journal article·2020-08-28Open access

Hyperspectral Imaging for Color Adulteration Detection in Red Chili

Muhammad Hussain Khan, Zainab Saleem, Muhammad Ahmad, Ahmed Sohaib, Hamail Ayaz, Manuel Mazzara

Applied Sciences· Volume 10· Issue 17

Abstract

The quality of red chili is characterized based on its color and pungency. Several factors like humidity, temperature, light, and storage conditions affect the characteristic qualities of red chili, thus preservation required several measures. Instead of ensuring these measures, traders are using oil and Sudan dye in red chili to increase the value of an inferior product. Thus, this work presents the feasibility of utilizing a hyperspectral camera for the detection of oil and Sudan dye in red chili. This study describes the important wavelengths (500–700 nm) where different adulteration affects the response of the reflected spectrum. These wavelengths are then utilized for training an Support Vector Machine (SVM) algorithm to detect pure, oil-adulterated, and Sudan dye-adulterated red chili. The classification performance achieves 97% with the reduced dimensionality and 100% with complete validation data. The trained algorithm is further tested on separate data with different adulteration levels in comparison to the training data. Results show that the algorithm successfully classifies pure, oil-adulterated, and Sudan-adulterated red chili with an accuracy of 100%.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Spectroscopy and Chemometric Analyses · Advanced Chemical Sensor Technologies · Dye analysis and toxicity

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Advance Image Processing Research Lab (AIPRL), Department of Computer Engineering, Khwaja Fareed University of Engineering and Information Technology, Rahim Yar Khan 64200, Pakistan

Institute of Software Development and Engineering, Innopolis University, 420500 Innopolis, Russia

References (44)

