journal article·2021-04-10Open access

Biologically Derived Gels for the Cleaning of Historical and Artistic Metal Heritage

Arianna Passaretti, Luana Cuvillier, Giorgia Sciutto, Elodie Guilminot, Edith Joseph

Applied Sciences· Volume 11· Issue 8

Abstract

In the general global rise of attention and research to seek greener attitudes, the field of cultural heritage (CH) makes no exception. In the last decades, an increasing number of sustainable and biologically based solutions have been proposed for the protection and care of artworks. Additionally, the safety of the target artwork and the operator must be kept as core goals. Within this scenario, new products and treatments should be explored and implemented in the common conservation praxes. Therefore, this review addressing metal heritage is aimed to report biologically derived gel formulations already proposed for this specific area as reliable tools for cleaning. Promising bio-gel-based protocols, still to be implemented in metal conservation, are also presented to promote their investigation by stakeholders in metal conservation. After an opening overview on the common practices for cleaning metallic surfaces in CH, the focus will be moved onto the potentialities of gel-alternatives and in particular of ones with a biological origin. In more detail, we displayed water-gels (i.e., hydrogels) and solvent-gels (i.e., organogels) together with particular attention to bio-solvents. The discussion is closed in light of the state-of-the-art and future perspectives.
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Research context

OpenAlex topics: Chemistry and Chemical Engineering · Calcium Carbonate Crystallization and Inhibition · Building materials and conservation

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Haute Ecole Arc Conservation-Restauration, HES-SO, Espace de l’Europe 11, 2000 Neuchatel, Switzerland

Laboratory of Technologies for Heritage Materials, Institute of Chemistry, University of Neuchâtel, Av. Bellevaux 51, 2000 Neuchatel, Switzerland

Department of Chemistry, University of Bologna, Ravenna Campus, via Guaccimanni, 48120 Ravenna, Italy

Arc’Antique conservation and research laboratory, 26 Rue de la Haute Forêt, 44300 Nantes, France

Funding

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

References (100+)

