One-Step Fabrication of Nickel-Electrochemically Reduced Graphene Oxide Nanocomposites Modified Electrodes and Application to the Detection of Sunset Yellow in Drinks

This work describes a straightforward method using one-step preparation of graphene/nickel nanocomposite materials from low-cost materials including graphene oxide and nickel metal. Repetitive CVs lead to the simultaneous deposition of metallic nickel nanoparticles and reduced graphene oxide sheets onto glassy carbon electrode. The obtained nanocomposite-modified surfaces were characterised by cyclic voltammetry, differential pulse voltammetry and field emission scanning electron microscopy. The result demonstrated the ability to produce nickel nanoparticles with a small size of about 20 nm, uniformly dispersed on a graphene oxide matrix. The ERGO-NiNP nanocomposite could be used as a sensor material exhibiting high performance; it is used here in order to detect Sunset Yellow (SY) and for quantification in complex media. The sensor enables rapid quantification of SY with a good linearity (R2 = 0.996) in the range of 10–1000 nM, together with a low detection limit of 3.7 nM (equivalent to 1.7 µg L−1) and a high sensitivity up to 7 µA/µM. The sensor also displays high reliability with a RSD value = 1.08 (n = 10) and good reusability (signal response variation below 5% after 5 detection/cleaning cycles). Finally, we demonstrate how this GCE/ERGO-NiNP sensor can be used for the successful determination of SY in commercial soft drink samples with an acceptable deviation below 6.4% when compared to HPLC method.