journal article·2021-11-09Open access

Petrogenesis of Neoproterozoic Ultramafic Rocks, Wadi Ibib–Wadi Shani, South Eastern Desert, Egypt: Constraints from Whole Rock and Mineral Chemistry

El Saeed R. Lasheen, Gehad M. Saleh, Farrage M. Khaleal, Mamdooh Alwetaishi

Applied Sciences· Volume 11· Issue 22

Abstract

This contribution deals with new geology, petrography, and bulk-rock/mineral chemistry of the poorly studied ultramafics of Wadi Ibib–Wadi Shani (WI–WS) district, South Eastern Desert, Egypt. These ultramafics are dismembered ophiolitic rocks that can be subdivided into serpentinites and serpentinized peridotites. Primary minerals such as olivine and pyroxene are absent in serpentinites, but relics of them occur in serpentinized peridotites. Pseudomorph after olivine is indicated by common hourglass textures with less mesh, whilst schistose bastites reflect a pyroxene pseudomorph. Chromite can be subdivided into Cr-spinel and Al-spinel. Cr-spinel ranges from chromite to magnesochromite in composition, whereas Al-spinel belongs to the spinel field. Cr-spinel includes YCr (Cr/(Cr+Al+Fe+3), YAl (Al/(Al+Cr+Fe+3), and YFe+3 (Fe+3/(Fe+3+Al+Cr), similar to forearc peridotite, whilst Al-spinel is more similar to abyssal peridotite, and may be formed during inanition of subduction processes in proto forearc environments. The main secondary minerals are tremolite, talc, and chlorite—which is subdivided into pycnochlorite and diabantite—and their temperature ranges from 174 to 224 °C. The examined rocks had undergone high partial melting degrees (>25%), as indicated by the Cr# of their unaltered cores (Cr-spinel, >0.6), whole rocks (Al2O3, SiO2, CaO, and MgO), trace and REEs, depleted Na2O, Al2O3, and Cr2O3 of clinopyroxene, and high forsterite content ((Fo = 100 Mg/Mg + Fe), av. 95.23 mol%), consistent with forearc settings.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Geological and Geochemical Analysis · Geochemistry and Geologic Mapping · earthquake and tectonic studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Geology Department, Faculty of Science, Al-Azhar University, Cairo P.O. Box 11884, Egypt

Nuclear Materials Authority, El Maadi, Cairo P.O. Box 530, Egypt

Department of Civil Engineering, College of Engineering, Taif University, P.O. Box 11099, Taif 21944, Saudi Arabia

References (79)