Show source-provided references
1. L’âge du Bronze, une période historique
2. Micro-Raman study of copper hydroxychlorides and other corrosion products of bronze samples mimicking archaeological coins10.1007/s00216-011-5268-9 ↗
3. Analysis of silver coins from colonial Brazil by hand held XRF and micro-XRF10.1016/j.apradiso.2020.109409 ↗
4. Nondestructive techniques in the study of a gilded metallic sword from the Islamic Art Museum
5. Surface analyses on modern and ancient copper based fakes10.1179/174329305X64402 ↗
6. Atmospheric corrosion of historical organ pipes: The influence of environment and materials10.1016/j.corsci.2008.06.045 ↗
7. Investigation of the content of ancient tibetan metallic buddha statues by means of neutron imaging methods10.1111/j.1475-4754.2009.00488.x ↗
8. The Corrosion of Metals
9. Application of electrochemical impedance spectroscopy to study the degradation of polymer-coated metals10.1016/0300-9440(95)00581-1 ↗
10. Biocorrosion: Towards understanding interactions between biofilms and metals10.1016/j.copbio.2004.05.001 ↗
11. Structural characterization of corrosion products on archaeological iron: An integrated analytical approach to establish corrosion forms10.1002/jrs.1130 ↗
12. Colloid and Materials Science for the Conservation of Cultural Heritage: Cleaning, Consolidation, and Deacidification10.1021/la304456n ↗
13. Turner-Walker, G. (2008). A Practical Guide to the Care and Conservation of Metals, Headquarters Administration of Cultural Heritage, Council for Cultural Affairs.
14. Use of Bacteria To Stabilize Archaeological Iron10.1128/AEM.03478-16 ↗
15. Comparison of a bio-based corrosion inhibitor versus benzotriazole on corroded copper surfaces10.1016/j.corsci.2018.08.020 ↗
16. PVA-based peelable films loaded with tetraethylenepentamine for the removal of corrosion products from bronze10.1016/j.apmt.2019.100549 ↗
17. Spectroscopic characterization of an innovative biological treatment for corroded metal artefacts10.1002/jrs.4164 ↗
18. Evaluation of cleaning treatments for tarnished silver: The conservator’s perspective
19. Watkinson, D. (2010). Preservation of Metallic Cultural Heritage. Shreir’s Corrosion, Elsevier.10.1016/B978-044452787-5.00172-4 ↗
20. Argyropoulos, V., Giannoulaki, M., Michalakakos, G.P., and Siatou, A. (2007). A Survey of the Type of Corrosion Inhibitors and Protective Coatings Used for the Conservation of Metal Objects from Museum Collections in the Mediterranean Basin. Strategies for Saving our Cultural Heritage. Proceedings of the International Conference on Conservation Strategies for Saving Indoor Metallic Collections, Cairo (Egypt). TEI of Athens, Athens, Academic Press.
21. A review of the development and testing of Incralac lacquer10.1080/01971360.2017.1362863 ↗
22. Physical ageing of organic coatings10.1016/S0300-9440(03)00037-7 ↗
23. An investigation into the cause of corrosion on indoor bronze sculpture10.1179/2047058412Y.0000000004 ↗
24. Short Communication Removal of Paraffin Wax in the Re-treatment of Archaeological Iron10.1179/019713608804539619 ↗
25. Chitosan-based coatings for corrosion protection of copper-based alloys: A promising more sustainable approach for cultural heritage applications10.1016/j.porgcoat.2018.05.002 ↗
26. Mari, Y. (2012). Il Restauro Della Grande Croce del Pollaiolo: Un Intervento All’interno del Cantiere Organizzato per l’Altare di san Giovanni. E l’informe si fa forma...: studi intorno a Santa Maria del Fiore in ricordo di Patrizio Osticresi, Mandragora.
27. La Banderuola di Palazzo Vecchio: Storia, vicende conservative, restauro
28. Phenix, A. (2013). Effects of Organic Solvents on Artists Oil Paint Films: Swelling. New Insights into the Cleaning of Paintings: Proceedings from the Cleaning 2010 International Conference, Universidad Politecnica de Valencia and Museum Conservation Institute, Smithsonian Institution.
29. Upper respiratory impairment in restorers of cultural heritage10.1093/occmed/kqq170 ↗
30. Environmental behavior and eco-toxicity of xylene in aquatic environments: A review10.1016/j.ecoenv.2017.07.050 ↗
31. Sustainability in conservation practice10.1080/19455224.2011.566013 ↗
32. Gupta, T., Mistry, B., and Gupta, B.S. (2017). Preface on Green Conservation of the Museum Objects. A treatise on Recent Trends and Sustainability in Crafts & Design, Excel India.
33. Criteria for Treatment: Reversibility10.1179/019713687806027852 ↗
34. Brandi, C. (1963). Teoria del Restauro, Ed. di storia e letteratura.
35. Corrosion of metal electrodes in deep eutectic solvents10.1016/j.elecom.2018.04.011 ↗
36. Heitz, E. (1974). Corrosion of Metals in Organic Solvents. Advances in Corrosion Science and Technology, Springer.10.1007/978-1-4615-9059-0_3 ↗
37. Bridgland, J. (2014). The removal of aged acrylic coatings from wall paintings using microemulsions. ICOM-CC 17th Triennial Conference Preprints, Melbourne, Australia, 15–19 September 2014, International Council of Museums. art. 1103.