Show source-provided references
1. Colour change in pepper (Capsicum annuum) during storage
2. Effects of processing and storage on the stability of free and esterified carotenoids of red peppers (Capsicum annuum L.) and hot chilli peppers (Capsicum frutescens L.)10.1007/s00217-006-0413-y ↗
3. Influences of γ-irradiation and storage on the carotenoids of sun-dried and dehydrated paprika10.1021/jf034177z ↗
4. A novel approach for color degradation kinetics of paprika as a function of water activity10.1016/j.lwt.2007.10.004 ↗
5. Carotenoid Content of the Varieties Jaranda and Jariza (Capsicum annuum L.) and Response during the Industrial Slow Drying and Grinding Steps in Paprika Processing10.1021/jf9908143 ↗
6. Sudan dyes and their potential health effects
7. Detection of sudan dyes in red chilli powder by thin layer chromatography
8. Quantitative analysis of Sudan dye adulteration in paprika powder using FTIR spectroscopy
9. (2020, March 10). Background about Sudan Dyes in Food. Available online: https://ec.europa.eu/commission/presscorner/detail/en/MEMO_05_61.
10. Quantitative analysis of the banned food dye Sudan-1 using surface enhanced Raman scattering with multivariate chemometrics10.1021/jp908892n ↗
11. (2019, September 30). Ghaziabad: Chilli Powder Samples to Be Tested for Adulteration. Available online: https://www.hindustantimes.com/noida/ghaziabad-chilli-powder-samples-to-be-tested-for-adulteration/story-lOd7FLTXYKF7aokec1ppvJ.html.
12. (2019, September 30). Food-Safety-Adulterated-Chilli-Powder-Sent-Laboratory-Examination. Available online: https://tribune.com.pk/story/1130329/food-safety-adulterated-chilli-powder-sent-laboratory-examination.
13. (2019, September 30). 40,000 kg Adulterated Spices Seized from 3 Cold Storages | Jaipur News—Times of India. Available online: https://timesofindia.indiatimes.com/city/jaipur/40000-kg-adulterated-spices-seized-from-3-cold-storages/articleshow/60137462.cms.
14. Detection and Determination of Para-red in Chillies and Spices by HPLC
15. Simultaneous determination of Sudan dyes and carotenoids in red pepper and tomato products by HPLC10.1093/chromsci/43.9.461 ↗
16. Nawrocka, A., and Lamorska, J. (2013). Determination of food quality by using spectroscopic methods. Advances in Agrophysical Research, IntechOpen.10.5772/52722 ↗
17. Design and fabrication of a real-time measurement system for the capsaicinoid content of Korean red pepper (Capsicum annuum L.) powder by visible and near-infrared spectroscopy10.3390/s151127420 ↗
18. A rapid FT-NIR method for estimation of aflatoxin B1 in red chili powder10.1016/j.foodcont.2008.11.003 ↗
19. Quantitative identification of adulterated Sichuan pepper powder by near-infrared spectroscopy coupled with chemometrics10.1155/2017/5019816 ↗
20. The feasibility of using near infrared and Raman spectroscopic techniques to detect fraudulent adulteration of chili powders with Sudan dye10.1016/j.foodcont.2014.03.047 ↗
21. Determining the adulteration of spices with Sudan I-II-II-IV dyes by UV–visible spectroscopy and multivariate classification techniques10.1016/j.talanta.2009.05.023 ↗
22. Surface Enhanced Raman Spectroscopy (SERS) and multivariate analysis as a screening tool for detecting Sudan I dye in culinary spices10.1016/j.saa.2011.11.027 ↗
23. Ahmad, M., Mazzara, M., Raza, R.A., Distefano, S., Asif, M., Sarfraz, M.S., Khan, A.M., and Sohaib, A. (2020). Multiclass Non-Randomized Spectral–Spatial Active Learning for Hyperspectral Image Classification. Appl. Sci., 10.10.3390/app10144739 ↗
24. A New Statistical Approach for Band Clustering and Band Selection Using K-Means Clustering
25. Hyperspectral imaging in crop fields: Precision agriculture10.1016/B978-0-444-63977-6.00018-3 ↗
26. Advanced techniques for hyperspectral imaging in the food industry: Principles and recent applications10.1146/annurev-food-032818-121155 ↗
27. Hyperspectral imaging in medical applications10.1016/B978-0-444-63977-6.00021-3 ↗
28. Hyperspectral imaging for non-contact analysis of forensic traces10.1016/j.forsciint.2012.09.012 ↗
29. Evaluation of glint correction approaches for fine-scale ocean color measurements by lightweight hyperspectral imaging spectrometers10.1364/AO.377059 ↗
30. Ahmad, M. (2020). A Fast 3D CNN for Hyperspectral Image Classification. arXiv.
31. Ahmad, M., Khan, A.M., Mazzara, M., and Distefano, S. (2019, January 25–27). Multi-layer Extreme Learning Machine-based Autoencoder for Hyperspectral Image Classification. Proceedings of the 14th International Joint Conference on Computer Vision, Imaging and Computer Graphics Theory and Applications (VISAPP, 2019), Prague, Czech Republic.10.5220/0007258000002108 ↗
32. Khan, M.H., Saleem, Z., Ahmad, M., Sohaib, A., and Ayaz, H. (2019). Unsupervised adulterated red-chili pepper content transformation for hyperspectral classification. arXiv.
33. (2020, May 30). Probe Reveals ‘Dangerous’ Adulteration of Chilli Powderer-Sent-Laboratory-Examination. Available online: https://www.thehindu.com/news/national/andhra-pradesh/Probe-reveals-%E2%80%98dangerous%E2%80%99-adulteration-of-chilli-powder/article16437652.ece.
34. (2019). MATLAB Version 9.3.0.713579 (R2019a), The Mathworks, Inc.
35. Atmospheric corrections: On deriving surface reflectance from hyperspectral imagers
36. Retrieval of apparent surface reflectance from AVIRIS data: A comparison of empirical line, radiative transfer, and spectral mixture methods10.1016/0034-4257(94)90099-X ↗
37. Review of the most common pre-processing techniques for near-infrared spectra10.1016/j.trac.2009.07.007 ↗
38. The effect of multiplicative scatter correction (MSC) and linearity improvement in NIR spectroscopy10.1366/0003702884429869 ↗
39. Standard normal variate transformation and de-trending of near-infrared diffuse reflectance spectra10.1366/0003702894202201 ↗
40. A combined derivative spectroscopy and Savitzky-Golay filtering method for the analysis of hyperspectral data10.2747/1548-1603.45.1.1 ↗
41. Assessment of visible near-infrared hyperspectral imaging as a tool for detection of horsemeat adulteration in minced beef10.1007/s11947-015-1470-7 ↗
42. Ruffin, C., and King, R.L. (July, January 28). The analysis of hyperspectral data using Savitzky-Golay filtering-theoretical basis. 1. Proceedings of the IEEE 1999 International Geoscience and Remote Sensing Symposium. IGARSS’99 (Cat. No. 99CH36293), Hamburg, Germany.
43. Principal component analysis: A review and recent developments10.1098/rsta.2015.0202 ↗
44. Support-vector networks10.1007/BF00994018 ↗