journal article·2022-03-04Open access

A High Thermal Conductivity of MgO-H2O Nanofluid Prepared by Two-Step Technique

Hadia Kadhim Judran, Adnan G. Tuaamah Al-Hasnawi, Faten N. Al Zubaidi, Wisam Abed Kattea Al-Maliki, Falah Alobaid, Bernd Epple

Applied Sciences· Volume 12· Issue 5

Abstract

In this paper, the main goal is to study the impact of nanopowder volume concentration and ultrasonication treatment time on the stability and thermophysical properties of MgO-DW nanofluid at room temperature. The co-precipitation method was utilized to prepare pure MgO nanoparticles with an average particle size of 33 nm. The prepared MgO nanopowder was characterized by using XRD, SEM, and EDX analyses. Then, MgO-DW nanofluid was obtained with different volume concentrations (i.e., 0.05, 0.1, 0.15, 0.2, and 0.25 vol.%) and different ultrasonication time periods (i.e., 45, 90, 135, and 180 min) by using a novel two-step technique. With volume concentration and ultrasonication time of 0.15 vol.% and 180 min, respectively, good stability was achieved, according to the zeta potential analysis. With increasing volume concentration and ultrasonication time period of the nanofluid samples, the thermal conductivity measurements showed significant increases. As a result, the maximum enhancement was found to be 25.08% at a concentration ratio of 0.25 vol.% and agitation time of 180 min. Dynamic viscosity measurements revealed two contrasting trends with volume concentration and ultrasonication time. The lowest value of relative viscosity was gained by 0.05 vol.% MgO-DW nanofluid. The chemical and physical interactions between MgO nanoparticles and DW molecules play an important function in determining the thermal conductivity and dynamic viscosity of MgO-DW nanofluid. These findings exhibit that MgO-DW nanofluid has the potential to be used as an advanced heat transfer fluid in cooling systems and heat exchangers.
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Research context

OpenAlex topics: Nanofluid Flow and Heat Transfer · Heat Transfer and Optimization · Magnesium Oxide Properties and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Electromechanical Engineering Department, University of Technology-Iraq, Baghdad 19006, Iraq

Mechanical Engineering Department, University of Technology-Iraq, Baghdad 19006, Iraq

Institut Energiesysteme und Energietechnik, TU Darmstadt, Otto-Berndt-Straße 2, 64287 Darmstadt, Germany

References (90)

