journal article·2023-07-19Open access

Rare Earth Elements Recovery from Primary and Secondary Resources Using Flotation: A Systematic Review

Pongsiri Julapong, Apisit Numprasanthai, Ladda Tangwattananukul, Onchanok Juntarasakul, Palot Srichonphaisarn, Kosei Aikawa, Ilhwan Park, Mayumi Ito, Carlito Baltazar Tabelin, Theerayut Phengsaart

Applied Sciences· Volume 13· Issue 14

Abstract

Rare earth minerals (REMs) contain rare earth elements (REEs) that are important in modern technologies due to their unique magnetic, phosphorescent, and catalytic properties. However, REMs are not only non-renewable resources but also non-uniformly distributed on the Earth’s crust, so the processing of REE-bearing secondary resources via recycling is one potential route to ensure the long-term sustainability of REE supply. Flotation—a method that separates materials based on differences in their surface wettability—is a process applied for both mineral processing and recycling of REEs, especially when the particles are fine and/or a high-purity product is required. In this review, studies about rare earth flotation from 2012 to 2021 were systematically reviewed using the PRISMA guideline. It was found that most REM flotation research works focused on finding better collectors and depressants while, for recycling, studies on advanced flotation techniques like froth flotation, ion flotation, solvent sublation, electroflotation, and adsorbing colloid flotation with an emphasis on the recovery of dissolved REEs from aqueous solutions dominated.
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Research context

OpenAlex topics: Extraction and Separation Processes · Minerals Flotation and Separation Techniques · Recycling and Waste Management Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Mining and Petroleum Engineering, Faculty of Engineering, Chulalongkorn University, Bangkok 10330, Thailand

Department of Mining and Materials Engineering, Faculty of Engineering, Prince of Songkla University, Songkhla 90110, Thailand

Department of Earth Sciences, Faculty of Science, Kasetsart University, Bangkok 10900, Thailand

Division of Sustainable Resources Engineering, Faculty of Engineering, Hokkaido University, Sapporo 060-8628, Japan

Department of Materials and Resources Engineering Technology, College of Engineering, Mindanao State University–Iligan Institute of Technology, Iligan City 9200, Philippines

Resource Processing and Technology Center, Research Institute of Engineering and Innovative Technology, Mindanao State University–Iligan Institute of Technology, Iligan City 9200, Philippines

Funding

Chulalongkorn University

References (100+)