Show source-provided references
1. Kusky, T.M. (2004). Neoproterozoic ophiolites of the Arabian-Nubian Shield, Precambrian ophiolites and related rocks. Developments in Precambrian Geology, Elsevier.
2. Dixon, T.H. (1979). The Evolution of Continental Crust in the Late Precambrian Egyptian Shield. [Ph.D. Thesis, University California].
3. Pan-African (intraplate and subduction-related?) metasomatism in the Fawakhir ophiolitic serpentinites, Central Eastern Desert of Egypt: Mineralogical and geochemical evidences10.1007/s12517-011-0319-2 ↗
4. Hamimi, Z., Arai, S., Fowler, A.R., and El-Bialy, M.Z. (2021). The Ophiolite-Dominated Suprastructure, Eastern Desert, Egypt. The Geology of the Egyptian Nubian Shield. Regional Geology Reviews, Springer.10.1007/978-3-030-49771-2 ↗
5. Neoproterozoic formation and evolution of Eastern Desert continental crust—the importance of the infrastructure-superstructure transition10.1016/j.jafrearsci.2017.01.001 ↗
6. Zoheir, B., Abd El-Rahman, Y., Kusky, T., and Xiong, F. (2021). New SIMS zircon U-Pb ages and oxygen isotope data for ophiolite nappes in the Eastern Desert of Egypt: Implications for Gondwana assembly. Gondwana Res.10.1016/j.gr.2021.09.022 ↗
7. Petrology of the Motaghairat mafic ultramafic complex, Eastern Desert, Egypt: A high-Mg post-collisional extension-related layered intrusion10.1016/j.jseaes.2015.11.015 ↗
8. Ultramafic hosting talc, chromite and uranium-bearing magnesite of Sol Hamed ophiolites South Eastern Desert, Egypt; petrology, geochemistry and tectonic evolution
9. Post-collisional tectonomagmatic evolution in the northern Arabian-Nubian Shield: Time constraints from ion-probe U-Pb dating of zircon10.1144/0016-76492007-169 ↗
10. A review of the Cu-Ni sulfide deposits in the Chinese Tianshan and Altay orogens (Xinjiang Autonomous Region, NW China): Principal characteristics and ore forming processes10.1016/j.jseaes.2007.10.006 ↗
11. Two ultramafic rock types in the Hongseong area, South Korea: Tectonic significance for northeast Asia10.1016/j.lithos.2013.04.014 ↗
12. Highly siderophile elements and Os isotope constraints on the genesis of peridotites from the Kızıldağ ophiolite, southern Turkey10.1016/j.lithos.2020.105583 ↗
13. Carbonation of ophiolitic ultramafic rocks: Listvenite formation in the Late Cretaceous ophiolites of eastern Iran10.1016/j.lithos.2019.105307 ↗
14. Bursnal, J.T. (1989). Geochemical evidence on the source of fluids and solutes for shear zone hosted mesothermal Au deposits. Mineralization in Shear Zones, Geological Association of Canada. Geological Association of Canada, 6 (Short Course Notes).
15. Review of late Proterozoic sutures, ophiolitic mélanges and tectonics of eastern Egypt and north Sudan10.1007/BF01083226 ↗
16. Petrological characteristics and geochemical compositions of the Neotethyan Mersin ophiolite (southern Turkey): Processes of melt depletion, refertilization, chromitite formation and oceanic crust generation10.1016/j.jseaes.2019.01.003 ↗
17. Geochemistry of subduction zone serpentinites: A review10.1016/j.lithos.2013.05.019 ↗
18. Neoproterozoic serpentinites from the Eastern Desert of Egypt: Insights into Neoproterozoic mantle geodynamics and processes beneath the Arabian-Nubian Shield10.1016/j.precamres.2016.10.006 ↗
19. Saleh, G.M. (2005). Geochemical characteristic of some mineralization in wadi Ibib—Um Rasayn—G. Madara area, South Eastern Desert, Egypt, Report PP 57.
20. Rapid analysis of silicate, carbonate and phosphate rocks, U.S
21. Hemley, R.J. (1998). Mineralogy and composition of the upper mantle. Ultrahigh Earth Sciences—Pressure mineralogy, Harvard University. Reviews in mineralogy 37.10.1515/9781501509179 ↗
22. Neoproterozoic (835–720 Ma) serpentinites in the Eastern Desert, Egypt: Fragments of fore-arc mantle10.1086/518052 ↗
23. Nomenclature of pyroxenes10.1180/minmag.1988.052.367.15 ↗
24. Mantle petrology and mineralogy of the Thetford Mines ophiolite complex10.1016/j.lithos.2007.06.017 ↗
25. The role of aluminum in igneous clinopyroxenes with relation to their parentage10.2475/ajs.260.4.267 ↗
26. A note on compositional variation of olivine and pyroxene in thermally metamorphosed ultramafic complexes from SW Japan. Okayama University
27. Geochemical character of serpentinites associated with high- to ultrahigh-pressure metamorphic rocks in the Alps, Cuba, and the Himalayas: Recycling of elements in subduction zones10.1029/2007GC001594 ↗
28. Peridotites from the Mariana Trough: First look at the mantle beneath an active back-arc basin10.1007/s00410-001-0329-2 ↗
29. The range of spinel composition in terrestrial mafic ultramafic rocks10.1093/petrology/42.12.2279 ↗
30. Spinel group minerals in metamorphosed ultramafic rocks from Río de Las Tunas belt, Central Andes, Argentina
31. Chromian spinel composition and platinum-group element mineralogy of chromitites from the Milia area, Pindos ophiolite complex, Greece10.3749/canmin.47.5.1037 ↗
32. Petrographic, geochemical and SHRIMP U-Pb titanite age characterization of the Thabazimbi mafic sills: Extended time frame and a unifying Petrogenetic model for the Bushveld Large Igneous Province10.1016/j.precamres.2013.02.002 ↗
33. Serpentinization. A review10.1016/0024-4937(76)90030-X ↗
34. Deer, W.A., Howie, R.A., and Zussman, J. (1992). An Introduction to the Rock Forming Minerals, Longman. [2nd ed.].
35. A new review of the chlorite
36. A chlorite solid solution geothermometer: The Los Azufres (Mexico) geothermal system10.1007/BF00413350 ↗
37. Chloritization of the hydrothermally altered bedrock at the Igarape Bahia gold deposite, Carajas, Brazil10.1007/BF00208874 ↗