38. Microemulsions, Micelles, and Functional Gels: How Colloids and Soft Matter Preserve Works of Art10.1002/anie.201710711 ↗
39. Micelle, microemulsions, and gels for the conservation of cultural heritage10.1016/j.cis.2013.09.008 ↗
40. Laponite micro-packs for the selective cleaning of multiple coherent deposits on wall paintings: The case study of Casina Farnese on the Palatine Hill (Rome-Italy)10.1016/j.ibiod.2014.06.004 ↗
41. Anti-corrosion ability of surfactants: A review10.1016/S1452-3981(23)18157-0 ↗
42. Fratini, E., and Carretti, E. (2013). CHAPTER 10. Cleaning IV: Gels and Polymeric Dispersions. Nanoscience for the Conservation of Works of Art, Royal Society of Chemistry.10.1039/9781849737630-00252 ↗
43. Definition of the concept of polymer gel10.1134/S1811238208010050 ↗
44. Baglioni, P., Baglioni, M., Bonelli, N., Chelazzi, D., and Giorgi, R. (2019). Smart Soft Nanomaterials for Cleaning. Nanotechnologies and Nanomaterials for Diagnostic, Conservation and Restoration of Cultural Heritage, Elsevier.10.1016/B978-0-12-813910-3.00009-4 ↗
45. Wolbers, R. (1992, January 20–22). Restoration’92: Conservation, training, materials and techniques: Latest developments. Proceedings of the Preprints to the Conference Held at the RAI International Exhibition and Congress Centre, Amsterdam, The Netherlands.
46. Wolbers, R. (2000). Cleaning Painted Surfaces: Aqueous Methods, Archetype Publications.
47. Van Loon, A., Hartman, L.E., van den Burg, J., Haswell, R., and Pottasch, C. (2019). The Development of an Aqueous Gel Testing Procedure for the Removal of Lead-Rich Salt Crusts on the Surface of Paintings by Giovanni Antonio Pellegrini (1675–1741) in the “Golden Room” of the Mauritshuis, Springer.10.1007/978-3-319-90617-1_16 ↗
48. Biological colonization on stone monuments: A new low impact cleaning method10.1016/j.culher.2017.09.004 ↗
49. A new approach to cleaning iron stained marble surfaces
50. Gellan hydrogel as a powerful tool in paper cleaning process: A detailed study10.1016/j.jcis.2013.10.062 ↗
51. Angelova, L.V., Ormsby, B., Townsend, J.H., and Wolbers, R. (2017). Gellan gum and agar compared to aqueous immersion for cleaning paper. Gels in the Conservation of Art, Archetype Publications.
52. Guilminot, E., Leroux, M., Raimon, A., and Chalvidal, C. (2018, January 29–30). Projet collaboratif sur l’utilisation des gels pour le traitement des métaux: Démarche et fonctionnement. Proceedings of the Journées des Restaurateurs en Archéologie, Journée d’Étude, de Recherche et d’Innovation Lyon, France.
53. A review of solvent action on oil paint10.1186/s40494-020-00388-x ↗
54. Angelova, L.V., Ormsby, B., Townsend, J.H., and Wolbers, R. (2017). A Comparison between Gel and Swab Cleaning: Physical Changes to Delicate Surfaces. Gels in the Conservation of Art, Archetype Publications.
55. Chemello, C., Brambilla, L., and Joseph, E. (2019). Use of Gels for the treatment of Metals. Proceedings of the Metal 2019 Proceedings of the Interim Meeting of the ICOM-CC Metals Working Group, International Councils of Museums—Committee for Conservation.
56. Angelova, L.V., Ormsby, B., Townsend, J.H., and Wolbers, R. (2017). Layer by layer: The removal of complex soiling on a collection of modern art bronzes using buffered pH-adjusted aquous gels. Gels in the Conservation of Art, Archetype Publications.
57. Film forming PVA-based cleaning systems for the removal of corrosion products from historical bronzes10.1515/pac-2017-0204 ↗
58. Feldman, D. (2020). Poly(Vinyl Alcohol) Recent Contributions to Engineering and Medicine. J. Compos. Sci., 4.10.3390/jcs4040175 ↗
59. Biodegradation of poly (vinyl alcohol) based materials10.1016/S0079-6700(02)00149-1 ↗
60. Steel versus Paper: The Conservation of a Piece of Modern Art Consisting of a Rust Print on Paper
61. Varghese, S.A., Rangappa, S.M., Siengchin, S., and Parameswaranpillai, J. (2020). Natural polymers and the hydrogels prepared from them. Hydrogels Based on Natural Polymers, Elsevier.10.1016/B978-0-12-816421-1.00002-1 ↗
62. Effect of freezing under electrostatic field on selected properties of an agar gel10.1016/j.ifset.2017.06.013 ↗
63. Rigid Gels and Enzyme Cleaning
64. Angelova, L.V., Ormsby, B., Townsend, J.H., and Wolbers, R. (2017). Towards the sustainable use of agar/agarose in conservation: A case study of the Izu peninsula, Japan. Gels in the Conservation of Art, Archetype Publications.
65. Angelova, L.V., Ormsby, B., Townsend, J.H., and Wolbers, R. (2017). A study of commercial agar gels as cleaning materials. Gels in the Conservation of Art, Archetype Publications.
66. Angelova, L.V., Ormsby, B., Townsend, J.H., and Wolbers, R. (2017). Terminology and properties of selected gels. Gels in the Conservation of Art, Archetype Publications.
67. Marchand, G., Chevallier, R., Guilminot, E., Rossetti, L., and Lemoine, S. (2013). Study of the conservation treatment applied to the archaeological horn silver artifacts. Proceedings of the Interim Meeting for the International Council of Museums Committee for Conservation Metal Working Group, Metal 2013, International Councils of Museums—Committee for Conseravtion and Historic Scotland.
