Potentialities of Reaction Sintering in the Fabrication of High-Strength Macroporous Ceramics Based on Substituted Calcium Phosphate
Source abstract
Abstract
Calcium alkali metal (potassium and sodium) double and triple phosphates have been synthesized in different ways. Was for the first time used reaction sintering to produce ceramics based on calcium alkali metal mixed phosphates and investigated the densification behavior of mixed phosphate-based multiphase materials during sintering by this method. Was presented the microstructure of polished surfaces of sintered samples differing in phase composition and determined the density of ceramics prepared using reaction mixtures differing in composition. The effect of reaction sintering on the porosity of the ceramics has been assessed. Using stereolithographic printing and reaction sintering, was produced macroporous mixed calcium phosphate-based ceramic implants. Their compressive strength has been determined to be 0.78 ± 0.21 MPa for two-phase samples and 1.02 ± 0.13 MPa for three-phase samples.
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Research context
OpenAlex topics: Bone Tissue Engineering Materials · Advanced ceramic materials synthesis · Advanced materials and composites
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (19)
Show source-provided references
1. Jarcho, M., Calcium phosphate ceramics as hard tissue prosthetics, Clin. Orthop. Relat. Res., 1981, vol. 157, pp. 259–278.10.1097/00003086-198106000-00037 ↗
2. Jarcho, M., Bolen, C.H., Thomas, M.B., Bobick, J., Kay, J.F., and Doremus, R.H., Hydroxylapatite synthesis and characterisation in dense polycrystalline form, J. Mater. Sci., 1976, vol. 11, pp. 2027–2035.https://doi.org/10.1007/PL0002032810.1007/PL00020328 ↗
3. Gross, K.A. and Berndt, C.C., Biomedical application of apatites, Rev. Mineral. Geochem., 2002, vol. 48, no. 1, pp. 631–672.https://doi.org/10.2138/rmg.2002.48.1710.2138/rmg.2002.48.17 ↗
4. Berger, G., Gildenhaar, R., and Ploska, U., Rapid resorbable, glassy crystalline materials on the basis of calcium alkali orthophosphates, Biomaterials, 1995, vol. 16, no. 16, pp. 1241–1248.https://doi.org/10.1016/0142-9612(95)98131-W10.1016/0142-9612(95)98131-W ↗
5. Evdokimov, P.V., Putlyaev, V.I., Ivanov, V.K., Garshev, A.P., Shatalova, T.B., Orlov, N.K., Klimashina, E.S., and Safronova, T.V., Phase equilibria in the tricalcium phosphate–mixed calcium sodium (potassium) phosphate systems, Russ. J. Inorg. Chem., 2014, vol. 59, pp. 1219–1227.https://doi.org/10.7868/S0044457X1411008710.7868/S0044457X14110087 ↗
6. Ievlev, V.M., Putlyaev, V.I., Safronova, T.V., and Evdokimov, P.V., Additive technologies for making highly permeable inorganic materials with tailored morphological architectonics for medicine, Inorg. Mater., 2015, vol. 51, pp. 1297–1315.https://doi.org/10.1134/S002016851513003810.1134/S0020168515130038 ↗
7. Ando, J., Phase diagrams of Ca3(PO4)2–Mg3(PO4)2 and Ca3(PO4)2–CaNaPO4, Bull. Chem. Soc. Jpn., 1958, vol. 31, pp. 201–205.10.1246/bcsj.31.201 ↗
8. Suk-Joong L. Kang, Sintering: Densification, Grain Growth and Microstructure, London: Butterworth, 2004.
9. Champion, E., Sintering of calcium phosphate bioceramics, Acta Biomater., 2013, vol. 9, pp. 5855–5875.10.1016/j.actbio.2012.11.029 ↗
10. Dey, A. and Chakrabarti, O., Investigation on synthesis of cordierite bonded porous SiC ceramics with emphasis on bond phase formation, Mater. Chem. Phys., 2019, vol. 222, pp. 275–285.10.1016/j.matchemphys.2018.10.025 ↗
11. Guo, W.-M., Wu, L.-X., Ma, T., You, Y., and Lin, H.-T., Rapid fabrication of Si3N4 ceramic by reaction-bonding and pressureless sintering, J. Eur. Ceram. Soc., 2016, vol. 36, no. 16, pp. 3919–3924.10.1016/j.jeurceramsoc.2016.06.007 ↗
12. Orlov, N.K., Evdokimov, P.V., Milkin, P.A., Garshev, A.V., Putlayev, V.I., Grebenev, V.V., and Günster, J., Phase equilibria in CaNaPO4–CaKPO4 system and their influence on formation of bioceramics based on mixed Ca–K–Na phosphates, J. Eur. Ceram. Soc., 2019, vol. 39, no. 16, pp. 5410–5422. https://doi.org/10.1016/j.jeurceramsoc.2019.07.04410.1016/j.jeurceramsoc.2019.07.044 ↗
13. Niu, J.L., Zhang, Z.X., and Jiang, D.Z., Investigation of phase evolution during the formation of calcium potassium sodium orthophosphate, Mater. Chem. Phys., 2002, vol. 78, no. 2, pp. 308–312.
14. Niu, J.L., Zhang, Z.X., Jiang, D.Z., Yang, S.H., et al., Preparation, structure and solubility of Ca2KNa(PO4)2, J. Mater. Sci., 2001, vol. 36, no. 15, pp. 3805–3808.10.1023/A:1017994321377 ↗
15. Orlov N.K., Putlyaev V.I., Evdokimov P.V., Safronova T.V., Garshev A.V., and Mil’kin, P.A., Composite bioceramics engineering based on analysis of phase equilibria in the Ca3(PO4)2–CaNaPO4–CaKPO4 system, Inorg. Mater., 2019, vol. 55, no. 5, pp. 516–523.https://doi.org/10.1134/S002016851905015710.1134/S0020168519050157 ↗
16. Znamierowska, T., Uklad Ca3(PO4)2–CaKPO4–CaNaPO4. Czesc I, Zesz. Nauk. Politech., 1982, vol. 709, pp. 33–43.
17. Znamierowska, T., Uklad Ca3(PO4)2–CaKPO4–CaNaPO4. Czesc II, Zesz. Nauk. Politech., 1982, vol. 709, pp. 45–56.
18. Tikhonov A.A., Evdokimov P.V., Putlyaev V.I., Safronova T.V., and Filippov Ya.Yu., On the choice of the architecture of osteoconductive bioceramic implants, Inorg. Mater.: Appl. Res., 2019, vol. 10, no. 1, pp. 242–247.https://doi.org/10.1134/S207511331901032510.1134/S2075113319010325 ↗
19. Putlyaev, V.I., Evdokimov, P.V., Safronova, T.V., Klimashina, E.S., and Orlov, N.K., Fabrication of osteoconductive Ca3 – xM2x(PO4)2 (M = Na, K) calcium phosphate bioceramics by stereolithographic 3D printing, Inorg. Mater., 2017, vol. 53, no. 5, pp. 529–535.https://doi.org/10.1134/S002016851705016810.1134/S0020168517050168 ↗