

The high consumption of natural resources in the industrial sector makes it necessary to implement measures that enable the reuse of the waste generated, seeking to achieve circular economy. This work assesses the viability of an alternative to the use of CEM III B 32.5 R cement in mortars for the internal coating of centrifugally spun cast iron pipes for water piping. The proposal is to reuse the slag generated in the casting process after being finely ground, as an addition mixed with CEM I 52.5 R cement, which is basically Portland clinker. In order to analyse this possibility, an extensive experimental campaign was carried out, including the analysis of the cupola slag (micro-structural and chemical composition, leachates, setting time, vitrification, puzzolanicity and resistance to sulphate) and regarding the mortars (workability and mechanical properties). The experimental programme has shown that the optimum substitution is achieved with a replacement percentage of 20% of the cement, with which similar workability, superior mechanical properties and guaranteed resistance to sulphate attack are obtained. In addition, both economic and environmental savings are achieved by not having to transport or landfill the waste. In addition, the new cement is cheaper than the cement currently used.
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Research context

OpenAlex topics: Recycled Aggregate Concrete Performance · Innovations in Concrete and Construction Materials · Innovative concrete reinforcement materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

LADICIM (Laboratory of Materials Science and Engineering), University of Cantabria, E.T.S. de Ingenieros de Caminos, Canales y Puertos, Av. Los Castros 44, 39005 Santander, Spain

References (43)

