journal article·2021-07-17Open access

Microstructural Characterization of TiC-Reinforced Metal Matrix Composites Fabricated by Laser Cladding Using FeCrCoNiAlTiC High Entropy Alloy Powder

Sangwoo Nam, Hyung Won Lee, In-Ho Jung, Young-Min Kim

Applied Sciences· Volume 11· Issue 14

Abstract

TiC-reinforced metal matrix composites were fabricated by laser cladding and FeCrCoNiAlTiC high entropy alloy powder. The heat of the laser formed a TiC phase, which was consistent with the thermodynamic calculation, and produced a coating layer without interfacial defects. TiC reinforcing particles exhibited various morphologies, such as spherical, blocky, and dendritic particles, depending on the heat input and coating depth. A dendritic morphology is observed in the lower part of the coating layer near the AISI 304 substrate, where heat is rapidly transferred. Low heat input leads to an inhomogeneous microstructure and coating depth due to the poor fluidity of molten pool. On the other hand, high heat input dissolved reinforcing particles by dilution with the substrate. The coating layer under the effective heat input of 50 J/mm2 had relatively homogeneous blocky particles of several micrometers in size. The micro-hardness value of the coating layer is over 900 HV, and the nano-hardness of the reinforcing particles and the matrix were 17 GPa and 10 GPa, respectively.
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Research context

OpenAlex topics: High Entropy Alloys Studies · High-Temperature Coating Behaviors · Additive Manufacturing Materials and Processes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Materials Science and Engineering, Seoul National University, Seoul 08826, Korea

Advanced Joining & Additive Manufacturing R&D Department, Korea Institute of Industrial Technology, Incheon 21999, Korea

Funding

Korea Institute of Industrial Technology

References (36)