Show source-provided references
1. Rare earth elements: A review of applications, occurrence, exploration, analysis, recycling, and environmental impact10.1016/j.gsf.2018.12.005 ↗
2. U.S. Geological Survey (2021). Mineral Commodity Summaries 2021.
3. Surface chemistry considerations of gangue dissolved species in the bastnaesite flotation system10.1016/j.fmre.2021.09.007 ↗
4. Dostal, J. (2017). Rare earth element deposits of alkaline igneous rocks. Resources, 6.10.3390/resources6030034 ↗
5. Klaus, J.H., and Schulz, J. (2017). Rare-Earth Elements, Critical Mineral Resources of the United States—Economic and Environmental Geology and Prospects for Future Supply.
6. Verplanck, P.L., Van Gosen, B.S., Seal, R.R., and McCafferty, A.E. (2014). A Deposit Model for Carbonatite and Peralkaline Intrusion-Related Rare Earth Element Deposits, U.S. Geological Survey Scientific Investigations Report 2010–5070-J.10.3133/sir20105070J ↗
7. Copper and critical metals production from porphyry ores and E-wastes: A review of resources availability, processing/recycling challenges, socio-environmental aspects, and sustainability issues10.1016/j.resconrec.2021.105610 ↗
8. Cincinnati, O.H. (2012). Rare Earth Elements: A Review of Production, Processing, Recycling, and Associated Environmental Issues, EPA 600/R-12/572.
9. Park, I., Kanazawa, Y., Sato, N., Galtchandmani, P., Jha, M.K., Tabelin, C.B., Jeon, S., Ito, M., and Hiroyoshi, N. (2021). Beneficiation of Low-Grade Rare Earth Ore from Khalzan Buregtei Deposit (Mongolia) by Magnetic Separation. Minerals, 11.10.3390/min11121432 ↗
10. Depression of lead-activated sphalerite by pyrite via galvanic interactions: Implications to the selective flotation of complex sulfide ores10.1016/j.mineng.2020.106367 ↗
11. Gold recovery from shredder light fraction of E-waste recycling plant by flotation-ammonium thiosulfate leaching10.1016/j.wasman.2018.04.039 ↗
12. Conventional and recent advances in gravity separation technologies for coal cleaning: A systematic and critical review10.1016/j.heliyon.2023.e13083 ↗
13. Abaka-Wood, G.B., Addai-Mensah, J., and Skinner, W. (2016). Magnetic Separation of Monazite from Mixed Minerals, Chemeca.
14. A review of the beneficiation of rare earth element bearing minerals10.1016/j.mineng.2012.10.017 ↗
15. Kim, K., and Jeong, S. (2019). Separation of Monazite from Placer Deposit by Magnetic Separation. Minerals, 9.10.3390/min9030149 ↗
16. Probing surface characteristics of rare earth minerals using contact angle measurements, atomic force microscopy, and inverse gas chromatography10.1021/acsomega.9b01491 ↗
17. Hornn, V., Ito, M., Shimada, H., Tabelin, C.B., Jeon, S., Park, I., and Hiroyoshi, N. (2020). Agglomeration-Flotation of Finely Ground Chalcopyrite and Quartz: Effects of Agitation Strength during Agglomeration Using Emulsified Oil on Chalcopyrite. Minerals, 10.10.3390/min10040380 ↗
18. Julapong, P., Ekasin, J., Katethol, P., Srichonphaisarn, P., Juntarasakul, O., Numprasanthai, A., Tabelin, C.B., and Phengsaart, T. (2022). Agglomeration–flotation of microplastics using kerosene as bridging liquid for particle size enlargement. Sustainability, 14.10.3390/su142315584 ↗
19. Heterogenous carrier flotation technique for recovering finely ground chalcopyrite particles using coarse pyrite particles as a carrier10.1016/j.mineng.2022.107518 ↗
20. Applications of micro–nano bubble technology in environmental pollution control10.1049/mnl.2018.5710 ↗
21. Hornn, V., Ito, M., Shimada, H., Tabelin, C.B., Jeon, S., Park, I., and Hiroyoshi, N. (2020). Agglomeration–Flotation of Finely Ground Chalcopyrite using Emulsified Oil Stabilized by Emulsifiers: Implications for Porphyry Copper Ore Flotation. Metals, 10.10.3390/met10070912 ↗
22. Kinetic Analysis for Agglomeration-Flotation of Finely Ground Chalcopyrite: Comparison of First Order Kinetic Model and Experimental Results10.2320/matertrans.M-M2020843 ↗
23. Agglomeration-flotation of finely ground chalcopyrite using surfactant-stabilized oil emulsions: Effects of co-existing minerals and ions10.1016/j.mineng.2021.107076 ↗
24. Hydrochloric Acid Leaching of Philippine Coal Fly Ash: Investigation and Optimisation of Leaching Parameters by Response Surface Methodology (RSM)10.3390/suschem3010006 ↗
25. Global demand for rare earth resources and strategies for green mining10.1016/j.envres.2016.05.052 ↗
26. Recycling of rare earths: A critical review10.1016/j.jclepro.2012.12.037 ↗
27. Preferred reporting items for systematic reviews and meta-analyses: The PRISMA statement10.1136/bmj.b2535 ↗
28. The place of systematic reviews in education research10.1111/j.1467-8527.2005.00303.x ↗
29. Orris, G.J., and Grauch, R.I. (2002). Rare Earth Element Mines, Deposits, and Occurrences, Open-File, Report 02-189.10.3133/ofr02189 ↗
30. Systematic literature review of primary-secondary transitions: International research10.1002/rev3.3197 ↗