68. Fays, M. (2018). «D’or, D’argent et de Pate Noire: Incrustations Révélées» Étude et Conservation-Restauration de Cinq Objets Islamiques en Alliage Cuivreux Incrustés, Institut National du Patrimoine.
69. Corroded applied lead-based decoration (hyomon) on Japanese lacquer: Principles and case studies10.1179/204705814X13975704319316 ↗
70. Angelova, L.V., Ormsby, B., Townsend, J.H., and Wolbers, R. (2017). Comparison of three hydrogels for cleaning tarnished silver threads using electrochemical treatment. Gels in the Conservation of Art, Archetype Publications.
71. Angelova, L.V., Ormsby, B., Townsend, J.H., and Wolbers, R. (2017). Trials fo agar gels and task-specific salts for the electrochemical reduction of silver sulphide on silver leaf. Gels in the Conservation of Art, Archetype Publications.
72. Domon Beuret, E., Mathys, L., Brambilla, L., Albini, M., Cevey, C., Bertholon, R., Junier, P., and Joseph, E. Biopatines: Des champignons au service des alliages cuivreux. Proceedings of the Cahier n°22—XXVIIIe Journées des restaurateurs en archéologie, Arles, 16–17 October 2014.
73. Angelova, L.V., Ormsby, B., Townsend, J.H., and Wolbers, R. (2017). The removal of Paraloid B-72 coatings with aqueous gelled systems: Roman frescoesfrom Empúries, Catalonia. Gels in the Conservation of Art, Archetype Publications.
74. Difference between Chitosan Hydrogels via Alkaline and Acidic Solvent Systems10.1038/srep36053 ↗
75. Chitosan-based self-healing protective coatings doped with cerium nitrate for corrosion protection of aluminum alloy 202410.1016/j.porgcoat.2012.02.012 ↗
76. Carneiro, J., Tedim, J., Fernandes, S.C.M., Freire, C.S.R., Gandini, A., Ferreira, M.G.S., and Zheludkevich, M.L. (2013). Chitosan as a smart coating for controlled release of corrosion inhibitor 2-mercaptobenzothiazole. ECS Electrochem. Lett., 2.10.1149/2.002306eel ↗
77. Study of Post-World War II French Aeronautical Aluminium Alloy and Coatings: Historical and Materials Science Approach10.1080/00393630.2019.1610846 ↗
78. Preparation and characterization of a chitosan-based low-pH-sensitive intelligent corrosion inhibitor10.1007/s12613-015-1161-4 ↗
79. Lai, H., Liu, S., Yan, J., Xing, F., and Xiao, P. (2020). Facile Fabrication of Biobased Hydrogel from Natural Resources: L-Cysteine, Itaconic Anhydride, and Chitosan. ACS Sustain. Chem. Eng.10.1021/acssuschemeng.0c00774 ↗
80. Bio-based biodegradable hydrogels prepared by crosslinking of microbial poly(γ-glutamic acid) with L-lysine in aqueous solution10.1038/pj.2010.142 ↗
81. Sustainability in art conservation: A novel bio-based organogel for the cleaning of water sensitive works of art10.1515/pac-2017-0507 ↗
82. Organogel formulations for the cleaning of easel paintings10.1007/s00339-015-9364-0 ↗
83. Organogels for the cleaning of artifacts10.1515/pac-2016-0908 ↗
84. A new bio-based organogel for the removal of wax coating from indoor bronze surfaces10.1186/s40494-019-0276-8 ↗
85. Soft, Peelable Organogels from Partially Hydrolyzed Poly(vinyl acetate) and Benzene-1,4-diboronic Acid: Applications to Clean Works of Art10.1021/acsami.7b09473 ↗
86. Chelazzi, D., Fratini, E., Giorgi, R., Mastrangelo, R., Rossi, M., and Baglioni, P. (2018). Gels for the Cleaning of Works of Art. Gels and Other Soft Amorphous Solids, ACS Publications.10.1021/bk-2018-1296.ch015 ↗
87. Life cycle assessments of biodegradable, commercial biopolymers—A critical review10.1016/j.resconrec.2013.06.010 ↗
88. Sustainability Metrics: Life Cycle Assessment and Green Design in Polymers10.1021/es101640n ↗
89. Expanding GSK’s Solvent Selection Guide?application of life cycle assessment to enhance solvent selections10.1007/s10098-004-0245-z ↗
90. Green and Bio-Based Solvents10.1007/s41061-018-0191-6 ↗
91. Green Chemistry: Principles and Practice10.1039/B918763B ↗
92. A survey of solvent selection guides10.1039/C4GC01149J ↗
93. Production of acetone, butanol, and ethanol from biomass of the green seaweed Ulva lactuca10.1016/j.biortech.2012.10.094 ↗
94. What is a green solvent? A comprehensive framework for the environmental assessment of solvents10.1039/b617536h ↗
95. Antimicrobial activity of Butyl acetate, Ethyl acetate and Isopropyl alcohol on undesirable microorganisms in cosmetic products10.1111/ics.12314 ↗
96. Gettens, R.J., and Stout, G.L. (1966). Painting Materials. A Short Encyclopaedia, Dover Publications, Inc.
97. A chemical study of organic materials in three murals by Keith Haring: A comparison of painting techniques10.1016/j.microc.2015.06.003 ↗
98. Analytical characterization of polymers used in conservation and restoration by ATR-FTIR spectroscopy10.1007/s00216-009-3201-2 ↗
99. Bio-based solvents: An emerging generation of fluids for the design of eco-efficient processes in catalysis and organic chemistry10.1039/c3cs60241a ↗
100. Recent trends in lactic acid biotechnology: A brief review on production to purification