Show source-provided references
1. Nanostructured high-entropy alloys with multiple principal elements: Novel alloy design concepts and outcomes10.1002/adem.200300567 ↗
2. Recent studies of the laser cladding of high entropy alloys10.5781/JWJ.2017.35.4.9 ↗
3. The use of high-entropy alloys in additive manufacturing10.1016/j.scriptamat.2014.11.037 ↗
4. Peng, Y.B., Zhang, W., Li, T.C., Zhang, M.Y., Wang, L., Song, Y., Hu, S.H., and Hu, Y. (2019). Microstructures and mechanical properties of FeCoCrNi high entropy alloy/WC reinforcing particles composite coatings prepared by laser cladding and plasma cladding. Int. J. Refract. Met. Hard Mater., 84.10.1016/j.ijrmhm.2019.105044 ↗
5. Decomposition in multi-component AlCoCrCuFeNi high-entropy alloy10.1016/j.actamat.2010.09.023 ↗
6. A review on the various synthesis routes of TiC reinforced ferrous based composites10.1023/A:1019699205003 ↗
7. Microstructure evolution of in-situ (Ti, W) C-Al2O3 particle-reinforced alloy fabricated by gas tungsten arc cladding10.1016/j.surfcoat.2018.09.012 ↗
8. Microstructure and wear resistance of in-situ TiC–Al2O3 particles reinforced Fe-based coatings produced by gas tungsten arc cladding10.1016/j.surfcoat.2015.11.019 ↗
9. In-situ precipitation of TiC upon PTA hardfacing with grey cast iron and titanium for enhanced wear resistance10.1016/j.surfcoat.2012.11.003 ↗
10. Microstructure and wear behavior of atmospheric plasma-sprayed AlCoCrFeNiTi high-entropy alloy coating10.1007/s11665-016-2396-6 ↗
11. Effect of laser irradiation on failure mechanism of TiCp reinforced titanium composite coating produced by laser cladding10.1016/j.jmatprotec.2014.04.035 ↗
12. The influence of combined laser parameters on in-situ formed TiC morphology during laser cladding10.1016/j.surfcoat.2011.06.062 ↗
13. Sliding abrasive wear characteristic of TIG cladded TiC reinforced Inconel825 composite coating10.1016/j.ijrmhm.2017.08.005 ↗
14. Microstructure and mechanical performance of TiC-Inconel825 composite coating deposited on AISI 304 steel by TIG cladding process10.1016/j.jmatprotec.2017.06.042 ↗
15. Effect of pulsed laser parameters on in-situ TiC synthesis in laser surface treatment10.1016/j.optlaseng.2010.12.002 ↗
16. Effect of fluid convection on dendrite arm spacing in laser deposition10.1007/s11663-014-0054-7 ↗
17. Chen, S., Chen, X., Wang, L., Liang, J., and Liu, C. (2017). Laser cladding FeCrCoNiTiAl high entropy alloy coatings reinforced with self-generated TiC particles. J. Laser Appl., 29.10.2351/1.4966052 ↗
18. Cai, Y., Zhu, L., Cui, Y., Shan, M., Li, H., Xin, Y., and Han, J. (2021). Fracture and wear mechanisms of FeMnCrNiCo + x(TiC) composite high-entropy alloy cladding layers. Appl. Surf. Sci., 543.10.1016/j.apsusc.2020.148794 ↗
19. Microstructure and high temperature wear behaviour of in-situ TiC reinforced AlCoCrFeNi-based high-entropy alloy composite coatings fabricated by laser cladding10.1016/j.optlastec.2019.05.006 ↗
20. Microstructural characterisation of high-entropy alloy AlCoCrFeNi fabricated by laser engineered net shaping10.1016/j.jallcom.2015.05.144 ↗
21. Cai, Y.C., Cui, Y., Zhu, L.S., Tian, R.Y., Geng, K.P., Li, H.J., and Han, J. (2021). Enhancing the (FeMnCrNiCo plus TiC) cladding layer by in-situ laser remelting. Surf. Eng.10.1080/02670844.2020.1868651 ↗
22. Concentrated solar energy for in-situ elaboration of wear-resistant composite layers. Part I: TiC and chromium carbide surface enrichment of common steels10.1016/j.surfcoat.2019.08.011 ↗
23. Microstructure and properties of TiB2–TiC–Al2O3 coating prepared by laser assisted SHS and subsequent cladding with micro-/nano-TiO2 as precursor constituent10.1016/j.matdes.2015.10.135 ↗
24. Investigation of heat transfer and fluid flow in activating TIG welding by numerical modeling10.1016/j.applthermaleng.2016.11.008 ↗
25. Intergrowth microstructure and superior wear resistance of (TiB + TiC)/Ti64 hybrid coatings by gas tungsten arc cladding10.1016/j.matdes.2018.11.039 ↗
26. Microstructure and mechanical properties of TiC-Ni coating on AISI304 steel produced by TIG cladding process10.1016/j.jmatprotec.2016.09.018 ↗
27. Effect of laser cladding process parameters on clad quality and in-situ formed microstructure of Fe–TiC composite coatings10.1016/j.surfcoat.2010.08.087 ↗
28. Effects of CeO2 on microstructure and properties of TiC/Ti2Ni reinforced Ti-based laser cladding composite coatings10.1016/j.optlaseng.2019.03.001 ↗
29. Liu, Y., Ding, J., Qu, W., Su, Y., and Yu, Z. (2017). Microstructure evolution of TiC particles in situ, synthesized by laser cladding. Materials, 10.10.3390/ma10030281 ↗
30. Laser cladding composite coating on mild steel using Ni–Cr–Ti–B4C powder
31. Fundamental deformation behavior in high-entropy alloys: An overview10.1016/j.cossms.2017.08.003 ↗
32. Perminov, A., Jurisch, M., Bartzsch, G., Biermann, H., Weißgärber, T., and Volkova, O. (2021). Manufacturing Fe–TiC metal matrix composite by electron beam powder bed fusion from pre-alloyed gas atomized powder. Mater. Sci. Eng. A, 813.10.1016/j.msea.2021.141130 ↗
33. Numerical simulation of molten pool dynamics in high power disk laser welding10.1016/j.jmatprotec.2011.09.011 ↗
34. Evolution of microstructure and mechanical properties of in situ synthesized TiC–TiB2/CoCrCuFeNi high entropy alloy coatings10.1016/j.surfcoat.2015.09.049 ↗
35. On the significance of the H/E ratio in wear control: A nanocomposite coating approach to optimised tribological behaviour10.1016/S0043-1648(00)00488-9 ↗
36. Relationships between hardness, Young’s modulus and elastic recovery in hard nanocomposite coatings10.1016/S0257-8972(01)01714-5 ↗