journal article·2019-05-17Open access

Effect of Nanoparticles Addition on the Microstructure and Properties of Lead-Free Solders: A Review

Peng Zhang, Songbai Xue, Jianhao Wang, Peng Xue, Sujuan Zhong, Weimin Long

Applied Sciences· Volume 9· Issue 10

Abstract

With the development of microelectronic packaging and increasingly specific service environment of solder joints, much stricter requirements have been placed on the properties of lead-free solders. On account of small size effect and high surface energy, nanoparticles have been widely used to improve the microstructure and properties of lead-free solders. Therefore, the composite solders bearing nanoparticles have recently attracted wide attention. This article reviewed the recent research on SnAgCu, SnBi, and SnZn composite solder alloys and introduced the effect of nanoparticles on their microstructure, mechanical properties, wettability, and reliability. The mechanism of nanoparticles strengthening was analyzed and summarized. In addition, the shortcomings and future development trends of nanoparticle-reinforced lead-free solders were discussed, which is expected to provide some theoretical reference for the application of these composite solder in 3D IC package.
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Research context

OpenAlex topics: Electronic Packaging and Soldering Technologies · Aluminum Alloys Composites Properties · 3D IC and TSV technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China

School of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing 210096, China

State Key Laboratory of Advanced Brazing Filler Metals and Technology, Zhengzhou Research Institute of Mechanical Engineering Co., Ltd., Zhengzhou 450002, China

Funding

The National Natural Science Foundation of China · The Priority Academic Program Development of Jiangsu Higher Education Institutions

References (100+)

