journal article·2019-08

Hydrolysis and Chemical Activity of Aqueous TiCl4 Solutions

E. N. Kuzin, N. E. Krutchinina

Inorganic Materials· Volume 55· Issue 8
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Abstract

Abstract— We have studied the physical and chemical properties of aqueous titanium(IV) chloride solutions. The results demonstrate that, during TiCl4 dissolution in water, only part of the titanium(IV) chloride hydrolyzes. Aqueous solutions with up to 60 wt % TiCl4 contain unhydrolyzed TiCl4 species. Titanium(IV) chloride solutions have an increased chemical activity for aluminum hydroxide and aluminum oxide compared to hydrochloric acid. It has been shown that reactions of metallic aluminum with titanium(IV) chloride solutions can yield lower titanium(III) chlorides.
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Research context

OpenAlex topics: Extraction and Separation Processes · Chemical Synthesis and Characterization · Catalysis and Hydrodesulfurization Studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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