Standard Enthalpies of Formation of the Bi2Mo3O12, Bi6Mo2Te2O21, and Bi2Te2O8 Complex Oxides
Source abstract
Abstract
Abstract— The tellurium molybdenum bismuth complex oxides Bi2Mo3O12, Bi6Mo2Te2O21, and Bi2Te2O8, promising starting materials for the preparation of bismuth-containing tellurite–molybdate glasses, have been synthesized by heating accurately weighed amounts of orthotelluric acid and ammonium heptamolybdate and bismuth nitrate crystal hydrates and identified by X-ray diffraction. Using reaction calorimetry, the standard enthalpies of formation of the complex oxide have been determined to be −2940.3 ± 39.8 kJ/mol for Bi2Mo3O12, −4128.6 ± 66.2 kJ/mol for Bi6Mo2Te2O21, and −1383.3 ± 11.5 kJ/mol for Bi2Te2O8. These values have been calculated as the difference between the standard enthalpies of solution of the complex oxide and mixtures of constituent binary oxides of corresponding content in concentrated hydrochloric acid.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Catalysis and Oxidation Reactions · Catalytic Processes in Materials Science · Thermal and Kinetic Analysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (31)
Show source-provided references
1. Balueva, K.V., Kut’in, A.M., Plekhovich, A.D., Motorin, S.E., and Dorofeev, V.V., Thermophysical characterization of TeO2−WO3−Bi2O3 glasses for optical applications, J. Non-Cryst. Solids, 2021, vol. 553, p. 120465. https://doi.org/10.1016/j.jnoncrysol.2020.12046510.1016/j.jnoncrysol.2020.120465 ↗
2. Kut’in, A.M., Plekhovich, A.D., Balueva, K.V., and Dorofeev, V.V., Glass transition characteristics and thermodynamic functions of (1 − x)(0.75TeO2 – 0.25WO3) + xLa2O3 glasses, Inorg. Mater., 2018, vol. 54, no. 7, pp. 706–712. https://doi.org/10.1134/S002016851807007510.1134/S0020168518070075 ↗
3. Kut’in, A.M., Plekhovich, A.D., and Sibirkin, A.A., Crystallization kinetics of (TeO2)1−x(MoO3)x glasses studied by differential scanning calorimetry, Inorg. Mater., 2015, vol. 51, no. 12, pp. 1288–1295. https://doi.org/10.1134/S002016851512005510.1134/S0020168515120055 ↗
4. Churbanov, M.F., Sibirkin, A.A., Zamyatin, O.A., Goreva, I.G., and Gavrin, S.A., RF Patent 2587199, Byull. Izobret., 2016, no. 17.
5. Zamyatin, O.A., Leksakov, D.A., Krasnov, M.V., Sibirkin, A.A., and Nosov, Z.K., Glass formation, optical and thermal properties of glasses in the Te2MoO7−Bi-2Mo3O12−ZnWO4 pseudo ternary system, Inorg. Chem. Commun., 2024, vol. 161, no. 3, p. 112102. https://doi.org/10.1016/j.inoche.2024.11210510.1016/j.inoche.2024.112105 ↗
6. Krapchanska, M., Iordanova, R., Dimitriev, Y., and Bachvarova-Nedelcheva, A., Glass formation in the system MoO3−TiO2−Bi2O3, J. Optoelectron., 2010, vol. 12, no. 8, pp. 1692–1695. https://doi.org/10.1007/s10853-011-5441-810.1007/s10853-011-5441-8 ↗