Show source-provided references
1. Hashim, A.A. (2012). Smart Nanoparticles Technology, IntechOpen.10.5772/1969 ↗
2. Das, S.K., Choi, S.U., Yu, W., and Pradeep, T. (2008). Nanofluids, Science and Technology, John Wiley & Sons Inc.10.1002/9780470180693 ↗
3. Importance of shape factor in Sisko nanofluid flow considering gold nanoparticles10.1016/j.aej.2021.09.010 ↗
4. Bharat, B., and Baral, D. (2021). Nanofluids for Heat and Mass Transfer (Fundamentals, Sustainable Manufacturing and Applications), Elsevier. [1st ed.].
5. Experimental determination of thermal conductivity and dynamic viscosity of Ag–MgO/water hybrid nanofluid10.1016/j.icheatmasstransfer.2015.06.003 ↗
6. Gonçalves, I., Souza, R., Coutinho, G., Miranda, J., Moita, A., Pereira, J.E., Moreira, A., and Lima, R. (2021). Thermal Conductivity of Nanofluids: A Review on Prediction Models, Controversies and Challenges. Appl. Sci., 11.10.3390/app11062525 ↗
7. A Review on Nanofluids: Fabrication, Stability, and Thermophysical Properties10.1155/2018/6978130 ↗
8. Ali, N., Bahman, A.M., Aljuwayhel, N.F., Ebrahim, S.A., Mukherjee, S., and Alsayegh, A. (2021). Carbon-Based Nanofluids and Their Advances towards Heat Transfer Applications—A Review. Nanomaterials, 11.10.3390/nano11061628 ↗
9. Chamsa-ard, W., Brundavanam, S., Fung, C.C., Fawcett, D., and Poinern, G. (2017). Nanofluid Types, Their Synthesis, Properties and Incorporation in Direct Solar Thermal Collectors: A Review. Nanomaterials, 7.10.3390/nano7060131 ↗
10. Maxwell, J.C. (1873). Electricity and Magnetism, Clarendon Press.
11. Maxwell, J.C. (2010). A Treatise on Electricity and Magnetism, Clarendon Press.10.1017/CBO9780511709340 ↗
12. Choi, S.U.S. (1995). Enhancing Thermal Conductivity of Fluids with Nanoparticles, ASME.
13. Judran, H.K. (2016). Preparation and Investigation Study on (CuO/H2O) Nanofluid for Improving the Performance of (PV/T) Hybrid System. [Ph.D. Thesis, University of Technology].
14. Nanofluids for thermal transport (review)
15. The mechanism of heat transfer in nanofluids: State of the art (review). Part1. Synthesis and properties of nanofluids10.1134/S0869864310010014 ↗
16. Nanofluid research advances: Preparation, characteristics and applications in food processing10.1016/j.foodres.2021.110751 ↗
17. Towards hybrid nanofluids: Preparation, thermophysical properties, applications and challenges10.1016/j.molliq.2019.02.102 ↗
18. Thermal conductivity and viscosity of Mg(OH)2-ethylene glycol nanofluids. Finding a critical temperature10.1007/s10973-015-4417-3 ↗
19. Evaluating the effect of temperature and concentration on the thermal conductivity of ZnO-TiO2/EG hybrid nanofluid using artificial neural network and curve fitting on experimental data10.1016/j.physa.2018.12.010 ↗
20. Heat transfer performance of two oil-based nanofluids containing ZnO and MgO nanoparticles; a comparative experimental investigation10.1016/j.powtec.2018.11.023 ↗
21. A novel comprehensive experimental study concerned synthesizes and prepare liquid paraffin-Fe3O4 mixture to develop models for both thermal conductivity & viscosity: A new approach of GMDH type of neural network10.1016/j.ijheatmasstransfer.2018.11.069 ↗
22. Experimental evaluation of dynamic viscosity of ZnO–MWCNTs/engine oil hybrid nanolubricant based on changes in temperature and concentration10.1007/s10973-018-7707-8 ↗
23. Effective Thermal Conductivity of Nanofluids: Measurement and Prediction10.1007/s10765-020-2621-2 ↗
24. Mahbubul, I.M. (2018). Preparation, Characterization, Properties, and Application of Nanofluid, William Andrew. [1st ed.].10.1016/B978-0-12-813245-6.00002-2 ↗
25. Modeling and optimization the effective parameters of nanofluid heat transfer performance using artificial neural network and genetic algorithm method10.1016/j.egyr.2021.10.121 ↗
26. The analogy of nanoparticle shapes on the theory of convective heat transfer of Au-Fe3O4 Casson hybrid nanofluid
27. A Review: Enhancement of turning process performance by effective utilization of hybrid nanofluid and MQL10.1016/j.matpr.2020.05.603 ↗
28. Unsteady thermal Maxwell power law nanofluid flow subject to forced thermal Marangoni Convection10.1038/s41598-021-86865-0 ↗
29. Magneto-Burgers Nanofluid Stratified Flow with Swimming Motile Microorganisms and Dual Variables Conductivity Configured by a Stretching Cylinder/Plate10.1155/2021/8817435 ↗
30. Hydrothermal variations of radiative nanofluid flow by the influence of nanoparticles diameter and nanolayer10.1016/j.icheatmasstransfer.2021.105781 ↗
31. Metal oxide nanofluids: Review of formulation, thermo-physical properties, mechanisms, and heat transfer performance10.1016/j.rser.2017.03.043 ↗
32. Porgar, S., and Rahmanian, N. (2022). Investigation of Effect of Aluminium Oxide Nanoparticles on the Thermal Properties of Water-Based Fluids in a Double Tube Heat Exchanger, University of Bradford.