31. Flotation chemistry features in bastnaesite flotation with potassium lauryl phosphate10.1016/j.mineng.2015.10.010 ↗
32. Surface chemistry and flotation behavior of dolomite, monazite and bastnäsite in the presence of benzohydroxamate, sodium oleate and phosphoric acid ester collectors10.1016/j.colsurfa.2018.03.030 ↗
33. Flotation behavior and electronic simulations of rare earth minerals in the presence of dolomite supernatant using sodium oleate collector10.1016/j.jre.2018.04.016 ↗
34. Flotation studies of monazite and dolomite10.1016/j.mineng.2017.02.010 ↗
35. Chen, W., Zhou, F., Wang, H., Zhou, S., and Yan, C. (2019). The occurrence states of rare earth elements bearing phosphorite ores and rare earth enrichment through the selective reverse flotation. Minerals, 9.10.3390/min9110698 ↗
36. Impact of crystal chemistry properties on the collector-mineral interactions observed for REE orthophosphates and oxides10.1016/j.apsusc.2018.10.103 ↗
37. Crystal structures, surface stability, and water adsorption energies of La-bastnäsite via density functional theory and experimental studies10.1021/acs.jpcc.6b04747 ↗
38. A comparative study of surface energies and water adsorption on Ce-bastnasite, La-bastnaasite, and calcite via density functional theory and water adsorption calorimetry10.1039/C7CP00811B ↗
39. Design and development of novel flotation reagents for the beneficiation of Mountain Pass rare-earth ore
40. The effect of dissolved calcite species on the flotation of bastnaesite using sodium oleate10.1016/j.mineng.2019.106095 ↗
41. Effect of dissolved fluorite and barite species on the flotation and adsorption behavior of bastnaesite10.1016/j.seppur.2019.116387 ↗
42. Rare earths (La, Ce, Nd) and rare metals (Sn, Nb, W) as by-products of kaolin production—Part 3: Processing of fines using gravity and flotation10.1016/j.mineng.2016.06.004 ↗
43. Towards the efficient flotation of monazite from silicate-rich tailings with fatty acids collectors using a lanthanum salt as a selective phosphate activator10.1016/j.mineng.2020.106704 ↗
44. Concentration of rare earth minerals from coal by froth flotation
45. Association characteristic study and preliminary recovery investigation of rare earth elements from Fire Clay seam coal middlings10.1016/j.fuel.2017.11.075 ↗
46. Flotation of rare earth minerals from silicate–hematite ore using tall oil fatty acid collector10.1016/j.mineng.2016.01.004 ↗
47. Wang, X., Zhang, Q., Mao, S., and Cheng, W. (2019). A theoretical study on the electronic structure and floatability of rare earth elements (La, Ce, Nd and Y) bearing fluorapatite. Minerals, 9.10.3390/min9080500 ↗
48. Selective flotation separation of bastnaesite from calcite using xanthan gum as a depressant10.1016/j.apsusc.2020.145714 ↗
49. The upgrading of rare earth oxides from iron-oxide silicate rich tailings: Flotation performance using sodium oleate and hydroxamic acid as collectors10.1016/j.apt.2018.08.019 ↗
50. A study of flotation characteristics of monazite, hematite, and quartz using anionic collectors10.1016/j.minpro.2016.11.012 ↗
51. Flotation recovery of rare earth oxides from hematite–quartz mixture using sodium oleate as a collector10.1016/j.mineng.2019.105847 ↗
52. A comparison of sodium silicate and ammonium lignosulfonate effects on xenotime and selected gangue mineral microflotation10.1016/j.mineng.2016.10.002 ↗
53. Physicochemical aspects of allanite flotation10.1016/S1002-0721(14)60096-X ↗
54. Surface characterisation of fergusonite10.1179/1879139513Y.0000000078 ↗
55. Towards cleaner production—Using flotation to recover monazite from a heavy mineral sands zircon waste stream10.1016/j.mineng.2016.10.011 ↗
56. Recovery of rare earth elements minerals from iron oxide–silicate rich tailings—Part 2: Froth flotation separation10.1016/j.mineng.2019.105888 ↗
57. Surface characterization and froth flotation of fergusonite from Abu Dob pegmatite using a combination of anionic and nonionic collectors
58. Extraction of rare earth elements from upgraded phosphate flotation tailings
59. Selective flotation of rare earth oxides from hematite and quartz mixtures using oleic acid as a collector10.1016/j.minpro.2017.10.002 ↗
60. The ultimate mineral processing challenge: Recovery of rare earths, phosphorus and uranium from Florida phosphatic clay
61. Characterizing rare earth elements in Alaskan coal and ash
62. Beneficiation studies of a complex REE ore10.1016/j.mineng.2014.10.005 ↗
63. Spectroscopic investigation of the interaction of hydroxamate with bastnaesite (cerium) and rare earth oxides10.1016/j.mineng.2012.03.001 ↗
64. Surface nanobubbles on the rare earth fluorcarbonate mineral synchysite10.1016/j.jcis.2019.05.014 ↗
65. Adsorption mechanism of alkyl hydroxamic acid onto bastnäsite: Fundamental steps toward rational collector design for rare earth elements10.1016/j.jcis.2019.06.025 ↗