7. Iordanova, R., Aleksandrov, L., and Bachvarova-Nedelcheva, A., AtaaLa, M., and Dimitriev, Y., Glass formation and structure of glasses in B2O3−Bi2O3−MoO3 system, J. Non-Cryst. Solids, 2011, vol. 357, pp. 2663–2668. https://doi.org/10.1016/j.jnoncrysol.2010.12.05610.1016/j.jnoncrysol.2010.12.056 ↗
8. Milanova, M., Iordanova, R., Dimitriev, Y., and Klissurski, D., Glass formation in the MoO3−Bi2O3−PbO system, J. Mater. Sci., 2004, vol. 39, pp. 5591–5593. https://doi.org/10.1023/B:JMSC.0000039296.40866.7c10.1023/B:JMSC.0000039296.40866.7c ↗
9. Ghule, A., Tzing, S.-H., Chang, J.-Y., Ghule, K., Chang, H., and Ling, Y.C., Synthesis and monitoring of α-Bi2Mo3O12 catalyst formation using thermo-Raman spectroscopy, Eur. J. Inorg. Chem., 2004, vol. 8, pp. 1753–1762. https://doi.org/10.1002/ejic.20030060410.1002/ejic.200300604 ↗
10. Carrazán, S.R.G., Martín, C., Mateos, R., and Rives, V., Influence of the active phase structure Bi−Mo−Ti−O in the selective oxidation of propene, Catal. Today, 2006, vol. 112, pp. 121–115. https://doi.org/10.1016/j.cattod.2005.11.04410.1016/j.cattod.2005.11.044 ↗
11. Ji Chul Jung, Howon Lee, Heesoo Kim, Young-Min Chung, Tae Jin Kim, Seong Jun Lee, Seung-Hoon Oh, Yong Seung Kim, and In Kyu Song, A synergistic effect of α-Bi2Mo3O12 and γ-Bi2MoO6 catalysts in the oxidative dehydrogenation of C4 raffinate-3 to 1,3-butadiene, J. Mol. Catal. A: Chem., 2007, vol. 271, pp. 261–265. https://doi.org/10.1016/j.molcata.2007.03.01610.1016/j.molcata.2007.03.016 ↗
12. Martínez-de la Cruz, A. and Obregón Alfaro, S., Synthesis and characterization of nanoparticles of α-Bi2Mo3O12 prepared by co-precipitation method: Langmuir adsorption parameters and photocatalytic properties with rhodamine B, Solid State Sci., 2009, vol. 11, pp. 829–835. https://doi.org/10.1016/j.solidstatesciences.2009.01.00710.1016/j.solidstatesciences.2009.01.007 ↗
13. HongHua Li, KunWei Li, and Hao Wang, Hydrothermal synthesis and photocatalytic properties of bismuth molybdate materials, Mater. Chem. Phys., 2009, vol. 116, pp. 134–142. https://doi.org/10.1016/j.matchemphys.2009.02.05810.1016/j.matchemphys.2009.02.058 ↗
14. Aiswarya, P.M., Shyam Kumar, S., Rajesh Ganesan, and Gnanasekaran, T., Determination of standard molar enthalpies of formation of Bi2Mo3O12 (s), Bi2MoO6 (s), Bi6Mo2O15 (s) and Bi6MoO12 (s) by solution calorimetry, Thermochim. Acta, 2019, vol. 682, p. 178401. https://doi.org/10.1016/j.tca.2019.17840110.1016/j.tca.2019.178401 ↗
15. Kratkii spravochnik fiziko-khimicheskikh velichin (A Brief Handbook of Physicochemical Quantities), Ravdel’, A.A. and Ponomareva, A.M., Eds., Leningrad: Khimiya, 1983, 8th ed.
16. Termicheskie konstanty veshchestv (Thermal Constants of Substances), Glushko, V.P., Ed., Moscow: VINITI, 19665–1972.
17. Barin, I., Thermochemical Data of Pure Substances, Weinheim: VCH, 1885.
18. Karapet’yants, M.Kh. and Karapet’yants, M.L., Osnovnye termodinamicheskie konstanty neorganicheskikh i organicheskikh veshchestv (Principal Thermodynamic Constants of Inorganic and Organic Substances), Moscow: Khimiya, 1968.