33. Effect of NiO/SiO2 nanofluids on the ultra-interfacial tension reduction between heavy oil and aqueous solution and their use for wettability alteration of carbonate rocks10.1016/j.petrol.2019.01.024 ↗
34. Toward TiO2 Nanofluids Part1: Preparation and Properties10.1186/s11671-017-2184-8 ↗
35. Maseer, M.M., Alnaimi, F.B.I., Hannun, R.M., Al-Gburi, K.A.H., and Mezan, S.O. (2021). A review of the characters of nanofluids used in the cooling of a photovoltaic -thermal collector. Mater. Today Proc., 1–9.10.1016/j.matpr.2021.09.214 ↗
36. Biosynthesized CuO nano-platelets: Physical properties and enhanced thermal conductivity nanofluidics10.1016/j.arabjc.2017.03.004 ↗
37. Towards convective heat transfer optimization in aluminum tube automotive radiators: Potential assessment of novel Fe2O3-TiO2/water hybrid nanofluid10.1016/j.jtice.2021.02.002 ↗
38. Magnesium oxide nanowires synthesized by pulsed liquid-injection metal organic chemical vapor deposition10.1063/1.3064134 ↗
39. Hornak, J. (2021). Synthesis, Properties, and Selected Technical Applications of Magnesium Oxide Nanoparticles: A Review. Int. J. Mol. Sci., 22.10.3390/ijms222312752 ↗
40. Kanny, A.V., Abitha, K., and Thomas, V.K. (2018). Chapter 5-Methods for Synthesis of Nanoparticles and Fabrication of Nanocomposites. Synthesis of Inorganic Nanomaterials, Wood Head Publishing. Micro and Nano Technologies.
41. Synthesis and characterization of MgO nanocrystals using strong and weak bases10.1016/j.powtec.2012.04.044 ↗
42. Sol-gel coupled ultrasound synthesis of photo-activated magnesium oxide nanoparticles: Optimization and antibacterial studies10.1002/cjce.23861 ↗
43. Epitaxial growth and strain relaxation of MgO thin films on Si grown by molecular beam epitaxy10.1116/1.2362759 ↗
44. Pradita, T., Shih, S.J., Aji, B.B. (2017). Synthesis of MgO powder from magnesium nitrate using spray pyrolysis. International Conference on Chemistry, AIP Publishing. Chemical Process and Engineering (IC3PE), AIP Conf. Proc. 1823, (020016-1)-(020016-5).10.1063/1.4978089 ↗
45. Syntheses and characterization of Mg(OH)2 and MgO nanostructures by ultrasonic method10.1016/j.ultsonch.2009.08.013 ↗
46. Mechanistic aspects of formation of MgO nanoparticles under microwave irradiation and its catalytic application10.1016/j.apt.2017.02.004 ↗
47. Synthesis of Magnesium Oxide Nanopowder by Thermal Plasma Using Magnesium Nitrate Hexahydr10.1155/2016/6853405 ↗
48. Synthesis of crystalline MgO nanoparticle with mesoporous-assembled structure via a surfactant-modified sol-gel process10.1016/j.matlet.2009.05.068 ↗
49. Stojanovic, B.D., Dzunuzovic, A.S., and Ilic, N.I. (2018). 17-Review of methods for the preparation of magnetic metal oxides. Magnetic, Ferroelectric, and Multiferroic Metal Oxides (Metal Oxides), Elsevier.10.1016/B978-0-12-811180-2.00017-7 ↗
50. Xu, R., and Xu, Y. (2017). Hydrothermal and Solvothermal Syntheses. Modern Inorganic Synthetic Chemistry, Elsevier. [2nd ed.].
51. MgO nanostructures synthesized by thermal evaporation10.1016/j.msec.2005.09.082 ↗
52. Ngo, C., Voorde, C., and van de Voorde, M.H. (2014). Nanotechnology in a Nutshell: From Simple to Complex Systems, Atlantis Press.10.2991/978-94-6239-012-6 ↗
53. Saied, E., Eid, A.M., Hassan, S.E.D., Salem, S.S., Radwan, A.A., Halawa, M., Saleh, F.M., Saied, E.M., and Fouda, A. (2021). The Catalytic Activity of Biosynthesized Magnesium Oxide Nanoparticles (MgO-NPs) for Inhibiting the Growth of Pathogenic Microbes, Tanning Effluent Treatment and Chromium Ion Removal. Catalysts, 11.10.3390/catal11070821 ↗
54. Exploring the therapeutic potential of Hibiscus rosa sinensis synthesized cobalt oxide (Co3O4-NPs) and magnesium oxide nanoparticles (MgO-NPs)10.1016/j.sjbs.2021.05.035 ↗
55. Pal, G., Rai, P., and Pandey, A. (2019). Chapter 1-Green synthesis of nanoparticles: A greener approach for a cleaner future. Green Synthesis, Characterization and Applications of Nanoparticles (Micro and Nano Technologies), Elsevier.10.1016/B978-0-08-102579-6.00001-0 ↗
56. Approaches to synthesize MgO nanostructures for diverse applications10.1016/j.heliyon.2020.e04882 ↗
57. Rapid synthesis of MgO nanoparticles & their utilization for formulation of a propylene glycol based nanofluid with superior transport properties10.1039/C4RA09173F ↗
58. An experimental study on thermal conductivity of MgO nanoparticles suspended in a binary mixture of water and ethylene glycol10.1016/j.icheatmasstransfer.2015.07.009 ↗
59. Dependency of nanofluid rheology on particle size and concentration of various metal oxide nanoparticles10.1590/0104-6632.20180352s20160172 ↗
60. Lu, J., Zhang, Z., Wang, W., and Ding, J. (2021). Effects of MgO Nanoparticles on Thermo-Physical Properties of LiNO3-NaNO3-KNO3 for Thermal Energy Storage. Energies, 14.10.3390/en14030677 ↗
