journal article·2022-06-15Open access

Green Hydrogen Storage in an Underground Cavern: A Case Study in Salt Diapir of Spain

Laura M. Valle-Falcones, Carlos Grima-Olmedo, Luis F. Mazadiego-Martínez, Antonio Hurtado-Bezos, Sonsoles Eguilior-Díaz, Ramón Rodríguez-Pons

Applied Sciences· Volume 12· Issue 12

Abstract

The Poza de la Sal diapir is a closed circular depression with Cretaceous Mesozoic materials, formed by gypsum, Keuper clays, and a large extension of salt in the center with intercalations of ophite. The low seismic activity of the area, the reduced permeability and porosity of the salt caverns, and the proximity to the Páramo de Poza wind park, make it a suitable place for the construction of a facility for underground storage of green hydrogen obtained from surplus wind power. The design of a cavern for hydrogen storage at a depth of 1000 m takes into account the differences in stresses, temperatures, and confining pressures involved in the salt deformation process. During the 8 months of the injection phase, 23.0 GWh can be stored in the form of hydrogen obtained from the wind energy surplus, to be used later in the extraction phase. The injection and extraction ratio must be developed under the conditions of geomechanical safety of the cavity, so as to minimize the risks to the environment and people, by conditioning the gas pressure inside the cavity to remain within a given range.
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Research context

OpenAlex topics: Hybrid Renewable Energy Systems · Spacecraft and Cryogenic Technologies · Hydrogen Storage and Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Departamento de Ingeniería Geológica y Minera, Escuela Técnica Superior de Ingenieros de Minas y Energía, Universidad Politécnica de Madrid, Ríos Rosas 23, 28003 Madrid, Spain

Departamento de Energía y Combustibles, Escuela Técnica Superior de Ingenieros de Minas y Energía, Universidad Politécnica de Madrid, Ríos Rosas 23, 28003 Madrid, Spain

Centro de Investigaciones Energéticas, Medioambientales y Tecnológicas, Avda. Complutense 40, Edif. 20, 28040 Madrid, Spain

Funding

Oil and Gas Engineering Master’s degree (mip) of the Universidad Politécnica de Madrid (UPM)

References (38)