19. Veryatin, U.D., Mashirev, V.P., Ryabtsev, N.G., Tarasov, V.I., Rogozkin, B.D., and Korobov, I.V., Termodinamicheskie svoistva neorganicheskikh veshchestv (Thermodynamic Properties of Inorganic Substances), Moscow: Atomizdat, 1965.
20. Ryabin, V.A., Ostroumov, M.A., and Svit, T.F., Termodinamicheskie svoistva veshchestv (Thermodynamic Properties of Substances), Leningrad: Khimiya, 1977.
21. Efimov, A.I., Belorukov, L.P., Vasil’kova, I.V., and Chechev, V.P., Svoistva neorganicheskikh soedinenii. Spravochnik (Properties of Inorganic Compounds: A Handbook), Leningrad: Khimiya, 1983.
22. Mengxiang, D. and Xiouzhen, Y., Bi6Te2Mo2O21—a new artificial crystal and its growth method and physical properties, Chin. J. Geochem., 1989, vol. 8, no. 2, pp. 187–191. https://doi.org/10.1007/BF0284044210.1007/BF02840442 ↗
23. Di Zhou, Hong Wang, Li-Xia Pang, Randall, C.A., and Xi Yao, Bi2O3−MoO3 binary system: an alternative ultralow sintering temperature microwave dielectric, J. Am. Ceram. Soc., 2009, vol. 92, no. 10, pp. 2242–2246. https://doi.org/10.1111/j.1551-2916.2009.03185.x10.1111/j.1551-2916.2009.03185.x ↗
24. Hartmanová, M., Le, M.T., Van Driessche, I., Hoste, S., and Kundracik, F., Phase composition and charge transport in bismuth molybdates, Russ. J. Electrochem., 2005, vol. 41, no. 5, pp. 455–460. https://doi.org/10.1007/s11175-005-0090-310.1007/s11175-005-0090-3 ↗
25. Ji Chul Jung, Heesoo Kim, Ahn Seop Choi, Young-Min Chung, Tae Jin Kim, Seong Jun Lee, Seung-Hoon Oh, and In Kyu Song, Preparation, characterization, and catalytic activity of bismuth molybdate catalysts for the oxidative dehydrogenation of n-butene into 1,3-butadiene, J. Mol. Catal. A: Chem., 2006, vol. 259, pp. 166–170. https://doi.org/10.1016/j.molcata.2006.06.02210.1016/j.molcata.2006.06.022 ↗
26. Yukhin, Yu.M. and Mikhailov, Yu.I., Khimiya vismutovykh soedinenii i materialov (Chemistry of Bismuth Compounds and Materials), Novosibirsk: Sib. Otd. Ross. Akad. Nauk, 2001.
27. Mironov, V.E., Kul’ba, F.Ya., Fedorov, V.A., and Nikitenko, T.F., Potentiometric study of bismuth chloride complexes, Zh. Neorg. Khim., 1963, vol. 8, no. 8, pp. 1852–1856.
28. Nabivanets, B.I. and Kapantsyan, E.E., State of tellurium(IV) in HCl and LiCl solutions, Zh. Neorg. Khim., 1968, vol. 13, no. 7, pp. 1817–1822.
29. Dobrovolski, J. and Korewa, R., Research on some complex compounds containing the $${\text{TeCl}}6^{{2 - }}$$ anion, Rocz. Chem., 1959, vol. 33, pp. 1459–1464.
30. Shapiro, K.Ya., Volk-Karachevskaya, I.V., Kulakova, V.V., and Yurkevich, Yu.N., Molybdenum(VI) extraction from hydrochloric acid solutions with ketones, Zh. Neorg. Khim., 1967, vol. 12, no. 7, pp. 2767–2772.
31. Lidin, R.A., Molochko, V.A., and Andreeva, L.L., Khimi-cheskie svoistva neorganicheskikh veshchestv (Chemical Properties of Inorganic Substances), Moscow: ARG-MAK–MEDIA, 2019.