61. Novel use of MgO nanoparticle additive for enhancing the thermal conductivity of CuO/water nanofluid10.1016/j.csite.2021.101279 ↗
62. A Review on Thermophysical Properties for Heat Transfer Enhancement of Carbon-Based Nanolubricant10.1002/adem.202100403 ↗
63. Evaluation of thermal conductivity of MgO-MWCNTs/EG hybrid nanofluids based on experimental data by selecting optimal artificial neural networks10.1016/j.physe.2016.08.020 ↗
64. Effects of temperature and particles volume concentration on the thermophysical properties and the rheological behavior of CuO/MgO/TiO2, aqueous ternary hybrid nanofluid: Experimental investigation10.1007/s10973-019-08006-0 ↗
65. A detailed investigation on the thermo-physical and rheological behavior of MgO/TiO2 aqueous dual hybrid nanofluid10.1016/j.molliq.2019.02.100 ↗
66. Hydrothermal performance of different alumina hybrid nanofluid types in plate heat exchanger: Experimental study10.1007/s10973-019-08682-y ↗
67. The Effect of Nanofluid Volume Concentration on Heat Transfer and Friction Factor inside a Horizontal Tube10.1155/2013/859563 ↗
68. Hunter, R.J. (1988). Zeta Potential in Colloid Science, Principles and Applications, Academic Press. [1st ed.].
69. Zainon, S.N.M., and Azmi, W.H. (2021). Recent Progress on Stability and Thermo-Physical Properties of Mono and Hybrid towards Green Nanofluids. Micromachines, 12.10.3390/mi12020176 ↗
70. Washington, C. (1992). Particle Size Analysis in Pharmaceutics and other Industries: Theory and Practice, Ellis Horwood Limited.10.1201/b12596 ↗
71. Bianco, V., Manca, O., Nardini, S., and Vafai, K. (2017). Heat Transfer Enhancement with Nanofluids. Routledge (Taylor & Francis Group), CRC Press. [1st ed.].
72. Synthesis of a complex nanostructure of CuO via a coupled chemical route10.1088/2053-1591/3/12/125025 ↗
73. Wahhab, H.A.A., and Al-Maliki, W.A.K. (2020). Application of a Solar Chimney Power Plant to Electrical Generation in Covered Agricultural Fields. IOP Conference Series: Materials Science and Engineering, IOP Publishing.
74. Phytoassisted synthesis of magnesium oxide nanoparticles from Pterocarpus marsupium rox.b heartwood extract and its biomedical applications10.1186/s43141-021-00119-0 ↗
75. Cullity, B.D. (1967). Elements of X-ray Diffraction, Wesley Publishing Company. [3rd ed.].
76. Effect of Cu Salt Molarity on the Nanostructure of CuO Prolate Spheroid
77. Response Surface Methodology Optimization of Mono-dispersed MgO Nanoparticles Fabricated by Ultrasonic-Assisted Sol–Gel Method for Outstanding Antimicrobial and Antibiofilm Activities10.1007/s10876-019-01651-3 ↗
78. Preparation of copper oxide nanoparticles and its application in nanofluid10.1016/j.powtec.2010.11.022 ↗
79. Al-Maliki, W., Mahmoud, N., Al-Khafaji, H., Alobaid, F., and Epple, B. (2021). Design and Implementation of the Solar Field and Thermal Storage System Controllers for a Parabolic Trough Solar Power Plant. Appl. Sci., 11.10.3390/app11136155 ↗
80. Enhancement of thermal conductivity in water-based nanofluids employing TiO2/reduced graphene oxide composites10.1007/s10853-016-0239-3 ↗
81. Assessment of thermal conductivity enhancement of nano-antifreeze containing single-walled carbon nanotubes: Optimal artificial neural network and curve-fitting10.1016/j.physa.2019.01.051 ↗
82. An experimental investigation on the effects of ultrasonication time on stability and thermal conductivity of MWCNT-water nanofluid: Finding the optimum ultrasonication time10.1016/j.ultsonch.2019.104639 ↗
83. An experimental study on the effect of ultrasonication on thermal conductivity of ferrofluid loaded with carbon nanotubes10.1016/j.tca.2015.08.025 ↗
84. Optimization of ultrasonication period for better dispersion and stability of TiO2-water nanofluid10.1016/j.ultsonch.2017.01.024 ↗
85. An experimental study on thermal conductivity and viscosity of nanofluids containing carbon nanotubes10.1186/1556-276X-9-151 ↗
86. Effect of dispersion behavior on the heat transfer characteristics of alumina nanofluid: An experimental investigation and development of a new correlation function10.1007/s40089-020-00306-w ↗
87. Measurement of the thermal conductivity of nanofluids by the multi current hot-wire method10.1063/1.2970086 ↗
88. Thermal conductivity and dynamic viscosity of mono and hybrid organic- and synthetic-based nanofluids: A critical review10.1515/ntrev-2021-0086 ↗
89. Effect of sonication characteristics on stability, thermophysical properties, and heat transfer of nanofluids: A comprehensive review10.1016/j.ultsonch.2019.104701 ↗
90. Effect of Ultrasonication Duration on Colloidal Structure and Viscosity of Alumina-Water Nanofluid. American Chemical Society10.1021/ie500705j ↗