38. Chemical variations of mineral inclusions in Neoproterozoic high-Cr chromitites from Egypt: Evidence of fluids during chromitite genesis10.1016/j.lithos.2015.11.029 ↗
39. Geochemistry of Ocean Floor and Fore-arc Serpentinites: Constraints on the Ultramafic Input to Subduction Zones
40. Nomenclature of amphiboles: Report of the subcommittee on amphiboles of the International Mineralogical Association, Commission on New Minerals and Mineral Names: American Mineralogist
41. Titanium and alkalies in amphiboles in metamorphism: Doklady of the Academy of Sciences U.S.S.R
42. The effects of recalculation on estimates of temperatures and oxygen fugacity from analyses of multicomponent iron-titanium oxides
43. Serpentinization of peridotites from the southern Mariana forearc10.1016/j.pnsc.2009.04.004 ↗
44. Bulk-rock major and trace element compositions of abyssal peridotites: Implications for mantle melting, melt extraction and post-melting processes beneath mid-ocean ridges10.1093/petrology/egh068 ↗
45. Carlson, R.W. (2003). Orogenic, ophiolitic, and abyssal peridotites. The Mantle and Core: Treatise on Geochemistry, Elsevier.
46. Composition of the depleted mantle10.1029/2003GC000597 ↗
47. Cosmochemical estimates of Mantle Composition
48. Floyd, P.A. (1991). Oceanic Basalts, Blachie and Son Ltd.10.1007/978-1-4615-3540-9 ↗
49. Petrological studies of peridotites from diapiric serpentinite seamounts in the Izu–Ogasawara–Mariana fore-arc, LEG125
50. Serpentinites of the Zermatt-Saas ophiolite complex and their texture evolution10.1111/j.1525-1314.2004.00503.x ↗
51. Chemical and Isotopic Systematics of Oceanic Basalts: Implications for Mantle Composition and Processes10.1144/GSL.SP.1989.042.01.19 ↗
52. Geology of supra-subduction zones-implications for the origin of ophiolites
53. The role of Chlorine in serpentinization10.1007/BF00373568 ↗
54. Nature of serpentinization and carbonation of ophiolitic peridotites (Eastern Desert, Egypt): Constrains from stable isotopes and whole-rock geochemistry10.1007/s12517-017-3215-6 ↗
55. Stability of chrysotile and antigorite in serpentinite multisystem
56. Serpentinite: What, why, where?10.2113/gselements.9.2.99 ↗
57. Alteration and geochemical patterns in the 3.7–3.8 Ga Isua greenstone belt, West Greenland10.1016/S0301-9268(03)00095-0 ↗
58. Uner, T. (2019). Listwaenitization and enrichment of precious metals in the hydrothermal mineralization zones of serpentinites in Sugeçer-Van (Eastern Anatolia, Turkey). Geochem. Explor. Environ. Anal., 25.10.1144/geochem2018-087 ↗
59. Coexistence of abyssal and ultra-depleted SSZ type mantle peridotites in a Neo-Tethyan Ophiolite in SW Turkey: Constraints from mineral composition, whole-rock geochemistry (major–trace–REE–PGE) and Re–Os isotope systematic
60. Coupled major and trace elements as indicators of the extent of melting in mid-ocean-ridge peridotites10.1038/35070546 ↗
61. Geochemistry and tectonic significance of peridotites from the South Sandwich arc-basin system, south Atlantic10.1007/s004100050572 ↗
62. Petrogenesis of the Kangjinla Peridotite in the Luobusa Ophiolite, Southern Tibet10.1016/j.jseaes.2011.05.007 ↗
63. Geochemical constraints on the origin and tectonic setting of the serpentinized peridotites from the Paleoproterozoic Nyong series, Eseka area, SW Cameroon
64. The Gabal Gerf complex: A Precambrian N-MORB ophiolite in the Nubian Shield, NE Africa10.1016/0009-2541(95)00018-H ↗
65. Continental back-arc basin origin of some ophiolites from the Eastern Desert of Egypt10.1007/s00710-004-0052-6 ↗
66. The origin and significance of crustal minerals in ophiolitic chromitites and peridotites10.1016/j.gr.2014.06.003 ↗
67. The composition of the Earth10.1016/0009-2541(94)00140-4 ↗
68. Geochemical and geochronological study of early carboniferous volcanic rocks from the West Junggar: Petrogenesis and tectonic implications10.1016/j.jseaes.2011.01.006 ↗
69. Chemistry of chromian spinel in volcanic rocks as a potential guide to magma chemistry10.1180/minmag.1992.056.383.04 ↗
70. Cordilleran ophiolites: A reappraisal of distinctive tectono-magmatic features of supra-subduction complexes in relation to subduction mode10.1016/j.tecto.2004.07.034 ↗
71. The abundance of major, minor and trace elements in the earth’s mantle as derived from primitive ultramafic nodules
72. Hydrous partial melting of lherzolite at 1 GPa: The effect of H2O on the genesis of basaltic magmas. Earth Planet
73. Chromian spinel as a petrogenetic indicator in abyssal and alpine type peridotites and spatially associated lavas: Contrib10.1007/BF00373711 ↗
74. Chromian spinel-silicate chemistry in ultramafic rocks of the Jijal complex, Northwestern Pakistan10.1093/petrology/31.3.667 ↗
75. Solubility of Ca and Al in orthopyroxene from spinel peridotite: An improved version of an empirical geothermometer10.1007/BF00321986 ↗
76. The Olivine-Orthopyroxene-Spinel Oxygen Geobarometer, the Nickel Precipitation Curve, and the Oxygen Fugacity of the Earth’s Upper Mantle10.1093/petrology/28.6.1169 ↗
77. High pressure experimental calibration of the olivine-orthopyroxene-spinel oxygen geobarometer: Implications for the oxidation state of the upper mantle10.1007/BF00311183 ↗
78. Petrology and geochemistry of ophiolitic ultramafic rocks and chromitites across the Eastern Desert of Egypt: Insights into the composition and nature of a Neoproterozoic mantle and implication for the evolution of SSZ system10.1016/j.precamres.2019.105565 ↗
79. Ophiolites of the Central Asian Orogenic Belt: Geochemical and petrological characterization and tectonic settings10.1016/j.gsf.2018.12.007 ↗