Show source-provided references
1. Kupecki, J., Skrzypkiewicz, M., and Błesznowski, M. (2018, January 12). Current advancements in hydrogen technology and pathways to meet decarbonisation. Towards hydrogen societies: Expert group meeting. Proceedings of the 24th Session of the Conference of the Parties to the United Nations Framework, Convention on Climate Change (UNFCCC)—COP24, Lubelskie, Poland.
2. MITERD (2020). Hoja de Ruta del Hidrógeno: Una Apuesta por el Hidrógeno Renovable.
3. Production, storage and properties of hydrogen as internal combustion engine fuel: A critical review
4. Abe, I. (2009). Physical and chemical properties of hydrogen. Energy Carriers and Conversion Systems, EOLSS Publications. Available online: https://www.eolss.net/ebooklib/sc_cart.aspx?File=E3-13-01-01.
5. Enabling large-scale hydrogen storage in porous media-the scientific challenges10.1039/D0EE03536J ↗
6. (2022, April 18). Las Energías Renovables en el Sistema Eléctrico Español 2020. Red Eléctrica de España. Available online: https://www.ree.es/sites/default/files/publication/2021/06/downloadable/informe_renovables_2020_0.pdf.
7. Ozarslan, A. (2012). Large-scale hydrogen energy storage in salt caverns. Int. J. Hydrogen Energy, 14265–14277.10.1016/j.ijhydene.2012.07.111 ↗
8. Net-zero emissions energy systems
9. Power to gas: Technological overview, systems analysis and economic assessment for a case study in Germany10.1016/j.ijhydene.2015.01.123 ↗
10. Bertuccioli, L., Chan, A., Hart, D., Lehner, F., Madden, B., and Standen, E. (2022, April 29). Study on Development of Water Electrolysis in the EU. Final Report. Available online: https://www.fch.europa.eu/sites/default/files/study%20electrolyser_0.pdf.
11. Kruck, O., Crotogino, F., Prelicz, R., and Rudolph, T. (2022, May 12). Overview on All Known Underground Storage Technologies for Hydrogen. HyUnder. Grant Agreement 303417 Deliverable, August 2013; p. 93. Available online: http://hyunder.eu/wp-content/uploads/2016/01/D3.1_Overview-of-all-known-underground-storage-technologies.pdf.
12. Technical potential of salt caverns for hydrogen storage in Europe10.1016/j.ijhydene.2019.12.161 ↗
13. Development of damage and permeability in deforming rock salt10.1016/S0013-7952(01)00051-5 ↗
14. Ruiz, C., Martinez, R., Recreo, F., Prado, P., Campos, R., Pelayo, M., Losa, A.D.L., Hurtado, A., Lomba, L., and Perez del Villar, L. (2022, April 19). Geological Storage of CO2. Site Selection Criteria. Madrid 2006. Ciemat-1085. p. 108. Available online: https://inis.iaea.org/collection/NCLCollectionStore/_Public/38/030/38030356.pdf?r=1.
15. La Cuenca Vasco-Cantábrica: Génesis y evolución tectonosedimentaria
16. Pedreira, D. (2004). Estructura de la Zona de Transición de los Pirineos y la Cordillera Cantábrica. [Ph.D. Thesis, Universidad de Oviedo].
17. Stability and serviceability of underground energy storage caverns in rock salt subjected to mechanical cyclic loading10.1016/j.ijrmms.2016.04.010 ↗
18. Underground hydrogen storage in the UK10.1144/SP313.13 ↗
19. Korzeniowski, W., Poborska-Młynarska, K., Skrzypkowski, K., Zagórski, K., and Chromik, M. (2020). Cutting Niches in Rock Salt by Means of a High-Pressure Water Jet in Order to Accelerate the Leaching of Storage Caverns for Hydrogen or Hydrocarbons. Energies, 13.10.3390/en13081911 ↗
20. Drilling Long Salt Sections Along the U.S. Gulf Coast10.2118/24605-PA ↗
21. Geomechanical Modeling of Wellbore Stability in Salt Formations
22. Cyran, K., and Kowalski, M. (2021). Shape Modelling and Volumen Optimisation of Salt Caverns for Energy Storage. Appl. Sci., 11.10.3390/app11010423 ↗
23. Bulk storage of hydrogen10.1016/j.ijhydene.2021.08.028 ↗
24. Regulatory, technical pressures prompt more US salt-cavern gas storage
25. Portarapillo, M., and Di Benedetto, A. (2021). Risk Assessment of the Large-Scale Hydrogen Storage in Salt Caverns. Energies, 14.10.37247/ADERES2EDN.3.2021.3 ↗
26. Albrecht, U., Bünger, U., Michalski, J., Raksha, T., Wurster, R., and Zerhusen, J. (2022, April 12). International Hydrogen Strategies. A Study Commissioned by and in Cooperation with the World Energy Council Germany 2020. Final Report. Available online: https://www.researchgate.net/publication/345163207.
27. Pure and pseudo-pure fluid thermophysical property evaluation and the open-source thermophysical property library coolprop10.1021/ie4033999 ↗
28. Londe, L. (2022, May 09). Hydrogen Caverns Are a Proven, Inexpensive and Reliable Technology. Available online: https://medium.com/@ch2ange.
29. Assessment of feasible strategies for seasonal underground hydrogen storage in a saline aquifer10.1016/j.ijhydene.2017.05.076 ↗
30. Cihlar, J., Mavins, D., and Van der Leun, K. (2021). Picturing the Value of Underground Gas Storage to the European Hydrogen System, Guidehouse.
31. Gupta, R.B. (2016). Underground and pipeline hydrogen storage. Compendium of Hydrogen, Elsevier.
32. LNG cold energy utilization: Prospects and challenges10.1016/j.energy.2018.12.170 ↗
33. An overview of hydrogen underground storage technology and prospects in China10.1016/j.petrol.2014.09.037 ↗
34. Geologic storage of hydrogen: Scaling up to meet city transportation demands10.1016/j.ijhydene.2014.07.121 ↗
35. Utility-scale subsurface hydrogen storage: UK perspectives and technology10.1016/j.ijhydene.2021.05.034 ↗
36. Hydrogen storage in saline aquifers: The role of cushion gas for injection and production10.1016/j.ijhydene.2021.09.174 ↗
37. Hemme, C., and Van Berk, W. (2018). Hydrogeochemical Modeling to Identify Potential Risks of Underground Hydrogen Storage in Depleted Gas Fields. Appl. Sci., 8.10.3390/app8112282 ↗
38. Crotogino, F., Donadei, S., Bünger, U., and Landinger, H. (2010, January 16–21). Large-scale hydrogen underground storage for securing future energy supplies. Proceedings of the 18th World Hydrogen Energy Conference 2010—WHEC 2010, Zürich, Switzerland.