Adsorption of Yttrium Ions on 3-Amino-5-Hydroxypyrazole Impregnated Bleaching Clay, a Novel Sorbent Material
Source abstract
Abstract
In this work, spent bleaching clay (SBC) was treated with ethyl acetate and impregnation with 3-amino-5-hydroxypyrazole (AHIBC) that utilized as economical sorbent material. The uptake of yttrium ions from aqueous solution using AHIBC was studied under batch process as a function of pH of the solution, contact time, adsorbent dosage, Yttrium ions concentration, and ambient temperature. The adsorption equilibrium was achieved at the value of pH = 6.0 and agitation time of 60 min at room temperature. The utmost adsorption capacity of Y(III) ions on AHIBC was 171.32 mg·g−1. Kinetic, isotherm, and thermodynamic models were applied to the experimental data obtained. Adsorption follows a pseudo–second–order kinetic model, while the adsorption isotherm fits the Langmuir model. A negative value of Gibbs free energy ΔG° revealed that the adsorption of the Y ions on the AHIBC adsorbent was spontaneously in nature. In addition, the electrostatic interaction process between the metal ions and AHIBC was favorable. The negative value of ΔH° states that Y ions adsorption was an exothermic process. Desorption efficiency reduced from 97% to 80% after eight consecutive rounds.
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Research context
OpenAlex topics: Extraction and Separation Processes · Radioactive element chemistry and processing · Adsorption and biosorption for pollutant removal
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Nuclear Materials Authority, Maadi, Cairo P.O. Box 530, Egypt
Chemistry Department, Faculty of Science, Ain Shams University, Cairo 11566, Egypt
Center for Applied Physics and Radiation Technologies, School of Engineering and Technology, Sunway University, Bandar Sunway 47500, Malaysia
Department of Radiologial Sciences, College of Applied Medical Sciences, Taif University, Taif 21944, Saudi Arabia
Department of Clinical Laboratories Sciences, College of Applied Medical Sciences, Taif University, P.O. Box 11099, Taif 21944, Saudi Arabia
Department of Nuclear Medicine Research, Institute for Research and Medical Consultations, Imam Abdulrahman Bin Faisal University, Dammam 31441, Saudi Arabia
Department of Physics, Faculty of Science, Isra University, Amman 11622, Jordan
Institute of Physics and Technology, Ural Federal University, St. Mira, 19, 620002 Yekaterinburg, Russia
Funding
Taif University
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