Study of Oxygen Vacancies in TiO2 Nanostructures and Their Relationship with Photocatalytic Activity

In this research work, we present the synthesis and characterization of four different TiO2 structures, such as nanotubes, nanocavities, nanosheets assembled on nanocavities and nanobowls assembled on nanocavities, prepared by electrochemical anodization using organic electrolytes. After synthesis, the structures were thermally annealed to pass from the amorphous phase to the anatase phase, which is one of the most important crystalline structures of TiO2 due to its high photocatalytic activity and stability. The unique morphology and topography were studied using scanning electron microscopy (SEM) and atomic force microscopy (AFM). The elemental composition was determined by energy-dispersive X-ray spectroscopy (EDS). The anatase phase was verified by Raman microscopy and X-ray diffraction (XRD), the band gap energy was calculated by the Kubelka–Munk function, and the main defect states that generate the emission, as well as their lifetime, were determined by photoluminescence spectroscopy and time response photoluminescence (TRPL), respectively. The TiO2 nanomaterials were tested as catalysts in the photodegradation of a solution of methylene blue using a UV lamp at room temperature. The results showed complex morphologies and different surface roughness areas of these nanomaterials. Furthermore, a relationship between defect states, band gap energy, and photocatalytic activity was established. We found that the catalytic activity was improved as an effect of geometric parameters and oxygen vacancies.