Preparation of powders and films of the lithium ion conducting solid electrolyte Li1.3Al0.3Ti1.7(PO4)3
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Abstract
This paper describes a process for the preparation of powders and films of the lithium ion conducting solid electrolyte Li 1.3 Al 0.3 Ti 1.7 (PO 4 ) 3 from peroxide solutions. The use of peroxide solutions ensures the preparation of Li 1.3 Al 0.3 Ti 1.7 (PO 4 ) 3 with a room-temperature electrical conductivity of (4–5) × 10 −4 S/cm by calcining a precursor at 800°C. The synthesized Li 1.3 Al 0.3 Ti 1.7 (PO 4 ) 3 powders were characterized by X-ray diffraction, thermal analysis (DTA/TG), and ionic and electronic conductivity measurements. The growth of Li 1.3 Al 0.3 Ti 1.7 (PO 4 ) 3 solid electrolyte films is described.
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OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Extraction and Separation Processes
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References (14)
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1. Aono, H., Sugimoto, E., Sadaoka, Y., Imanaka, N., and Adachi, G., Ionic Conductivity of the Lithium Titanium Phosphate (Li1 + x MxTi2 − x (PO4)3, M = Al, Sc, Y, and La) Systems, J. Electrochem. Soc., 1989, vol. 136, no. 2, pp. 590–591.10.1149/1.2096693 ↗
2. Aono, H., Sugimoto, E., Sadaoka, Y., et al., Ionic Conductivity of Solid Electrolytes Based on Lithium Titanium Phosphate, J. Electrochem. Soc., 1990, vol. 137, no. 4, pp. 1023–1027.10.1149/1.2086597 ↗
3. Fergus, J.W., Ceramic and Polymeric Solid Electrolytes for Lithium-Ion Batteries, J. Power Sources, 2010, vol. 195, pp. 4554–4569.10.1016/j.jpowsour.2010.01.076 ↗
4. Pinus, I.Yu., Arkhangel’skii, I.V., Zhuravlev, N.A., and Yaroslavtsev, A.B., Cation Mobility in Modified Li1 + x Ti2 − x Gax(PO4)3 Lithium Titanium NASICON Phosphates, Russ. J. Inorg. Chem., 2009, vol. 54, no. 8, pp. 1177–1180.10.1134/S0036023609080026 ↗
5. Nagata, K. and Nanno, T., All Solid Battery with Phosphate Compounds Made through Sintering Process, J. Power Sources, 2007, vol. 174, pp. 832–837.10.1016/j.jpowsour.2007.06.227 ↗
6. Kosova, N.V., Osintsev, D.I., Uvarov, N.F., and Devyatkina, E.T., Lithium Titanium Phosphate As a Cathode, Anode, and Electrolyte for Lithium-Ion Batteries, Khim. Interesakh Ustoich. Razvit., 2005, no. 13, pp. 253–260.
7. Birke, P., Salam, F., Doring, S., and Weppner, W., A First Approach to a Monolithic All Solid State Inorganic Lithium Battery, Solid State Ionics, 1999, vol. 118, pp. 149–157.10.1016/S0167-2738(98)00462-7 ↗
8. Xian Ming Wu, Jin Lian Liu, Run Xiu Li, et al., Preparation and Characterization of Li1 + x Mn2O4/Li1.3Al0.3Ti1.7(PO4)3/Li1 − x Mn2O4 Thin-Film Battery by Spray Technique, Russ. J. Electrochem., 2011, vol. 47, no. 8, pp. 917–922.10.1134/S1023193511080179 ↗
9. Wu, X.M., Liu, J.L., Chen, S., et al., Effect of Sintering Conditions on the Properties of Sol-Gel-Derived Li1.3Al0.3Ti1.7(PO4)3, Ionics, 2010, pp. 827–831.10.1007/s11581-010-0471-9 ↗
10. Xu, X., Wen, Z., Wu, J., and Yang, X., Preparation and Electrical Properties of NASICON-Type Structured Li1.4Al0.4Ti1.6(PO4)3 Glass-Ceramics by the Citric Acid-Assisted Sol-Gel Method, Solid State Ionics, 2007, vol. 178, pp. 29–34.10.1016/j.ssi.2006.11.009 ↗
11. Huang, L., Wen, Z., Wu, M., et al., Electrochemical Properties of Li1.4Al0.4Ti1.6(PO4)3 Synthesized by a Co-Precipitation Method, J. Power Sources, 2011, vol. 196, pp. 6943–6946.10.1016/j.jpowsour.2010.11.140 ↗
12. Gromov, O.G., Kunshina, G.B., Kuz’min, A.P., and Kalinnikov, V.T., Ionic Conductivity of Li1.3Al0.3Ti1.7(PO4)3-Based Solid Electrolytes, Zh. Prikl. Khim. (S.-Peterburg), 1996, vol. 69, no. 3, pp. 433–436.
13. Guseinov, R.M. and Kukoz, F.I., Elektronnye protsessy v tverdykh elektrolitakh (Electronic Processes in Solid Electrolytes), Rostov: Rostovsk. Gos. Univ., 1986.
14. Popovici, D., Nagai, H., Fujishima, S., and Akedo, J., Preparation of Lithium Aluminum Titanium Phosphate Electrolytes Thick Films by Aerosol Deposition Method, J. Am. Ceram. Soc., 2011, vol. 94, no. 11, pp. 3847–3850.10.1111/j.1551-2916.2011.04551.x ↗