Show source-provided references
1. Field evaluation and durability analysis of an eco-friendly prestressed concrete sleeper10.1061/(ASCE)MT.1943-5533.0001109 ↗
2. Tamayo, P., Pacheco, J., Thomas, C., de Brito, J., and Rico, J. (2019). Mechanical and Durability Properties of Concrete with Coarse Recycled Aggregate Produced with Electric Arc Furnace Slag Concrete. Appl. Sci., 10.10.3390/app10010216 ↗
3. Durability aspects in self-compacting siderurgical aggregate concrete10.1016/j.jobe.2021.102268 ↗
4. Sosa, I., Thomas, C., Polanco, J.A., Setién, J., and Tamayo, P. (2020). High Performance Self-Compacting Concrete with Electric Arc Furnace Slag Aggregate and Cupola Slag Powder. Appl. Sci., 10.10.3390/app10030773 ↗
5. Innovative usages of stainless steel slags in developing self-compacting concrete10.1016/j.conbuildmat.2015.10.079 ↗
6. Skrzypkowski, K. (2021). Determination of the Backfilling Time for the Zinc and Lead Ore Deposits with Application of the BackfillCAD Model. Energies, 14.10.3390/en14113186 ↗
7. Raju, K., Ganesh, M.P., Murthy, N., Anirudha, K.V., and Rao, P.R. (2010, January 16–18). Geotechnical characterization of miscellaneous wastes. Proceedings of the GEOtrendz Indian Geotechnical Conference (IGC), II T Bombay, Mumbai, India.
8. Designing more sustainable and greener self-compacting concrete10.1016/j.conbuildmat.2015.02.072 ↗
9. Sainz-Aja, J.A., Carrascal, I.A., Polanco, J.A., Sosa, I., Thomas, C., Casado, J., and Diego, S. (2020). Determination of the optimum amount of superplasticizer additive for self-compacting concrete. Appl. Sci., 10.10.3390/app10093096 ↗
10. Fast fatigue method for self-compacting recycled aggregate concrete characterization10.1016/j.jclepro.2020.123263 ↗
11. Structural, material, mechanical and durability properties and behaviour of recycled aggregates concrete10.1016/j.jobe.2016.02.003 ↗
12. Kou, S. (2006). Reusing Recycled Aggregates in Structural Concrete. [Ph.D. Thesis, Hong Kong Polytechnic University].
13. Sainz-Aja, J., Thomas, C., Polanco, J.A., and Carrascal, I. (2019). High-Frequency Fatigue Testing of Recycled Aggregate Concrete. Appl. Sci., 10.10.3390/app10010010 ↗
14. Influence of curing conditions on recycled aggregate concrete10.1016/j.conbuildmat.2018.04.009 ↗
15. Fatigue failure micromechanisms in recycled aggregate mortar by μCT analysis10.1016/j.jobe.2019.101027 ↗
16. Concrete with fine recycled aggregates: A review10.1080/19648189.2013.851038 ↗
17. Self-compacting recycled aggregate concrete using out-of-service railway superstructure wastes10.1016/j.jclepro.2019.04.386 ↗
18. del Angel, G.G., Aghajanian, A., Tamayo, P., Rico, J., and Thomas, C. (2021). Siderurgical aggregate cement-treated bases and concrete using foundry sand. Appl. Sci., 11.10.3390/app11010435 ↗
19. The greening of the concrete industry10.1016/j.cemconcomp.2008.12.010 ↗
20. A sustainability comparison between green concretes and traditional concrete using an emergy ternary diagram10.1016/j.jclepro.2020.120421 ↗
21. Mechanical behaviour of structural concrete with ground recycled concrete cement and mixed recycled aggregate10.1016/j.jclepro.2020.122913 ↗
22. Water transport and shrinkage in concrete made with ground recycled concrete-additioned cement and mixed recycled aggregate10.1016/j.cemconcomp.2021.103957 ↗
23. Comparison of possibilities the blast furnaceand cupola slag utilization by concrete production
24. Green Concrete by Replacing Coarse Aggregate with Cupola Slag for Environmental Protection10.1007/978-981-32-9578-0_20 ↗
25. Alabi, S.A., and Mahachi, J. (2019). On the development of sustainable and strong concrete. Mater. Today Proc., 918–922.10.1016/j.matpr.2020.05.369 ↗
26. Cupola Furnace Slag: Its Origin, Properties and Utilization
27. Properties of cupola slag as a pozzolana and its effects on partial replacement of cement in a mortar10.1016/0361-3658(82)90048-0 ↗
28. Stroup, W.W., Stroup, R.D., and Fallin, J.H. (2003). Cupola Slag Cement Mixture and Methods of Making and Using the Same. (WO2001060758A9).
29. Reciclaje de escoria granulada de fundición (EGF) como sustitución de parte del cemento en hormigón
30. Investigation on the potentials of cupola furnace slag in concrete
31. Sosa, I., Tamayo, P., Sainz-Aja, J.A., Cimentada, A., Polanco, J.A., Setién, J., and Thomas, C. (2021). Viability of cupola slag as an alternative eco-binder and filler in concrete and mortars. Appl. Sci., 11.10.3390/app11041957 ↗
32. CEN (2011). EN 197-1 Cement Part 1: Composition, Specifications and Conformity Criteria for Common Cements, CEN.
33. CEN (2013). EN 80103:2013 Test Methods of Cements. Physical Analysis. Actual Density Determination, CEN.
34. CEN (2010). EN-196-6 Methods of Testing Cement—Part 6: Determination of Fineness, CEN.
35. CEN (2003). EN 12457-4 Characterisation of Waste—Leaching—Compliance Test for Leaching of Granular Waste Materials and Sludges—Part 4: One Stage Batch Test at a Liquid to Solid Ratio of 10 l/kg for Materials with Particle Size below 10 mm (without or with Size), CEN.
36. CEN (2017). UNE-EN 196-3 Methods of Testing Cement—Part 3: Determination of Setting Times and Soundness, CEN.
37. CEN (2011). EN-196-5 Methods of Testing Cement—Part 5: Pozzolanicity Test for Pozzolanic Cement, CEN.
38. CEN (2012). EN-933-1 Tests for Geometrical Properties of Aggregates—Part 1: Determination of Particle Size Distribution—Sieving Method, CEN.
39. CEN (2018). EN 196-1 Methods of Testing Cement—Part 1: Determination of Strength, CEN.
40. (2004). EN 1015-3, Methods of Test for Mortar for Masonry—Part 3: Determination of Consistency of Fresh Mortar (by Flow Table), (n.d.), DIN.
41. CEN (2020). EN 12350-5 Testing Fresh Concrete—Part 5: Flow Table Test, CEN.
42. Rodrigues, P., Silvestre, J.D., Flores-Colen, I., Viegas, C.A., de Brito, J., Kurad, R., and Demertzi, M. (2017). Methodology for the assessment of the ecotoxicological potential of construction materials. Materials, 10.10.3390/ma10060649 ↗
43. Rodrigues, P., Silvestre, J.D., Flores-colen, I., Viegas, C.A., Ahmed, H.H., Kurda, R., and de Brito, J. (2020). Evaluation of the ecotoxicological potential of fly ash and recycled concrete aggregates use in concrete. Appl. Sci., 10.10.3390/app10010351 ↗