Show source-provided references
1. High-performance electronics using dense, perfectly aligned arrays of single-walled carbon nanotubes10.1038/nnano.2007.77 ↗
2. Effect of TiO2 additions on Sn-0.7Cu-0.05Ni lead-free composite solder10.1016/j.microrel.2016.08.011 ↗
3. Recent Developments on Epoxy-Based Thermally Conductive Adhesives (TCA): A Review10.1080/03602559.2017.1354253 ↗
4. Recent advances of conductive adhesives as a lead-free alternative in electronic packaging: Materials, processing, reliability and applications10.1016/j.mser.2006.01.001 ↗
5. Present status of Sn–Zn lead-free solders bearing alloying elements10.1007/s10854-014-2659-7 ↗
6. Effect of Rare-Earth (La, Ce, and Y) Additions on the Microstructure and Mechanical Behavior of Sn-3.9Ag-0.7Cu Solder Alloy10.1007/s11661-009-0146-1 ↗
7. Wettability and interfacial whiskers of Sn–9Zn–0.5Ga–0.08Nd solder with Sn, SnBi and Au/Ni coatings10.1007/s10854-014-2049-1 ↗
8. Effects of small additions of Ag, Al, and Ga on the structure and properties of the Sn–9Zn eutectic alloy10.1016/j.jallcom.2005.08.034 ↗
9. Effect of In on microstructure, thermodynamic characteristic and mechanical properties of Sn–Bi based lead-free solder10.1016/j.jallcom.2015.01.219 ↗
10. Effects of Co and Ni addition on reactive diffusion between Sn–3.5Ag solder and Cu during soldering and annealing10.1016/j.msea.2006.01.032 ↗
11. Effect of indium addition on interfacial IMC growth and bending properties of eutectic Sn–0.7Cu solder joints10.1007/s10854-017-7512-3 ↗
12. Effect of Nd on tin whisker growth in Sn–Zn soldered joint10.1007/s10854-015-4217-3 ↗
13. Whisker growth on SnAgCu–xPr solders in electronic packaging10.1007/s10854-016-4468-7 ↗
14. Tensile creep characteristics of Sn–3.5Ag–0.5Cu (SAC355) solder reinforced with nano-metric ZnO particles10.1016/j.msea.2014.02.061 ↗
15. Suppression of Cu6Sn5 in TiO2 reinforced solder joints after multiple reflow cycles10.1016/j.matdes.2016.06.121 ↗
16. Improving the mechanical performance of Sn57.6Bi0.4Ag solder joints on Au/Ni/Cu pads during aging and electromigration through the addition of tungsten (W) nanoparticle reinforcement10.1016/j.msea.2016.05.092 ↗
17. Synthesis and characterization of ceramic nanoparticles reinforced lead-free solder10.1016/j.ceramint.2017.01.067 ↗
18. Structure and properties of lead-free solders bearing micro and nano particles10.1016/j.mser.2014.06.001 ↗
19. Sn–3.0Ag–0.5Cu nanocomposite solders reinforced by graphene nanosheets10.1007/s10854-016-4631-1 ↗
20. Comparative study of the microstructure and mechanical strength of tin-copper (Sn0.7Cu) solder modified with silver (Ag) by both alloying and doping methods10.1007/s10854-016-4635-x ↗
21. Effect of additions of ZrO2 nano-particles on the microstructure and shear strength of Sn–Ag–Cu solder on Au/Ni metallized Cu pads10.1016/j.microrel.2011.03.042 ↗
22. Tensile deformation behavior and melting property of nano-sized ZnO particles reinforced Sn–3.0Ag–0.5Cu lead-free solder10.1016/j.msea.2014.09.028 ↗
23. Influence of La2O3 nanoparticle additions on microstructure, wetting, and tensile characteristics of Sn–Ag–Cu alloy10.1016/j.matdes.2015.07.137 ↗
24. Shielding effect of Ag3Sn on growth of intermetallic compounds in isothermal heating and cooling during multiple reflows10.1007/s10854-017-8428-7 ↗
25. Influence of SrTiO3 nano-particles on the microstructure and shear strength of Sn–Ag–Cu solder on Au/Ni metallized Cu pads10.1016/j.jallcom.2010.10.081 ↗
26. Effects of reflow on the interfacial characteristics between Zn nanoparticles containing Sn-3.8Ag-0.7Cu solder and copper substrate10.1108/09540911311309040 ↗
27. Tang, Y., Luo, S.M., Li, G.Y., Yang, Z., and Hou, C.J. (2018). Ripening Growth Kinetics of Cu6Sn5 Grains in Sn-3.0Ag-0.5Cu-xTiO2/Cu Solder Joints During the Reflow Process. J. Electron. Packag., 140.10.1115/1.4038861 ↗
28. Effect of γ-Fe2O3 nanoparticles size on the properties of Sn-1.0Ag–0.5Cu nano-composite solders and joints10.1016/j.jallcom.2015.11.213 ↗
29. Effect of the size of carbon nanotubes (CNTs) on the microstructure and mechanical strength of CNTs-doped composite Sn0.3Ag0.7Cu-CNTs solder10.1016/j.msea.2018.05.002 ↗
30. Effect of nano-Al addition on properties and microstructure of low-Ag content Sn–1Ag–0.5Cu solders10.1007/s10854-016-4751-7 ↗
31. Effects of Mn nanoparticles on tensile properties of low-Ag Sn-0.3Ag-0.7Cu-xMn solder alloys and joints10.1016/j.jallcom.2017.05.182 ↗
32. Effects of Nano-TiO2 additions on thermal analysis, microstructure and tensile properties of Sn3.5Ag0.25Cu solder10.1016/j.matdes.2009.08.008 ↗
33. Effect of Nano-particles TiO2 on the Microstructures and Properties of SnAgCu Solders
