Bismuth Monocation IR Photoluminescence in Mixed Cyclotriphosphates of Alkali and Alkaline Earth Metals
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Abstract
Abstract— Polycrystalline samples of the mixed cyclotriphosphates KMgP3O9, KCaP3O9, RbMgP3O9, RbCaP3O9, CsCaP3O9, and CsSrP3O9 containing Bi+ bismuth impurity monocations have been prepared via crystallization from a melt of appropriate composition. The presence of Bi+ is responsible for broadband bright near-IR luminescence in all of the materials. The shape of the photoluminescence and photoluminescence excitation spectra has been shown to be determined by the nature of the alkaline earth cation in the composition in the cyclotriphosphates and the symmetry of the local environment of the Bi+ ions under the assumption that they isomorphously substitute for alkali metal cations in the crystal lattice of the cyclotriphosphates. The characteristic photoluminescence decay time is also determined by the symmetry of the local environment of Bi+.
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OpenAlex topics: Luminescence Properties of Advanced Materials · Crystal Structures and Properties · Mesoporous Materials and Catalysis
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References (35)
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