66. Surface chemistry considerations in the flotation of rare-earth and other semisoluble salt minerals
67. A Micro-scale investigation of the adsorption of collectors on bastnaesite
68. Studies on the nature of salicyl hydroxamate adsorption at the surface of neodymium oxide10.1080/01932691.2018.1544079 ↗
69. Cao, S., Cao, Y., Liao, Y., and Ma, Z. (2018). Depression mechanism of strontium ions in bastnaesite flotation with salicylhydroxamic acid as collector. Minerals, 8.10.3390/min8020066 ↗
70. The effect of dissolved mineral species on bastnäsite, monazite and dolomite flotation using benzohydroxamate collector10.1016/j.colsurfa.2017.12.038 ↗
71. Beneficial effects and mechanism of lead ions for bastnaesite flotation with octyl hydroxamic acid collector10.1016/j.mineng.2020.106199 ↗
72. A fundamental study of octanohydroxamic acid adsorption on monazite surfaces10.1016/j.minpro.2017.05.006 ↗
73. Surface charge of rare earth phosphate (monazite) in aqueous solutions10.1016/j.powtec.2017.05.048 ↗
74. Surface chemistry and flotation behaviors of monazite–apatite–ilmenite–quartz–rutile–zircon with octanohydroxamic acid10.1007/s40831-016-0114-0 ↗
75. Flotation separation of bastnaesite from calcite using novel octylmalon dihydroxamic acid as collector10.1016/j.molliq.2020.113484 ↗
76. Separation of bastnäsite from fluorite using ethylenediamine tetraacetic acid as depressant10.1016/j.mineng.2019.01.030 ↗
77. Depression behavior and mechanism of sodium silicate on bastnaesite and parisite flotation10.1016/j.colsurfa.2021.127691 ↗
78. Surface mechanism of Fe3+ ions on the improvement of fine monazite flotation with octyl hydroxamate as the collector10.3389/fchem.2021.700347 ↗
79. Flotation of monazite in the presence of calcite part I: Calcium ion effects on the adsorption of hydroxamic acid10.1016/j.mineng.2016.09.020 ↗
80. Flotation of monazite in the presence of calcite part II: Enhanced separation performance using sodium silicate and EDTA10.1016/j.mineng.2018.01.042 ↗
81. Fundamental studies on the surface chemistry of ancylite, calcite, and strontianite10.1007/s40831-016-0097-x ↗
82. Alternative flowsheet for rare earth beneficiation of Bear Lodge ore10.1016/j.mineng.2017.04.016 ↗
83. A molecular-scale approach to rare-earth beneficiation: Thinking small to avoid large losses10.1016/j.isci.2020.101435 ↗
84. Surface chemistry considerations in the flotation of bastnäsite10.1016/j.mineng.2014.04.013 ↗
85. Beneficiation of the Nechalacho rare earth deposit: Flotation response using benzohydroxamic acid10.1016/j.mineng.2016.08.024 ↗
86. Boulanger, J.-F., Bazin, C., and Turgeon, K. (2019). Effect of depressants and temperature on bastnaesite and monazite flotation separation from a Canadian rare earth element (REE) ore. Minerals, 9.10.3390/min9040225 ↗
87. Xiong, W., Deng, J., Zhao, K., Wang, W., Wang, Y., and Wei, D. (2020). Bastnaesite, barite, and calcite flotation behaviors with salicylhydroxamic acid as the collector. Minerals, 10.10.3390/min10030282 ↗
88. Process mineralogy of Dalucao rare earth ore and design of beneficiation process based on AMICS10.1007/s12598-020-01446-w ↗
89. Activation mechanisms of apatite by purifying reagent polyacrylamide for backwater from mineral processing in flotation of rare earths10.1016/j.apt.2021.09.024 ↗
90. Investigating the performance of oxalic acid for separating bastnaesite from calcium-bearing gangue minerals based on experiment and theoretical calculation10.1016/j.mineng.2021.107047 ↗
91. Flotation of ultra-fine rare-earth minerals with selective flocculant PDHA10.1016/j.mineng.2014.01.027 ↗
92. Synthesis of 3-hydroxy-2-naphthyl hydroxamic acid collector: Flotation performance and adsorption mechanism on bastnaesite10.17159/2411-9717/2017/v117n6a10 ↗
93. Flotation-magnetic separation for the beneficiation of rare earth ores10.1016/j.mineng.2018.01.014 ↗
94. Hydroxamic acid interactions with solvated cerium hydroxides in the flotation of monazite and bastnäsite—Experiments and DFT study10.1016/j.apsusc.2016.07.044 ↗
95. Ionic-liquid collectors for rare-earth minerals flotation—Case of tetrabutylammonium bis(2-ethylhexyl)-phosphate for monazite and bastnäsite recovery10.1016/j.colsurfa.2016.06.011 ↗
96. A study of selective flotation recovery of rare earth oxides from hematite and quartz using hydroxamic acid as a collector10.1016/j.apt.2018.04.028 ↗
97. A novel decanedioic hydroxamic acid collector for the flotation separation of bastnäsite from calcite10.1016/j.mineng.2020.106306 ↗
98. β-Amino-hydroxamate surfactants: Preparation, and adsorption mechanism in bastnaesite flotation10.1016/j.seppur.2020.116634 ↗
99. Probing the hydrophobic mechanism of N-[(3-hydroxyamino)-propoxy]-N-octyl dithiocarbamate toward bastnaesite flotation by in situ AFM, FTIR and XPS10.1016/j.jcis.2020.03.080 ↗
100. Preparation of a novel bis hydroxamic collector and its impact on bastnaesite flotation10.1016/j.mineng.2020.106496 ↗