34. Influence of Ag-modified graphene nanosheets addition into Sn–Ag–Cu solders on the formation and growth of intermetallic compound layers10.1016/j.jallcom.2017.01.286 ↗
35. The Frontier Analysis of RCS for Micro-Nano Particle10.4028/www.scientific.net/AMR.337.526 ↗
36. Composite lead-free electronic solders
37. Effect of metal/ceramic nanoparticle-doped fluxes on the wettability between Sn–Ag–Cu solder and a Cu layer10.1016/j.jallcom.2008.11.015 ↗
38. Effect of nano-Fe2O3 additions on wettability and interfacial intermetallic growth of low-Ag content Sn–Ag–Cu solders on Cu substrates10.1016/j.jallcom.2014.12.024 ↗
39. Effects of α-Al2O3 nanoparticles-doped on microstructure and properties of Sn–0.3Ag–0.7Cu low-Ag solder10.1007/s10854-018-8727-7 ↗
40. Effect of Graphene Nanoplatelets on Wetting, Microstructure, and Tensile Characteristics of Sn-3.0Ag-0.5Cu (SAC) Alloy10.1007/s11661-015-3214-8 ↗
41. Interfacial IMC Layer and Tensile Properties of Ni-Reinforced Cu/Sn–0.7Cu–0.05Ni/Cu Solder Joint: Effect of Aging Temperature10.1007/s12666-017-1104-z ↗
42. Influence of TiO2 nanoparticles on IMC growth in Sn–3.0Ag–0.5Cu–xTiO2 solder joints during isothermal aging process10.1007/s10854-013-1675-3 ↗
43. In situ quantitative study of microstructural evolution at the interface of Sn3.0Ag0.5Cu/Cu solder joint during solid state aging10.1016/j.jallcom.2015.02.088 ↗
44. Suppression effect of Cu and Ag on Cu3Sn layer in solder joints10.1007/s10854-013-1454-1 ↗
45. Reliability enhancement of Sn-1.0Ag-0.5Cu nano-composite solders by adding multiple sizes of TiO2 nanoparticles10.1016/j.jallcom.2016.12.037 ↗
46. Suppressing effect of 0.5 wt.% nano-TiO2 addition into Sn-3.5Ag-0.5Cu solder alloy on the intermetallic growth with Cu substrate during isothermal aging10.1016/j.jallcom.2011.05.116 ↗
47. Performance of Sn–3.0Ag–0.5Cu composite solder with TiC reinforcement: Physical properties, solderability and microstructural evolution under isothermal ageing10.1016/j.jallcom.2016.05.245 ↗
48. Stress relaxation and failure behavior of Sn–3.0Ag–0.5Cu flip-chip solder bumps undergoing electromigration10.1557/jmr.2014.231 ↗
49. Electromigration-induced intermetallic growth and voids formation in symmetrical Cu/Sn/Cu and Cu/Intermetallic compounds (IMCs)/Cu joints10.1007/s10854-015-2736-6 ↗
50. Electromigration of composite Sn-Ag-Cu solder bumps10.1007/s13391-015-4454-x ↗
51. Effects of Ni-coated Carbon Nanotubes addition on the electromigration of Sn-Ag-Cu solder joints10.1016/j.jallcom.2013.07.058 ↗
52. Interfacial intermetallic growth and mechanical properties of carbon nanotubes reinforced Sn3.5Ag0.5Cu solder joint under current stressing10.1016/j.jallcom.2014.01.083 ↗
53. Effect of Ag addition on the corrosion properties of Sn-based solder alloys10.1002/maco.200905237 ↗
54. Effect of graphene nanosheets on the corrosion behavior of Sn–Ag–Cu solders10.1007/s10854-015-3112-2 ↗
55. Interfacial microstructure, wettability and material properties of nickel (Ni) nanoparticle doped tin–bismuth–silver (Sn–Bi–Ag) solder on copper (Cu) substrate
56. A study of Ag additive methods by comparing mechanical properties between Sn57.6Bi0.4Ag and 0.4 wt% nano-Ag-doped Sn58Bi BGA solder joints10.1007/s10854-014-2177-7 ↗
57. Effect of silver (Ag) nanoparticle size on the microstructure and mechanical properties of Sn58Bi–Ag composite solders10.1016/j.jallcom.2015.05.023 ↗
58. Solderability of SnBi-nano Cu solder pastes and microstructure of the solder joints10.1007/s10854-015-4016-x ↗
59. Effects of nanoscale Cu6Sn5 particles addition on microstructure and properties of SnBi solder alloys10.1016/j.msea.2016.12.089 ↗
60. Improvement of mechanical properties of Sn-58Bi alloy with multi-walled carbon nanotubes10.1016/S1003-6326(12)61788-9 ↗
61. Effect of CNTs and Ni coated CNTs on the mechanical performance of Sn57.6Bi0.4Ag BGA solder joints10.1016/j.msea.2016.01.045 ↗
62. Improved microstructure and mechanical properties for Sn58Bi solder alloy by addition of Ni-coated carbon nanotubes10.1016/j.msea.2015.06.080 ↗
63. Reinforcement of graphene nanosheets on the microstructure and properties of Sn58Bi lead-free solder10.1016/j.matdes.2016.10.034 ↗
64. Improved microstructure and mechanical properties for Sn58Bi0.7Zn solder joint by addition of graphene nanosheets10.1016/j.jallcom.2016.02.093 ↗
65. Influence of BaTiO3 Nanoparticle Addition on Microstructure and Mechanical Properties of Sn-58Bi Solder10.1007/s11664-015-3796-3 ↗
66. Effect of Y2O3 particles on microstructure formation and shear properties of Sn-58Bi solder10.1007/s10854-009-0025-y ↗
67. Effects of nano-copper particles on the properties of Sn58Bi composite solder pastes10.1108/MI-02-2016-0013 ↗
68. Recent progress on the development of Sn–Bi based low-temperature Pb-free solders10.1007/s10854-019-00701-w ↗
69. Interfacial segregation of Bi during current stressing of Sn-Bi/Cu solder interconnect10.1007/s11664-005-0191-5 ↗
70. Effects of electromigration on the growth of intermetallic compounds in Cu/SnBi/Cu solder joints10.1557/JMR.2008.0331 ↗
71. Enhanced electromigration reliability via Ag nanoparticles modified eutectic Sn–58Bi solder joint10.1007/s00542-012-1701-z ↗
72. Effect of nano Al2O3 particles doping on electromigration and mechanical properties of Sn–58Bi solder joints10.1016/j.microrel.2015.05.008 ↗
73. Effects of indium addition on properties and wettability of Sn–0.7Cu–0.2Ni lead-free solders10.1016/j.matdes.2014.07.035 ↗
74. Microstructures and properties of SnZn-xEr lead-free solders10.1016/S1002-0721(12)60131-8 ↗
75. Interfacial microstructures and mechanical properties of Sn–9Zn–0.5Ga–xNd on Cu substrate with aging treatment10.1016/j.matdes.2014.03.052 ↗
76. Microstructure, thermal analysis and damping properties of Ag and Ni nano-particles doped Sn-8Zn-3Bi solder on OSP-Cu substrate10.1016/j.jallcom.2014.08.076 ↗
77. Microstructure and kinetic analysis of the properties and behavior of nickel (Ni) nano-particle doped tin–zinc–bismuth (Sn–8Zn–3Bi) solders on immersion silver (Ag)-plated copper (Cu) substrates10.1007/s10854-014-1906-2 ↗
78. Microstructure and mechanical properties of Sn-9Zn-xAl2O3 nanoparticles (x = 0–1) lead-free solder alloy: first-principles calculation and experimental research10.1016/j.msea.2016.10.006 ↗
79. Influences of ZrO2 nano-particles on the microstructures and microhardness of Sn8Zn1Bi-xZrO2/Cu solder joints10.1007/s10854-012-0711-z ↗
80. Effect of adding nanometric ZnO particles on thermal, microstructure and tensile creep properties of Sn–6.5 wt%Zn–3 wt%In solder alloy10.1007/s10854-017-7166-1 ↗
81. Influence of small Sb nanoparticles additions on the microstructure, hardness and tensile properties of Sn–9Zn binary eutectic solder alloy10.1007/s10854-011-0608-2 ↗
82. Interfacial microstructure and shear strength of Ag nano particle doped Sn-9Zn solder in ball grid array packages10.1016/j.microrel.2009.05.004 ↗
83. Effect of graphene nanosheets reinforcement on the performance of Sn-Ag-Cu lead-free solder10.1016/j.msea.2012.10.079 ↗
84. Microstructures and properties of new Sn–Ag–Cu lead-free solder reinforced with Ni-coated graphene nanosheets10.1016/j.jallcom.2015.09.178 ↗
85. Design and performance of Ag nanoparticle-modified graphene/SnAgCu lead-free solders10.1016/j.msea.2016.04.084 ↗
86. Single-wall carbon nanotube (SWCNT) functionalized Sn–Ag–Cu lead-free composite solders10.1016/j.jallcom.2006.10.123 ↗
87. Influence of Ag micro-particle additions on the microstructure, hardness and tensile properties of Sn–9Zn binary eutectic solder alloy10.1016/j.microrel.2010.03.017 ↗
88. Li, Y., Song, B., Zhang, Y., Xiong, Y., Shi, X., and Zhang, K. (2018). Microstructure, interfacial IMC layer and mechanical properties of Cu/Sn-9Zn-xZrC/Cu solder joints. Mater. Res. Express, 5.10.1088/2053-1591/aacd97 ↗
89. Effect of nano Al2O3 additions on the interfacial behavior and mechanical properties of eutectic Sn-9Zn solder on low temperature wetting and soldering of 6061 aluminum alloys10.1016/j.jallcom.2016.11.136 ↗
90. Inhibiting the growth of Sn whisker in Sn-9Zn lead-free solder by Nd and Ga10.1007/s10854-014-1927-x ↗
91. Effect of nano Ni additions on the structure and properties of Sn–9Zn and Sn–Zn–3Bi solders in Au/Ni/Cu ball grid array packages10.1016/j.mseb.2009.03.010 ↗
92. Effects of Ag and Cu addition on microstructural properties and oxidation resistance of Sn–Zn eutectic alloy10.1016/j.jallcom.2006.12.037 ↗
93. Mechanical properties and fracture mechanisms of Sn-3.0Ag-0.5Cu solder alloys and joints at cryogenic temperatures10.1016/j.msea.2016.12.058 ↗
94. Effect of deep cryogenic treatment on mechanical properties and microstructure of Sn3.0Ag0.5Cu solder10.1007/s10854-017-8400-6 ↗
95. Effect of gamma-ray irradiation on microstructure and mechanical property of Sn63Pb37 solder joints10.1007/s10854-018-0213-8 ↗
96. Coupling effects of rare-earth Pr and Al2O3 nanoparticles on the microstructure and properties of Sn-0.3Ag-0.7Cu low-Ag solder10.1016/j.jallcom.2019.01.034 ↗
97. Thermo-migration behavior of SAC305 lead-free solder reinforced with fullerene nanoparticles10.1007/s10853-016-0234-8 ↗
98. Lead free Sn-Ag-Cu solders reinforced by Ni-coated graphene nanosheets prepared by mechanical alloying: Microstructural evolution and mechanical durability10.1016/j.msea.2017.07.024 ↗
99. Reduction of electromigration damage in SAC305 solder joints by adding Ni nanoparticles through flux doping10.1007/s10853-015-9230-7 ↗
100. In situ nanoparticulate-reinforced lead-free Sn–Ag composite prepared by rapid solidification10.1007/s10854-006-9056-9 ↗